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玉门稠油组分特征及其对结蜡行为的影响

苏慧君 陈刚 栗菁 李小龙 张洁

苏慧君, 陈刚, 栗菁, 李小龙, 张洁. 玉门稠油组分特征及其对结蜡行为的影响[J]. 燃料化学学报(中英文), 2014, 42(02): 187-192.
引用本文: 苏慧君, 陈刚, 栗菁, 李小龙, 张洁. 玉门稠油组分特征及其对结蜡行为的影响[J]. 燃料化学学报(中英文), 2014, 42(02): 187-192.
SU Hui-jun, CHEN Gang, LI Jing, LI Xiao-long, ZHANG Jie. Characteristics of Yumen heavy oil components and its effect on wax deposition behavior[J]. Journal of Fuel Chemistry and Technology, 2014, 42(02): 187-192.
Citation: SU Hui-jun, CHEN Gang, LI Jing, LI Xiao-long, ZHANG Jie. Characteristics of Yumen heavy oil components and its effect on wax deposition behavior[J]. Journal of Fuel Chemistry and Technology, 2014, 42(02): 187-192.

玉门稠油组分特征及其对结蜡行为的影响

基金项目: 陕西省科技计划项目(2012KJXX-40);陕西省教育厅科研计划项目(2013JK0647)。
详细信息
    通讯作者:

    陈刚(1977- ),男,副教授,研究方向为油田助剂合成与应用,Tel:029-88382693;E-mail:gangchen@xsyu.edu.cn。

  • 中图分类号: TE345

Characteristics of Yumen heavy oil components and its effect on wax deposition behavior

