Characteristics of Yumen heavy oil components and its effect on wax deposition behavior
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摘要: 为了研究稠油不同组分的特征及其相互作用,利用柱层色谱分离法、傅里叶红外光谱、差示扫描量热法(DSC)和偏光显微分析等表征方法及手段,对采自玉门油田的稠油样品进行了组分分离、分析,并对饱和烃组分结蜡行为的影响进行了研究。结果表明,稠油各组分相互作用可以有效抑制蜡晶的析出。饱和烃组分(A1)中分别加入其他不同极性组分后,其结蜡行为与原油原始状态差异较大;A1的析蜡点、析蜡峰温和析蜡量均有所降低。偏光显微分析发现胶质沥青质组分使A1冷却结晶时的蜡晶颗粒数增多,尺寸相对减小,可以减弱蜡晶之间的联结强度,削弱蜡晶缔合而形成大块蜡晶聚集体的倾向。Abstract: The characteristics of components of heavy oil, their interactions and effects on the wax deposition behavior of heavy oil from Yumen oil field were studied by using chromatogram separation, Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC) and optical microscope. The results indicate that the interaction between the components can inhibit the precipitation of wax crystal effectively. The behaviors of A1 with different polarity components added are quite different from that of the heavy oil. The wax-appearing temperature, the peak temperature of wax-precipitation and the percentage of precipitated wax are decreased. The optical microscope analysis shows that the addition of resin and asphaltene to A1 can increase the number of wax crystal particles and decrease their dimensions during the cooling crystallization process, which can prevent the particles from contacting and crosslinking each other to form bulk wax crystal aggregation.
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Key words:
- heavy oil /
- saturated hydrocarbon /
- colloid /
- asphaltene /
- wax deposition
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GANG C, YING T, JIE Z. Synthesis and application of polyaminoamide as paraffin inhibitor from vegetable oil[J]. Chem Cent J, 2011, 5: 82-86. JIE Z, YAN S, YING T, GANG C. Wax precipitation research of crude oil by differential scanning calorimeter[J]. Adv Mat Res, 2012, 524-527: 1730-1733. 梁文杰. 石油化学(第2版)[M]. 北京: 中国石油大学出版社, 2009. (LIANG Wen-jie. Petroleum chemistry, 2nd ed[M]. Beijing: China University of Petroleum Press, 2009.) 蒋庆哲, 宋昭峥, 葛际江, 柯明, 赵密福. 原油组分与降凝剂相互作用[J]. 西南石油学院学报, 2006, 28(1): 59-64. (JIANG Qing-zhe, SONG Shao-zheng, GE Ji-jiang, KE Ming, ZHAO Mi-fu. Interaction between pour point depressant and components of crude[J]. Journal of Southwest Petroleum Institute, 2006, 28(1): 59-64.) QIAN J W, QI G R, DING X Z, YANG S L. Assessment of polymer flow improvers for crude oil by viscometry[J]. Fuel, 1996, 75(3): 307-312. ELSHARKAWY A M. Determination and prediction of wax deposition from Kuwaiti crude oils[C]//Latin american and caribbean petroleum engineering conference. SPE 54006, 1999. ESCOBEDO J. Viscometric principles of onsets of colloidal asphaltene flocculation in paraffinic oils and asphaltene micellization in aromatics[J]. SPE Production & Facilities, 1997, 12(2): 116-122. 顾欢, 路遥, 尚绪柱, 张海永. 原油成分分析方法的研究进展[J]. 理化检验(化学分册), 2011, 47(4): 496-500. (GU Huan, LU Yao, SHANG Xu-zhu, ZHANG Hai-yong. Recent advances on researches of method for componental analysis of crude oil[J]. Physical Testing and Chemical Analysis Part B (Chemical Analysis), 2011, 47(4): 496-500.) SUTTON P A, LEWIS C A, ROWLAND S J. Isolation of individual hydrocarbons from the unresolved complex hydrocarbon mixture of a biodegraded crude oil using preparative capillary gas chromatography[J]. Org geochem, 2005, 36(6): 963-970. 林壬子, 张敏. 