Preferential oxidation of CO in H2-rich stream on non-noble metal catalyst
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摘要: 以Co和Ni为催化剂活性组分、活性炭为载体,通过饱和浸渍法制得非贵金属催化剂,采用XRD、SEM和TPD对催化剂性能进行表征,考察了该催化剂用于富氢气中CO选择性氧化活性及H2O或/和CO2对催化性能的影响。研究结果表明,催化剂以NiO和高分散的Co3O4为主要物相,催化剂吸附O2的能力随着金属氧化物负载量的增加而增加,且催化剂对O2分子的吸附能力明显强于CO2分子。金属氧化物负载量为35%的催化剂表现出较高的CO选择性氧化活性和选择性,在低于473K时O2氧化选择性达50%以上,此时可将CO浓度降到40×10-6以下,达到燃料电池对氢燃料气的要求。同时,催化剂表现出较强的抗水蒸气和CO2的能力。Abstract: A non-noble metal catalyst was prepared by loading cobalt and nickel on activated carbon through saturated impregnation; it was characterized by XRD, SEM and TPD and used in preferential oxidation of CO in H2-rich stream. The influence of water vapor and/or CO2 on the performance of this non-noble metal catalyst was also examined. The results indicted that NiO and finely dispersed Co3O4 are formed in the catalyst; the catalyst exhibits stronger adsorption ability to O2 than to CO2 and the adsorption ability to O2 increases with the loading of metal oxides. The non-noble metal catalyst exhibits high activity and selectivity in the preferential oxidation of CO. Over the catalyst CN250(35) with a metal oxide loading of 35%, CO concentration can be decreased to 40×10-6 at 433K~473K; meanwhile, the selectivity of O2 consumed by CO oxidation exceeds 50% at 473K. Moreover, the non-noble metal catalyst exhibits good resistance to water vapor and CO2 in the stream. These suggest that current catalyst may meet the requests in purification of H2 feed for PEMFC fuel cell application.
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