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面向CH4-CO2重整反应的生物质炭基催化剂载体制备工艺的研究进展

陈庆明 刘大伟 吕随明 张维祥 赵青鹏 张宁 徐龙 马晓迅

陈庆明, 刘大伟, 吕随明, 张维祥, 赵青鹏, 张宁, 徐龙, 马晓迅. 面向CH4-CO2重整反应的生物质炭基催化剂载体制备工艺的研究进展[J]. 燃料化学学报. doi: 10.1016/S1872-5813(22)60038-0
引用本文: 陈庆明, 刘大伟, 吕随明, 张维祥, 赵青鹏, 张宁, 徐龙, 马晓迅. 面向CH4-CO2重整反应的生物质炭基催化剂载体制备工艺的研究进展[J]. 燃料化学学报. doi: 10.1016/S1872-5813(22)60038-0
CHEN Qing-ming, LIU Da-wei, LÜ Sui-ming, ZHANG Wei-xiang, ZHAO Qing-peng, ZHANG Ning, XU Long, MA Xiao-xun. Research progress on the preparation process of biochar-based catalyst support for dry reforming of methane[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(22)60038-0
Citation: CHEN Qing-ming, LIU Da-wei, LÜ Sui-ming, ZHANG Wei-xiang, ZHAO Qing-peng, ZHANG Ning, XU Long, MA Xiao-xun. Research progress on the preparation process of biochar-based catalyst support for dry reforming of methane[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(22)60038-0

面向CH4-CO2重整反应的生物质炭基催化剂载体制备工艺的研究进展

doi: 10.1016/S1872-5813(22)60038-0
基金项目: 国家自然科学基金(22008197),陕西省重点研发计划(2018ZDXMGY-167,2022QCY-LL-69),陕西省教育厅服务地方专项计划项目(17JF029),中国博士后科学基金(2021M702649)和咸阳市科学技术研究计划(2021ZDYF-NY-0017)资助
详细信息
    通讯作者:

    E-mail: dwliu@nwu.edu.cn

    longxuxulong@163.com

  • 中图分类号: TQ426.65

Research progress on the preparation process of biochar-based catalyst support for dry reforming of methane

Funds: The project was supported by the National Natural Science Foundation of China (22008197), the Key R&D Program of Shaanxi Province (2018ZDXMGY-167, 2022QCY-LL-69), Shaanxi Provincial Education Department Serves Local Special Project (17JF029), Project funded by China Postdoctoral Science Foundation (2021M702649), Scientific and Technological Research Program of Xianyang (2021ZDYF-NY-0017)
  • 摘要: CH4干重整(DRM)技术能够同时将CH4和CO2两种温室气体转化为合成气,以实现温室气体减排及资源化利用,因此,越来越受到研究者的青睐。生物质炭具有高比表面积、发达的孔隙结构、高的热稳定性、优异的耐酸碱性、丰富的碱/碱土金属和含氧官能团含量以及成本低廉等优点,其应用于DRM,可以适用于页岩气、油田伴生气、焦炉煤气和煤层气等不同的重整体系,省去部分废气的脱硫等预处理过程,具有重要的工业应用前景。本工作对用于DRM的生物质炭基催化剂载体的制备工艺进行了总结。综述了不同的炭化工艺及其对生物质炭产量和性质的影响;介绍了生物质炭的理化性质对重整反应的影响及影响理化性质的因素;分析了不同的活化方法对生物质炭基催化剂催化性能的影响;并对影响催化剂稳定性的碳消耗进行了介绍。
  • 图  1  温室气体排放概况 (a) 和来源 (b) [4]

    Figure  1  Overview (a) and sources (b) of greenhouse gas emissions[4]

    图  2  不同炭化工艺的反应器示意图[4043]

    Figure  2  Reactors for different carbonization processes[4043](with permission from Elsevier)

    图  3  不同炭化温度对生物质炭结构的影响[7274]

    Figure  3  Different carbonization temperatures effect on the structure of bio-char[7274](with permission from Springer Nature and Elsevier)

    图  4  各个阶段Co-Ca/AC催化剂涉及的反应机理[86]

    Figure  4  Reaction mechanism involved in Co-Ca/AC catalysts at various stages[86](with permission from Elsevier)

    图  5  生物质炭表面的含氧官能团[17,104]

    Figure  5  Oxygen-containing functional groups on the surface of bio-char[17,104](with permission from Elsevier)

    图  6  生物质炭活化[108-113]

    Figure  6  Bio-char activation[108-113](with permission from Elsevier)

    图  7  (a)LBC和(b)KOH-LBC的 SEM 照片[154]

    Figure  7  SEM images of (a) LBC and (b) KOH-LBC[154](with permission from Elsevier)

    图  8  两种掺N方法制备流程[167]

    Figure  8  Preparation process of two nitrogen doping methods[167]Y-NC: in-situ doping; H-NC: post-processing doping(with permission from Elsevier)

    表  1  甲烷干重整过程中涉及的反应

    Table  1  Reactions involved in the dry reforming of methane

    ReactionReaction equation$\Delta {H}_{298\;{\rm{K} } }/({\rm{ kJ} }\cdot { {\rm{mol} } }^{-1})$Number
    Main reaction
    Dry reforming of methane${{\rm{CH}}}_{4}+{{\rm{CO}}}_{2}\to 2{{\rm{H}}}_{2}+2{\rm{CO}}$+274.3(1)
    Side reaction
    Reverse water gas shift${{\rm{CO}}}_{2}+{{\rm{H}}}_{2}\leftrightarrow {{\rm{H}}}_{2}{\rm{O}}+{\rm{CO}}$–41(2)
    Decomposition of methane${{\rm{CH}}}_{4}\to 2{{\rm{H}}}_{2}+{\rm{C}}$+75(3)
    Disproportionation of CO$2{\rm{CO}}\leftrightarrow {{\rm{CO}}}_{2}+{\rm{C}}$–172.4(4)
    Hydrogenation of CO2${ {\rm{CO} } }_{2}+2{ {\rm{H} } }_{2}\to {2{\rm{H} } }_{2}{\rm{O} }+{\rm{C}}$–90(5)
    Hydrogenation of CO${\rm{CO}}+{{\rm{H}}}_{2}\to {\rm{C}}+{{\rm{H}}}_{2}{\rm{O}}$–131(6)
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  • 收稿日期:  2022-03-25
  • 录用日期:  2022-05-26
  • 修回日期:  2022-05-25
  • 网络出版日期:  2022-06-23

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