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Ni(OH)2/Ni/g-C3N4 composite: An efficient electrocatalyst for hydrogen evolution

ZHANG Jie ZHAO Yu WU Ai-lian LI Jia WANG Yu-xue

张杰, 赵煜, 武爱莲, 李佳, 王玉雪. Ni(OH)2/Ni/g-C3N4复合材料:一种高效的析氢电催化剂[J]. 燃料化学学报, 2021, 49(2): 198-204. doi: 10.1016/S1872-5813(21)60010-5
引用本文: 张杰, 赵煜, 武爱莲, 李佳, 王玉雪. Ni(OH)2/Ni/g-C3N4复合材料:一种高效的析氢电催化剂[J]. 燃料化学学报, 2021, 49(2): 198-204. doi: 10.1016/S1872-5813(21)60010-5
ZHANG Jie, ZHAO Yu, WU Ai-lian, LI Jia, WANG Yu-xue. Ni(OH)2/Ni/g-C3N4 composite: An efficient electrocatalyst for hydrogen evolution[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 198-204. doi: 10.1016/S1872-5813(21)60010-5
Citation: ZHANG Jie, ZHAO Yu, WU Ai-lian, LI Jia, WANG Yu-xue. Ni(OH)2/Ni/g-C3N4 composite: An efficient electrocatalyst for hydrogen evolution[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 198-204. doi: 10.1016/S1872-5813(21)60010-5

Ni(OH)2/Ni/g-C3N4复合材料:一种高效的析氢电催化剂

doi: 10.1016/S1872-5813(21)60010-5
详细信息
  • 中图分类号: O614.81

Ni(OH)2/Ni/g-C3N4 composite: An efficient electrocatalyst for hydrogen evolution

Funds: The project was supported by the National Natural Science Foundation of China and Shenhua Group Corp. (U1261103)
More Information
    Corresponding author: E-mail: Zhouyu@tyut.edu.cn
  • 摘要: 高效析氢催化剂的制备仍是目前亟待解决的重要课题。本研究采用液相浸渍原位还原法制备了Ni(OH)2/Ni/g-C3N4复合催化剂,并与碳纸(CP)组合作为微生物电解电池(MEC)的阴极。采用SEM、TEM、XRD、XPS和电化学分析等技术对所制备的催化剂样品的结构性质和析氢电催化性能进行了分析研究。结果表明,Ni(OH)2/Ni/g-C3N4催化剂在100 A/cm2的电流密度驱动下具有优秀的析氢过电位(1881 mV)、较低的电荷转移电阻(10.86 Ω)和较低的塔费尔斜率(44.3 mV/dec),其电化学活性优于纯g-C3N4催化剂和CP,甚至可与Pt催化剂媲美。
  • Figure  1  SEM images of g-C3N4 (a) and Ni(OH)2/Ni/g-C3N4 catalysts (b); TEM image of Ni(OH)2/Ni/g-C3N4 catalyst (c); XRD patterns of g-C3N4 and Ni(OH)2/Ni/g-C3N4 catalysts (d); survey spectrum and XPS spectrum (inset) of O 1s for the Ni(OH)2/Ni/g-C3N4 catalyst (e); XPS spectra of Ni 2p (f), N 1s (g), and C 1s (h) for the Ni(OH)2/Ni/g-C3N4 catalyst; N2 sorption isotherms of g-C3N4 (a) and Ni(OH)2/Ni/g-C3N4 catalysts (i)

    Figure  2  LSV curves of Ni(OH)2/Ni/g-C3N4 composite catalysts with different Ni loading ratios (a) and coating amounts (b); Tafel plot (points represent raw data, lines represent fitted data) (c); EIS spectra of bare CP, Ni(OH)2/Ni/g-C3N4 and Pt catalysts (d) (the illustration in Graph (d) is the equivalent circuit used to simulate the HER kinetics process); CP curves (e)

    Figure  3  Current generation for the cathode electrodes in the MEC (a) and the composition of MEC effluent gas per cycle (b)

    Table  1  Energy efficiencies and hydrogen production in the MEC with different cathodes

    CathodeRcat/%$ {R_{\rm{H}}}_{_2} $/%$ {Q_{\rm{H}}}_{_2} $/
    (m3-H2·m−3·d−1)
    ηw/%ηw+s/%
    CP24.7779.510.11952.4125.22
    Ni(OH)2/Ni/g-C3N449.62249.340.3725104.9862.18
    Pt37.47134.470.200979.2740.37
    下载: 导出CSV
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出版历程
  • 收稿日期:  2020-09-22
  • 修回日期:  2020-11-03
  • 刊出日期:  2021-02-08

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