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十氢萘选择性开环反应的研究进展

刘雅杰 梁振辉 刘兴 袁利静

刘雅杰, 梁振辉, 刘兴, 袁利静. 十氢萘选择性开环反应的研究进展[J]. 燃料化学学报(中英文), 2022, 50(5): 576-582. doi: 10.1016/S1872-5813(21)60186-X
引用本文: 刘雅杰, 梁振辉, 刘兴, 袁利静. 十氢萘选择性开环反应的研究进展[J]. 燃料化学学报(中英文), 2022, 50(5): 576-582. doi: 10.1016/S1872-5813(21)60186-X
LIU Ya-jie, LIANG Zhen-hui, LIU Xing, YUAN Li-jing. Progress of selective ring-opening reaction of decalin[J]. Journal of Fuel Chemistry and Technology, 2022, 50(5): 576-582. doi: 10.1016/S1872-5813(21)60186-X
Citation: LIU Ya-jie, LIANG Zhen-hui, LIU Xing, YUAN Li-jing. Progress of selective ring-opening reaction of decalin[J]. Journal of Fuel Chemistry and Technology, 2022, 50(5): 576-582. doi: 10.1016/S1872-5813(21)60186-X

十氢萘选择性开环反应的研究进展

doi: 10.1016/S1872-5813(21)60186-X
基金项目: 山西省揭榜招标项目(20201101012)和山西省青年科技研究基金(201901D211584)资助
详细信息
    通讯作者:

    Tel: +86-15634971059, E-mail: yuanlijing@sxicc.ac.cn

  • 中图分类号: O643.3

Progress of selective ring-opening reaction of decalin

Funds: The project was supported by the Shanxi Science and Technology Department (20201101012) and Shanxi Province Science Foundation for Yout (201901D211584).
  • 摘要: 本文介绍了顺式和反式十氢萘的分子结构和反应特性,系统分析了十氢萘在不同催化体系下选择性开环的反应机理,包括在单功能酸性催化剂上的碳正离子机理,在单功能金属催化剂上的氢解反应机理以及基于酸性-金属双功能催化剂的双功能开环反应机理。总结了反应温度、载体酸性和分子筛孔径等工艺条件对十氢萘选择性开环反应性能的影响。最后提出了当前研究存在的不足之处,展望了亟需开展的研究课题。
  • FIG. 1525.  FIG. 1525.

    FIG. 1525.  FIG. 1525.

    图  1  十氢萘结构式(a)反式十氢萘,(b)顺式十氢萘

    Figure  1  Spatial structure of decalin (a): trans-decalin; (b): cis-decalin

    图  2  基于碳正离子机理的十氢萘选择性开环反应路径

    Figure  2  Proposed reaction path of selective ring-opening reaction of decalin based on the carbocation mechanism

    图  3  基于不同开环机理的十氢萘反应路径

    Figure  3  Reaction pathways of decalin under different ring-opening mechanisms(a): dicarbene mechanism; (b): metallocyclobutane mechanism

    图  4  十氢萘在双功能催化剂上的反应路径示意图M代表金属活性位,B代表B酸位

    Figure  4  Reaction pathway of decalin over a bifunctional catalyst, M stands for metal active sites, B stands for B acid sites

    图  5  基于GC × GC-MS技术考察Ir催化剂对十氢萘开环选择性及耐硫性的影响[20]

    Figure  5  Effect of Ir catalyst on the decalin ring-opening selectivity and sulfur tolerance[20]

    (with permission from ACS Publications)

    图  6  十氢萘在Ir(Pt)/Cs-β催化剂上转化率为30%−40%时开环产物分布[21]

    Figure  6  Distribution of ring-opening products when the conversion rate of decalin on Ir(Pt)/Cs-β catalyst is 30%−40%[21]

    (a) Single ring-opening product distribution; (b) Double ring-opening product distribution(with permission from Royal Society of Chemistry)

    表  1  部分典型异构产物和开环产物的十六烷值

    Table  1  Cetane number of some typical isomerized products and ring-opening products

    IsomersOne-ring-opening productsTwo-ring-opening products
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出版历程
  • 收稿日期:  2021-10-09
  • 修回日期:  2021-12-07
  • 录用日期:  2021-12-07
  • 网络出版日期:  2021-12-20
  • 刊出日期:  2022-05-24

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