油藏地球化学进展[M]. 西安: 陕西科学技术出版社, 1996: 169-184. (LIN Ren-zi, ZHANG Min. Advances in reservoir geochemistry[M]. Xi'an: Shaanxi Science and Technology Press, 1996: 169-184.) SY/T0520-2008, 原油粘度测定旋转粘度计平衡法[S]. (SY/T0520-2008, Viscosity determination of crude petroleum. Equilibrium method by rotational viscometer[S].) SY/T0541-2009, 原油凝点测定法[S]. (SY/T0541-2009, Test method for gel point of crude oils[S].) GB/T13377-2010, 原油和液体或固体石油产品密度或相对密度的测定, 毛细管塞比重瓶和带刻度双毛细管比重瓶法[S]. (GB/T13377-2010, Crude petroleum and liquid or solid petroleum products. Determination of density or relative density. Capillary stoppered pyknometer and graduated bicapillary pyknometer methods[S].) 张洁, 汤颖, 孙文娟. 原油分析新方法—TGA 曲线法及其应用. 油田化学, 2012, 29(3): 357-360. (ZHANG Jie, TANG Ying, SUN Wen-juan. A new analysis method for crude oil-TGA method and its application[J]. Oilfield Chemistry, 2012, 29(3): 357-360.) 庞万忠, 王彪, 陈立滇. 大庆、大港原油对降凝剂的感受性及其非烃组份对降凝效果的影响[J]. 石油学报, 1995, 16(2): 125-134. (PANG Wan-zhong, WANG Biao, CHEN Li-dian. The responses of Daqing and Dagang crudes to pour point depressants and the effect of non-hydrocarbon components[J]. Acta Petrolei Sinica, 1995, 16(2): 125-134. ) ZHANG F S, OUYANG J, HONG L, FENG X F, ZHANG H B. Inhibition of deposits of high-molecular weight paraffins in oil wells[J]. Chem Technol Fuels Oils, 2011, 47(1): 53-57. 李鸿英, 黄启玉, 张帆, 张劲军. 用差示扫描量热法确定原油的含蜡量[J]. 石油大学学报, 2003, 27(1): 60-62. (LI Hong-ying, HUANG Qi-yu, ZHANG Fan, ZHANG Jing-jun. Determination of wax content in crude oil using differential scanning calorimetry[J]. Journal of the University of Petroleum, China, 2003, 27(1): 60-62.) 范恩荣. 聚合物沥青复合材料开发方向[J]. 玻璃钢/复合材料, 1997, (4): 42-44. (FAN En-rong. Developing direction of polymer pitch composites[J]. Fiber Reinforced Plastics/Composites, 1997, (4): 42-44.) 樊西惊. 石油胶态分散体的稳定[J]. 油田化学, 1999, 16(1): 72-76. (FAN Xi-jing. Stability of colloid-type petroleum systems[J]. Oilfield Chemistry, 1999, 16(1): 72-76.) 李鸿英, 张劲军, 高鹏. 蜡晶形态、结构与含蜡原油流变性的关系[J]. 油气储运, 2004, 23(9): 19-23. (LI Hong-ying, ZHANG Jing-jun, GAO Peng. Correlation between wax crystal morphology and crude rheology[J]. Oil & Gas Storage and Transportation, 2004, 23(9): 19-23.) 程亮, 李纪晖, 孙晨. 稠油中胶质稳定分散沥青质的作用研究[J]. 西安石油大学学报, 2011, 26(1): 64-69. (CHENG Liang, LI Ji-hui, SUN Chen. Dispersing effect of resins on asphaltenes in crude oil[J]. Journal of Xi'an Shiyou University (Natural Science Edition), 2011, 26(1): 64-69.) 李传宪, 张春光, 孙德军. 降凝剂与原油组分相互作用的影响因素及降凝剂发展[J]. 化学通报, 2002, 65(12): 819-823. (LI Chuan-xian, ZHANG Chun-guang, SUN De-jun. The development of PPD and the interactions between PPD and composition of crude oil[J]. Chemistry, 2011, 26(12): 819-823.) GROCKER M E, MARCHIN L M. Wettability and adsorption characteristics of crude oil asphaltene and polar fractions[J]. J Petrol Technol, 1998, 40(4): 470-474. 赵凤兰, 鄢捷年. 沥青质沉积引起的储层损害与对策[J]. 油田化学, 2002, 19(4): 367-372. (ZHAO Feng-lan, YAN Jie-nian. Formation damage induced by asphaltene deposition and measures for damage prevention and removal[J]. Oilfield Chemistry, 2002, 19(4): 367-372.) 张红, 沈本贤. 蜡晶形态结构对原油降凝的影响[J]. 石油学报(石油加工), 2006, 22(5): 74-79. (ZHANG Hong, SHEN Ben-xian. Effect of wax crystal morphology on the pour point decline of crude oil[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2006, 22(5): 74-79.)
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