Application of metal-organic frameworks in CO<sub>2</sub> hydrogenation

ZHOU Cheng; NAN Yong-yong; ZHA Fei; TIAN Hai-feng; TANG Xiao-hua; CHANG Yue

doi:10.1016/S1872-5813(21)60097-X

Volume 49 Issue 10

Oct. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(10): 1444-1457

ZHOU Cheng, NAN Yong-yong, ZHA Fei, TIAN Hai-feng, TANG Xiao-hua, CHANG Yue. Application of metal-organic frameworks in CO2 hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2021, 49(10): 1444-1457. doi: 10.1016/S1872-5813(21)60097-X

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ZHOU Cheng, NAN Yong-yong, ZHA Fei, TIAN Hai-feng, TANG Xiao-hua, CHANG Yue. Application of metal-organic frameworks in CO₂ hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2021, 49(10): 1444-1457. doi: 10.1016/S1872-5813(21)60097-X

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Application of metal-organic frameworks in CO₂ hydrogenation

doi: 10.1016/S1872-5813(21)60097-X

1.
Northwest Normal University Chemistry and Chemical Engineering, Gansu 730070, China
2.
Jingyuan Coal Industry Group Liuhua Chemical Co., Ltd, Gansu 730900, China

Funds: The project was supported by National Natural Science Foundation of China (21865031)

Received Date: 2021-03-16
Rev Recd Date: 2021-04-21

Available Online: 2021-05-18

Publish Date: 2021-10-30

Abstract

Abstract

The dramatic increase in atmospheric CO₂ concentrations has attracted people's attention, and many strategies have been developed to convert CO₂ into high-value chemicals. Metal-organic frameworks (MOFs), as a class of versatile materials, can be used in the CO₂ capture and conversion because of their unique porosity, large specific surface area, rich pore structure, multiple active centers, good stability and recyclability. Various functional nanomaterials have been designed and synthesized based on metal organic framework (MOF) of crystalline porous materials to meet these challenges. Herein, in this review, the latest processes of MOFs in field the of CO₂ hydrogenation to carbon monoxide, methane, formic acid, methanol and olefins are summarized, and the synthesis methods of catalysts based on MOFs and the reasons for their high catalytic activity are analyzed. Besides, a brief introduction to improve the catalytic activity of the new MOF material and explore the feasible strategies for CO₂ conversion are advised. Finally, the paper discusses the main challenges and opportunities of MOF-type catalysts in CO₂ chemical conversion, and presents a brief outlook on further developments in this research area.
- metal-organic frameworks,
- CO₂ hydrogenation,
- catalysis,
- research progress

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References(63)

References

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