Catalytic performance of carbide slag loaded with potassium fluoride in transesterification
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摘要: 通过浸渍法制备以氟化钾为活性体、电石渣为载体的负载型钙基酯交换催化剂,并在借助X射线荧光光谱仪、热分析天平、X射线衍射仪、氮气吸附-脱附仪、扫描电子显微镜以及哈米特指示剂法等手段对催化剂表征,以及气相色谱仪对原料油成分分析的基础上,通过间歇式酯交换实验系统,从催化剂添加量、醇油物质的量比、酯交换温度与时间等影响因素出发,研究了电石渣负载氟化钾催化花生油与甲醇酯交换的特性。电石渣负载氟化钾后,产生KCaF3、CaF2以及KF等新物相,并且在催化剂添加量为5%、反应温度为62 ℃、反应时间为2 h以及醇油物质的量比为15的酯交换条件下,能够取得91.58%的甘油收率,相比较氢氧化钙和未有活性体负载的电石渣,其催化酯交换性能得到提高。Abstract: Using the potassium fluoride as the active site and the carbide slag as the carrier, a calcium-based loaded catalyst for the transesterification was prepared through the impregnation method. The catalyst was characterized by X-ray fluorescence, thermogravimetric analysis, X-ray diffraction, nitrogen adsorption and desorption, scanning electron microscope and Hammett indicator. Also, the composition of peanut oil was analyzed by gas chromatograph. Then, the performance of prepared catalyst in the transesterification of peanut oil with methanol was examined with a batchwise experimental system. After being loaded with potassium fluoride, the new textural phases of KCaF3, CaF2 and KF emerge. Under the condition of the catalyst addition of 5%, the transesterification temperature of 62 ℃, the transesterification time of 2 h and the molar ratio of methanol to oil of 15, the glycerol yield of 91.58% can be achieved. Compared with calcium hydroxide and unloaded carbide slag, this loaded catalyst has a better performance.
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Key words:
- transesterification /
- catalyst /
- carbide slag /
- potassium fluoride /
- load
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郑华艳, 李茜茜, 崔丽萍, 李忠. Ca/Al固体碱催化菜籽油制备生物柴油[J]. 燃料化学学报, 2012, 40(3): 331-336. (ZHENG Hua-yan, LI Qian-qian, CUI Li-ping, LI Zhong. Synthesis of biodiesel from rapeseed oil catalyzed by Ca/Al solid base[J]. Journal of Fuel Chemistry and Technology, 2012, 40(3): 331-336.) 梁金花, 任晓乾, 王锦堂, 姜岷, 李振江. 双核碱性离子液体催化棉籽油酯交换制备生物柴油[J]. 燃料化学学报, 2010, 38(3): 275-280. (LIANG Jin-hua, REN Xiao-qian, WANG Jin-tang, JIANG Min, LI Zhen-jiang. Preparation of biodiesel by transesterification from cottonseed oil using the basic dication ionic liquids as catalysts[J]. Journal of Fuel Chemistry and Technology, 2010, 38(3): 275-280.) 侯凯丽, 赵华, 田薇薇, 李会鹏. 固体催化剂催化酯交换反应制备生物柴油研究进展[J]. 工业催化, 2010, 18(8): 7-11. (HOU Kai-li, ZHAO Hua, TIAN Wei-wei, LI Hui-peng. Latest researches in synthesis of biodiesel biodiesel via transesterification catalyzed by solid catalysts[J]. Industrial Catalysis, 2010, 18(8): 7-11.) KOUZU M, HIDAKA J. Transesterification of vegetable oil into biodiesel catalyzed by CaO: A review[J]. Fuel, 2012, 93: 1-12. WEI Z K, XU C L, LI B X. Application of waste eggshell as low-cost solid catalyst for biodiesel production[J]. Bioresour Technol, 2009, 100(11): 2883-2885. BOEY P L, MANIAM G P, HAMID S A, ALI D M H. Crab and cockle shells as catalyst for the preparation of methyl esters from low FFA chicken fat[J]. J Am Oil Chem Soc, 2011, 88(2): 283-288. NAKATANI N, TAKAMORI H, TAKEDA K, SAKUGAWA H. Transesterification of soybean oil using combusted oyster shell waste as a catalyst[J]. Bioresour Technol, 2009, 100(3): 1510-1513. LI Y J, LIU H L, SUN R Y, WU S M, LU C M. Thermal analysis of cyclic carbonation behavior of CaO derived from carbide slag at high temperature[J]. J Therm Anal Calorim, 2012, 110(2): 685-694. 谭亚, 李彩亭, 曾光明, 翟云波, 李珊红, 邓久华. 添加剂对燃煤电石渣固硫的促进作用[J]. 燃料化学学报, 2005, 33(6): 767-770. (TAN Ya, LI Cai-ting, ZENG Guang-ming, ZHAI Yun-bo, LI Shan-hong, DENG Jiu-hua. Promotion effect of additives on sulfur capture during coal combustion with carbide slag[J]. Journal of Fuel Chemistry and Technology, 2005, 33(6): 767-770.) NIU S L, LIU M Q, LU C M, LI H, HUO M J. Thermogravimetric analysis of carbide slag: A potential transesterification catalyst validation[J]. J Therm Anal Calorim, 2014, 115(1): 73-79. 牛胜利, 李辉, 路春美, 刘梦琪, 霍梦佳. 造纸白泥催化花生油与甲醇酯交换的特性研究[J]. 燃料化学学报, 2013, 41(7): 856-861. (NIU Sheng-li, LI Hui, LU Chun-mei, LIU Meng-qi, HUO Meng-jia. Catalytic performance of papermaking white clay in the transesterification of peanut oil with methanol[J]. Journal of Fuel Chemistry and Technology, 2013, 41(7): 856-861.) GAO L, TENG G, XIAO G, WEI R. Biodiesel from palm oil via loading KF/Ca-Al hydrotalcite catalyst[J]. Biomass Bioenergy, 2010, 34(9): 1283-1288. 钱卫卫, 韩萍芳, 吕效平. 超声作用下KF/CaO催化酯交换反应制备生物柴油[J]. 燃料化学学报, 2010, 38(1): 52-56. (QIAN Wei-wei, HAN Ping-fang, LV XIAO-ping. KF/CaO as solid base catalyst for transesterification to biodiesel by ultrasound[J]. Journal of Fuel Chemistry and Technology, 2010, 38(1): 52-56.) 刘云, 陈文, 邓利. 生物柴油工艺技术[M]. 北京: 化学工业出版社, 2011: 12-13. (LIU Yun, CHEN Wen, DENG Li. Process technology of biodiesel[M]. Beijing: Chemical Industry Press, 2011: 12-13.) YIN J Z, MA Z, SHANG Z Y, HU D P, XIU Z L. Biodiesel production from soybean oil transesterification in subcritical methanol with K3PO4 as catalyst[J]. Fuel, 2012, 93: 284-287. FREEDMAN B, PRYDE E H, MOUNTS T L. Variables affecting the yields of fatty esters from transesterified vegetable oil[J]. J Am Oil Chem Soc, 1984, 61(10): 1638-1643. 李亚娥. 非负载型固体碱催化剂制备生物柴油的研究[D]. 西安: 西北大学, 2010. (LI Ya-e. Study on non-carrier solid base catalysts for synthsis of biodiesel[D]. Xi'an: Xibei University, 2010.)
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