Synthesis of polyethylnaphthalenes base oil catalyzed by ionic liquid and its lubricating properties

LI Yuan-yuan; TANG Qiong; CHEN Chen; ZUO Zhi-jun; LIU Lei; DONG Jin-xiang

doi:10.19906/j.cnki.JFCT.2022087

Volume 51 Issue 5

May 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(5): 635-643

LI Yuan-yuan, TANG Qiong, CHEN Chen, ZUO Zhi-jun, LIU Lei, DONG Jin-xiang. Synthesis of polyethylnaphthalenes base oil catalyzed by ionic liquid and its lubricating properties[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 635-643. doi: 10.19906/j.cnki.JFCT.2022087

Citation:

LI Yuan-yuan, TANG Qiong, CHEN Chen, ZUO Zhi-jun, LIU Lei, DONG Jin-xiang. Synthesis of polyethylnaphthalenes base oil catalyzed by ionic liquid and its lubricating properties[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 635-643. doi: 10.19906/j.cnki.JFCT.2022087

Citation:

LI Yuan-yuan, TANG Qiong, CHEN Chen, ZUO Zhi-jun, LIU Lei, DONG Jin-xiang. Synthesis of polyethylnaphthalenes base oil catalyzed by ionic liquid and its lubricating properties[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 635-643. doi: 10.19906/j.cnki.JFCT.2022087

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Synthesis of polyethylnaphthalenes base oil catalyzed by ionic liquid and its lubricating properties

doi: 10.19906/j.cnki.JFCT.2022087

1.
College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China
2.
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan 030024, China

Funds: The project was supported by National Natural Science Foundation of China (U1910202, 21978794), the Key Research and Development Project of Shanxi Province (202102090301005), Shanxi Province Science Foundation for Youths (202103021223064)

Received Date: 2022-10-06
Accepted Date: 2022-11-08
Rev Recd Date: 2022-11-06

Available Online: 2022-11-16

Publish Date: 2023-05-15

Abstract

Abstract

Polyethylnaphthalenes lubricating base oil were synthesized by alkylation of cooking naphthalene with ethylene using organic ammonium salt/metal chloride ionic liquid as catalyst. It was found that the AlCl₃/Et₃NHCl ionic liquid showed better active in the naphthalene alkylation with ethylene by regulating the composition of anions and cations in ionic liquids. Two different compositions of polyethylnaphthalenes base oils PEN-1 (92.9% of mono- and di-ethylnaphthalenes) and PEN-2 (91.3% of polyethylnaphthalenes) were synthesized by optimizing reaction conditions (catalyst dosage, reaction time and temperature). The lubrication test results showed that PEN-2 base oil with a large number of alkyl side chains exhibited good tribological properties and showed better wear resistance than the commercial alkylnaphthalenes base oil AN5, showing a good application prospect.
- naphthalene,
- ionic liquids,
- alkylation,
- synthetic lubricating base oil,
- lubricating properties

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References(41)

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