龙口页岩油中含氧化合物的分析与鉴定

耿层层; 李术元; 何继来

龙口页岩油中含氧化合物的分析与鉴定

1.
中国石油大学(北京) 重质油国家重点实验室, 北京 102249;
2.
龙口矿业集团有限公司, 山东龙口 265700

详细信息

通讯作者:
李术元, 教授, 从事油页岩、煤、油砂方面研究, Tel: 010-89733287, E-mail: syli@cup.edu.cn。

中图分类号: O657
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出版历程
- 收稿日期: 2011-07-23
- 修回日期: 2011-10-18
- 刊出日期: 2012-05-31

Determination and indentification of oxygen-containing compounds in Longkou shale oil

1.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum(Beijing), Beijing 102249, China;
2.
Longkou Mining Processing Group Ltd, Longkou 265700, China

摘要

摘要: 用酸碱分离和萃取色谱分离相结合的方法将龙口页岩油分离为酸性组分、碱性组分和五个中性组分(饱和烃、芳香烃、含氮化合物、含氧化合物1、含氧化合物2)。采用GC-MS和负离子ESI FT-ICR MS鉴定了龙口页岩油中酸性组分、中性组分4和中性组分5中含氧化合物的组成。GC-MS分析结果表明,龙口页岩油酸性组分含氧化合物主要包括苯酚类、茚满酚类、萘酚类、联苯酚类、芴酚类、菲酚类,以及C_5～16烷酸;龙口页岩油中性组分4和中性组分5中含氧化合物主要包括C_9～32脂肪酮和酯类化合物。FT-ICR MS分析结果表明,龙口页岩油中含氧化合物主要有O₁、O₂、O₃、N₁O₁、N₁O₂类化合物,其中,O₁和O₂类化合物种类较多。龙口页岩油重均相对分子质量集中在150～600 Da,说明龙口页岩油是由小分子化合物组成的。其表现出来的某些大分子化合物的性质,是由小分子化合物通过范德华力或氢键聚合在一起而形成的。龙口页岩油中O₁、O₂、O₃类化合物中DBE主要分布在1和4,说明龙口页岩油中O₁、O₂、O₃类化合物不饱和度和缩合度较低,因此,龙口页岩油是生物降解程度较低的油。
- 页岩油 /
- 含氧化合物 /
- GC-MS /
- FT-ICR MS
Abstract: The methods of acid-base separation and extraction-chromatography were used to separate Longkou shale oil into acid fractions, basic fractions and five neutral fractions. The molecular structure and mass distribution of oxygen compounds in Longkou shale oil were investigated using gas chromatography-mass spectrometry (GC-MS) and negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). The results of GC-MS show that the oxygen compounds in acid fractions involve phenols, indanols, naphthols, phenylphenols, fluorenols, phenanthrenols, and carboxylic acids ranging from C₅ to C₁₆. The oxygen compounds in neutral fraction 4 and 5 involve aliphatic ketones ranging from C₉ to C₃₂ and lipid compounds. The results of ESI FT-ICR MS show that the class species of O₁, O₂, O₃, N₁O₁, N₁O₂ are found. The O₁ and O₂ have the higher ion intensity among the species in shale oil. The m/z range of shale oil is from 150 to 600. It is obviously that Longkou shale oil is mainly composed of small molecular compounds which are polymerized by Van der Waals force and hydrogen bonding. The properties of shale oil are similar to macromolecular compounds. Longkou shale oil has O₁, O₂, O₃ compounds mainly with DBE of 1 and 4, suggesting that Longkou shale oil can be regarded as a less biodegraded oil.
- shale oil /
- oxygen compounds /
- GC-MS /
- FT-ICR MS

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