  • 摘要: 为了研究稠油不同组分的特征及其相互作用,利用柱层色谱分离法、傅里叶红外光谱、差示扫描量热法(DSC)和偏光显微分析等表征方法及手段,对采自玉门油田的稠油样品进行了组分分离、分析,并对饱和烃组分结蜡行为的影响进行了研究。结果表明,稠油各组分相互作用可以有效抑制蜡晶的析出。饱和烃组分(A1)中分别加入其他不同极性组分后,其结蜡行为与原油原始状态差异较大;A1的析蜡点、析蜡峰温和析蜡量均有所降低。偏光显微分析发现胶质沥青质组分使A1冷却结晶时的蜡晶颗粒数增多,尺寸相对减小,可以减弱蜡晶之间的联结强度,削弱蜡晶缔合而形成大块蜡晶聚集体的倾向。
  • GANG C, YING T, JIE Z. Synthesis and application of polyaminoamide as paraffin inhibitor from vegetable oil[J]. Chem Cent J, 2011, 5: 82-86.
    JIE Z, YAN S, YING T, GANG C. Wax precipitation research of crude oil by differential scanning calorimeter[J]. Adv Mat Res, 2012, 524-527: 1730-1733.
    梁文杰. 石油化学(第2版)[M]. 北京: 中国石油大学出版社, 2009. (LIANG Wen-jie. Petroleum chemistry, 2nd ed[M]. Beijing: China University of Petroleum Press, 2009.)
    蒋庆哲, 宋昭峥, 葛际江, 柯明, 赵密福. 原油组分与降凝剂相互作用[J]. 西南石油学院学报, 2006, 28(1): 59-64. (JIANG Qing-zhe, SONG Shao-zheng, GE Ji-jiang, KE Ming, ZHAO Mi-fu. Interaction between pour point depressant and components of crude[J]. Journal of Southwest Petroleum Institute, 2006, 28(1): 59-64.)
    QIAN J W, QI G R, DING X Z, YANG S L. Assessment of polymer flow improvers for crude oil by viscometry[J]. Fuel, 1996, 75(3): 307-312.
    ELSHARKAWY A M. Determination and prediction of wax deposition from Kuwaiti crude oils[C]//Latin american and caribbean petroleum engineering conference. SPE 54006, 1999.
    ESCOBEDO J. Viscometric principles of onsets of colloidal asphaltene flocculation in paraffinic oils and asphaltene micellization in aromatics[J]. SPE Production & Facilities, 1997, 12(2): 116-122.
    顾欢, 路遥, 尚绪柱, 张海永. 原油成分分析方法的研究进展[J]. 理化检验(化学分册), 2011, 47(4): 496-500. (GU Huan, LU Yao, SHANG Xu-zhu, ZHANG Hai-yong. Recent advances on researches of method for componental analysis of crude oil[J]. Physical Testing and Chemical Analysis Part B (Chemical Analysis), 2011, 47(4): 496-500.)
    SUTTON P A, LEWIS C A, ROWLAND S J. Isolation of individual hydrocarbons from the unresolved complex hydrocarbon mixture of a biodegraded crude oil using preparative capillary gas chromatography[J]. Org geochem, 2005, 36(6): 963-970.
    林壬子, 张敏. 油藏地球化学进展[M]. 西安: 陕西科学技术出版社, 1996: 169-184. (LIN Ren-zi, ZHANG Min. Advances in reservoir geochemistry[M]. Xi'an: Shaanxi Science and Technology Press, 1996: 169-184.)
    SY/T0520-2008, 原油粘度测定旋转粘度计平衡法[S]. (SY/T0520-2008, Viscosity determination of crude petroleum. Equilibrium method by rotational viscometer[S].)
    SY/T0541-2009, 原油凝点测定法[S]. (SY/T0541-2009, Test method for gel point of crude oils[S].)
    GB/T13377-2010, 原油和液体或固体石油产品密度或相对密度的测定, 毛细管塞比重瓶和带刻度双毛细管比重瓶法[S]. (GB/T13377-2010, Crude petroleum and liquid or solid petroleum products. Determination of density or relative density. Capillary stoppered pyknometer and graduated bicapillary pyknometer methods[S].)
    张洁, 汤颖, 孙文娟. 原油分析新方法—TGA 曲线法及其应用. 油田化学, 2012, 29(3): 357-360. (ZHANG Jie, TANG Ying, SUN Wen-juan. A new analysis method for crude oil-TGA method and its application[J]. Oilfield Chemistry, 2012, 29(3): 357-360.)
    庞万忠, 王彪, 陈立滇. 大庆、大港原油对降凝剂的感受性及其非烃组份对降凝效果的影响[J]. 石油学报, 1995, 16(2): 125-134. (PANG Wan-zhong, WANG Biao, CHEN Li-dian. The responses of Daqing and Dagang crudes to pour point depressants and the effect of non-hydrocarbon components[J]. Acta Petrolei Sinica, 1995, 16(2): 125-134. )
    ZHANG F S, OUYANG J, HONG L, FENG X F, ZHANG H B. Inhibition of deposits of high-molecular weight paraffins in oil wells[J]. Chem Technol Fuels Oils, 2011, 47(1): 53-57.
    李鸿英, 黄启玉, 张帆, 张劲军. 用差示扫描量热法确定原油的含蜡量[J]. 石油大学学报, 2003, 27(1): 60-62. (LI Hong-ying, HUANG Qi-yu, ZHANG Fan, ZHANG Jing-jun. Determination of wax content in crude oil using differential scanning calorimetry[J]. Journal of the University of Petroleum, China, 2003, 27(1): 60-62.)
    范恩荣. 聚合物沥青复合材料开发方向[J]. 玻璃钢/复合材料, 1997, (4): 42-44. (FAN En-rong. Developing direction of polymer pitch composites[J]. Fiber Reinforced Plastics/Composites, 1997, (4): 42-44.)
    樊西惊. 石油胶态分散体的稳定[J]. 油田化学, 1999, 16(1): 72-76. (FAN Xi-jing. Stability of colloid-type petroleum systems[J]. Oilfield Chemistry, 1999, 16(1): 72-76.)
    李鸿英, 张劲军, 高鹏. 蜡晶形态、结构与含蜡原油流变性的关系[J]. 油气储运, 2004, 23(9): 19-23. (LI Hong-ying, ZHANG Jing-jun, GAO Peng. Correlation between wax crystal morphology and crude rheology[J]. Oil & Gas Storage and Transportation, 2004, 23(9): 19-23.)
    程亮, 李纪晖, 孙晨. 稠油中胶质稳定分散沥青质的作用研究[J]. 西安石油大学学报, 2011, 26(1): 64-69. (CHENG Liang, LI Ji-hui, SUN Chen. Dispersing effect of resins on asphaltenes in crude oil[J]. Journal of Xi'an Shiyou University (Natural Science Edition), 2011, 26(1): 64-69.)
    李传宪, 张春光, 孙德军. 降凝剂与原油组分相互作用的影响因素及降凝剂发展[J]. 化学通报, 2002, 65(12): 819-823. (LI Chuan-xian, ZHANG Chun-guang, SUN De-jun. The development of PPD and the interactions between PPD and composition of crude oil[J]. Chemistry, 2011, 26(12): 819-823.)
    GROCKER M E, MARCHIN L M. Wettability and adsorption characteristics of crude oil asphaltene and polar fractions[J]. J Petrol Technol, 1998, 40(4): 470-474.
    赵凤兰, 鄢捷年. 沥青质沉积引起的储层损害与对策[J]. 油田化学, 2002, 19(4): 367-372. (ZHAO Feng-lan, YAN Jie-nian. Formation damage induced by asphaltene deposition and measures for damage prevention and removal[J]. Oilfield Chemistry, 2002, 19(4): 367-372.)
    张红, 沈本贤. 蜡晶形态结构对原油降凝的影响[J]. 石油学报(石油加工), 2006, 22(5): 74-79. (ZHANG Hong, SHEN Ben-xian. Effect of wax crystal morphology on the pour point decline of crude oil[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2006, 22(5): 74-79.)
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出版历程
  • 收稿日期:  2013-09-27
  • 修回日期:  2013-11-17
  • 刊出日期:  2014-02-28

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