微量元素与煤有机质的结合关系浅探——以太原西山矿区8号煤层为例

杨建业; 张卫国; 赵洲; 汪广恒

微量元素与煤有机质的结合关系浅探——以太原西山矿区8号煤层为例

1.
西安科技大学材料科学与工程学院, 陕西西安 710054;
2.
西安科技大学地质与环境学院, 陕西西安 710054;
3.
西安科技大学化学与化工学院, 陕西西安 710054

基金项目: 国家自然科学基金（41172143）；教育部博士学科点专项科研基金（20126121110002）；陕西省自然科学基础研究计划（2012JM5005）；陕西省教育厅科学研究计划（12JK0483）。

详细信息

通讯作者:
杨建业，男，教授，研究方向为煤地球化学。E-mail：yjyxust@163.com。

中图分类号: TQ533
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出版历程
- 收稿日期: 2013-12-09
- 修回日期: 2014-02-20
- 刊出日期: 2014-06-30

Preliminary study about combination between trace elements and organic matter in coal——An example of 8^# coal seam from Taiyuan Xishan

1.
College of Material Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China;
2.
College of Geology and Environment, Xi'an University of Science and Technology, Xi'an 710054, China;
3.
College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China

摘要

摘要: 对太原西山矿区8号煤层的肥、焦、瘦、贫等不同烟煤的镜煤组分进行了酸洗脱灰处理，并同时对这些酸洗后的样品进行了红外分峰处理和微量元素含量的测定，发现随着煤的变质程度加深，某些有机基团与某些微量元素呈正相关关系，并因其正相关系数很高而结合的可能性很大；有的呈负相关关系；也有的和微量元素部分呈正相关变化部分则呈负相关变化。因此，将煤的有机基团分为三类：微量元素亲和性有机基团、微量元素憎厌性有机基团和对微量元素既无亲和性也无憎厌性的中性有机基团。微量元素和煤的有机基团之间相互选择性很强。但无论表现为典型的亲和性还是憎厌性，其亲和、憎厌程度的变化波动趋势，均遵循一个统一的变化规律——元素周期律。典型的中性有机基团，对亲石元素和亲铁亲铜元素所表现的亲和、憎厌倾向也有明显不同，有一定的规律可循。煤中不同类型的有机基团和微量元素的正负相关性，即对微量元素的亲和和憎厌性，对元素周期律的响应型式和响应程度差别也很大。
- 镜煤 /
- 红外分峰处理 /
- 微量元素亲和性和憎厌性有机基团 /
- 元素周期律
Abstract: The acid pickling and demineralization for vitrain samples of fat coal, coking coal, lean coal and meager coal from 8^# coal seam of Taiyuan Xishan, China was accomplished. Meanwhile, both the trace elements testing and curve fitting of infrared spectra of the samples were carried out. It shows that correlation between some of organic group and trace elements in vitrain may be positive changes, or negative changes, or they suddenly be positive or negative with the deepening of coal metamorphism. Accordingly, organic structure-groups in coal can be divided into three types: affinity organic groups for trace elements, abhorred organic groups for trace elements and the neutral organic groups which neither affinity nor abhorred for trace elements. It is discovered that the mutual selection is very intense between organic groups and trace elements in vitrain. Whether typical affinity organic groups or typical abhorred one for trace elements, their change of affinity or abhorred are all abide by a common law, namely, the element periodic law. Even if neutral ones, its tendency of affinity or abhorred for lithophile element, chalcophile and siderophile elements are obviously different.
- vitrain /
- curve fitting of infrared spectra /
- the affinity and abhorred organic groups for trace element /
- element periodic law

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参考文献(9)

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