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Ni2P催化剂的低温还原法合成及其HDS性能

宋华 王紫东 代敏 宋华林 万霞 李锋

宋华, 王紫东, 代敏, 宋华林, 万霞, 李锋. Ni2P催化剂的低温还原法合成及其HDS性能[J]. 燃料化学学报(中英文), 2014, 42(06): 733-737.
引用本文: 宋华, 王紫东, 代敏, 宋华林, 万霞, 李锋. Ni2P催化剂的低温还原法合成及其HDS性能[J]. 燃料化学学报(中英文), 2014, 42(06): 733-737.
SONG Hua, WANG Zi-Dong, DAI Min, SONG Hua-Lin, WAN Xia, LI Feng. Preparation of Ni2P catalyst at low reduction temperature and its HDS performance[J]. Journal of Fuel Chemistry and Technology, 2014, 42(06): 733-737.
Citation: SONG Hua, WANG Zi-Dong, DAI Min, SONG Hua-Lin, WAN Xia, LI Feng. Preparation of Ni2P catalyst at low reduction temperature and its HDS performance[J]. Journal of Fuel Chemistry and Technology, 2014, 42(06): 733-737.

Ni2P催化剂的低温还原法合成及其HDS性能

基金项目: 国家自然科学基金(21276048);黑龙江省自然科学基金(ZD201201)。
详细信息
    通讯作者:

    宋华林,Tel:0453-6984321,E-mail:songhualin401@126.com,songhua2004@sina.com。

  • 中图分类号: O643.361

Preparation of Ni2P catalyst at low reduction temperature and its HDS performance

  • 摘要: 在低还原温度下程序升温还原法制备了Ni2P/MCM-41催化剂,并采用H2-TPR、TG-DTG、XRD、BET、XPS等手段对制备的催化剂进行了表征,考察了还原温度对活性相Ni2P形成以及催化剂二苯并噻吩HDS性能的影响。结果表明,在210~390 ℃下还原得到的催化剂活性相为单一的Ni2P相;在390 ℃下还原得到的催化剂具有最高的二苯并噻吩HDS活性,在反应温度340 ℃、反应压力3.0 MPa、氢/油体积比500、质量空速(WHSV)2.0 h-1的条件下二苯并噻吩HDS转化率达到99.0%。
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出版历程
  • 收稿日期:  2013-12-08
  • 修回日期:  2014-03-26
  • 刊出日期:  2014-06-30

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