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摘要: 通过研究钛硅分子筛TS-1在异丙醇溶剂中催化丙烯与H2O2的连续环氧化过程,考察催化剂的活性变化情况;并将失活的催化剂进行再生,活性评价表明再生后催化剂的活性基本恢复。用SEM, N2物理吸附,TG,XRD,IR和NH3-TPD等多种方法对新鲜、失活和再生后的催化剂进行表征,结果显示:催化剂失活是大分子反应副产物堵塞孔道引起的暂时性失活和部分钛流失引起的永久失活共同作用的结果。
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关键词:
- 钛硅分子筛(TS-1) /
- 丙烯环氧化 /
- 环氧丙烷 /
- 失活
Abstract: The relationship of TS-1 activity with time was investigated in a continuous epoxidation reactor, and the function curve of time to TS-1 activity was observed. The used catalyst was regenerated by calcinations.The results of the activity tests indicated that the activity of the regenerated catalyst was almost recovered.The fresh, the deactivated and the regenerated were characterized by a number of techniques such as SEM, N2 physical adsorption, TG, XRD, IR and NH3-PD.On the basis of the characterization, the mechanism of the deactivation was proposed.The deactivation of TS-1 can be attributed to the deposition of slowly diffusing organic by-products inside TS-1 channels. Additionally, small amount of titanium may be leached out from the framework of the catalyst.-
Key words:
- titanium silicalite (TS-1) /
- epoxidation of propylene /
- propylene oxide /
- deactivation
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