Morphology effect of nano-hydroxyapatite as support for loading Ni in methane dry reforming

WANG Yan-bo; HE Lei; LI Wen-cui

doi:10.1016/S1872-5813(23)60332-9

Volume 51 Issue 7

Jul. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(7): 977-986

WANG Yan-bo, HE Lei, LI Wen-cui. Morphology effect of nano-hydroxyapatite as support for loading Ni in methane dry reforming[J]. Journal of Fuel Chemistry and Technology, 2023, 51(7): 977-986. doi: 10.1016/S1872-5813(23)60332-9

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WANG Yan-bo, HE Lei, LI Wen-cui. Morphology effect of nano-hydroxyapatite as support for loading Ni in methane dry reforming[J]. Journal of Fuel Chemistry and Technology, 2023, 51(7): 977-986. doi: 10.1016/S1872-5813(23)60332-9

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Morphology effect of nano-hydroxyapatite as support for loading Ni in methane dry reforming

doi: 10.1016/S1872-5813(23)60332-9

State Key Laboratory of Fine Chemicals, Liaoning Key Laboratory for Catalytic Conversion Carbon Resources, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Received Date: 2022-11-07
Accepted Date: 2022-12-25
Rev Recd Date: 2022-12-24

Available Online: 2023-01-10

Publish Date: 2023-07-01

Abstract

Abstract

In this paper, hydroxyapatite (HAP) with nanorod, nanosheet and nanowire morphologies were synthesized with different surface Ca, O and P distributions. After loading 1.25% of nickel, Ni/HAP-R, Ni/HAP-S and Ni/HAP-W catalysts were obtained and applied for MDR. Among them, the Ni/HAP-R catalyst showed the best performance. The geometric structure, electronic properties and surface basicity of the catalyst were characterized by XRD, N₂ sorption, FT-IR, XPS and CO₂-TPD. It proved that HAP-R possessed the larges surface area, thus beneficial for Ni dispersion to obtain high MDR activity. Meanwhile, it was rich in Ca-O-P which could accelerate the CO₂ activation for coke elimination. TPSR experiments further confirmed that the deep cracking of methane on Ni/HAP-R catalyst was inhibited. However, it could be accelerated in the presence of CO₂ to produce CO and H₂. In this case, Ni/HAP-R catalyst showed excellent anti-coking performance. This study provides inspiration for the design and synthesis of highly stable heterogeneous catalysts.
- hydroxyapatite,
- nickel,
- methane dry reforming,
- morphology effect

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References(30)

References

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