煤及其拔头半焦的燃烧反应特性研究

于广锁; 祝庆瑞; 许慎启; 霍威; 周志杰

煤及其拔头半焦的燃烧反应特性研究

华东理工大学煤气化教育部重点实验室, 上海 200237

基金项目: 国家自然科学基金(20876048);国家重点基础研究发展规划(973计划,2010CB227006)。

详细信息

通讯作者:
于广锁(1970-), 教授, 从事煤清洁利用研究, Tel: 021-64252974, Fax: 021-64251312, E-mail: gsyu@ecust.edu.cn。

中图分类号: TQ534
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- 被引次数: 0
出版历程
- 收稿日期: 2011-07-18
- 修回日期: 2011-10-13
- 刊出日期: 2012-05-31

Combustion characteristics of coal and coal char from coal topping process

Key Laboratory of Ministry of Education for Coal Gasification, East China University of Science and Technology, Shanghai 200237, China

Funds: 国家自然科学基金(20876048);国家重点基础研究发展规划(973计划,2010CB227006)。

摘要

摘要: 采用热天平研究了贵州褐煤、三江原煤及其拔头半焦的燃烧行为,考察了粒径和升温速率对样品着火点和燃烧稳定性的影响。减小样品的粒径可显著降低样品的着火点,改善样品的燃烧性能,在粒径100～120目和升温速率25 ℃/min下,样品的燃烧稳定性最好。根据Coats-Redfern方法求解燃烧反应动力学参数。燃烧反应动力学分析表明,三种样品的热天平燃烧反应均为一级反应,并得到了实验样品的燃烧反应动力学参数,表观活化能E和指前因子A。贵州褐煤的活化能为100.0～163.6 kJ/mol,三江原煤的活化能为73.4～161.2 kJ/mol,三江煤焦的活化能为68.3～178.1 kJ/mol。
- 粒径 /
- 燃烧 /
- 着火点 /
- 热重分析
Abstract: A systematic research on the combustion characteristics of Guizhou lignite, Sanjiang coal and Sanjiang char had been done using STA 409C Netzh- thermogravimetric analyzer. The effects of particle diameter and heating rate on maximum mass loss rate, ignition point and combustibility were analyzed. The decrease of particle diameter can reduce the ignition point and improve the combustibility. When particle size is 100～120 mesh and heating rate is 25 ℃/min, the combustibility of samples is the best. The combustion reactions are one-order reaction and kinetics parameters (activation energy E and frequency factor A) were obtained by the method of Coats-Redfern basing on experimental data. Activation energy of Guizhou lignite, Sanjiang coal and Sanjiang char are 100.0～163.6 kJ/mol, 73.4～161.2 kJ/mol, 68.3～178.1 kJ/mol.
- particle diameter /
- combustion /
- ignition point /
- thermogravimetric analysis

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