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贵金属负载TiO2对光催化还原CO2选择性的影响

郝瑞鹏 杨朋举 王志坚 朱珍平

郝瑞鹏, 杨朋举, 王志坚, 朱珍平. 贵金属负载TiO2对光催化还原CO2选择性的影响[J]. 燃料化学学报(中英文), 2015, 43(01): 94-99.
引用本文: 郝瑞鹏, 杨朋举, 王志坚, 朱珍平. 贵金属负载TiO2对光催化还原CO2选择性的影响[J]. 燃料化学学报(中英文), 2015, 43(01): 94-99.
HAO Rui-peng, YANG Peng-ju, WANG Zhi-jian, ZHU Zhen-ping. Effect of noble metals loaded TiO2 on the selectivity of photocatalytic CO2 reduction[J]. Journal of Fuel Chemistry and Technology, 2015, 43(01): 94-99.
Citation: HAO Rui-peng, YANG Peng-ju, WANG Zhi-jian, ZHU Zhen-ping. Effect of noble metals loaded TiO2 on the selectivity of photocatalytic CO2 reduction[J]. Journal of Fuel Chemistry and Technology, 2015, 43(01): 94-99.

贵金属负载TiO2对光催化还原CO2选择性的影响

基金项目: 国家自然科学基金(21173250).
详细信息
    通讯作者:

    王志坚,Tel:0351-4045918,Fax:0351-4151663,E-mail:wangzhijian@sxicc.ac.cn;朱珍平,Tel:0351-4048715,Fax:0351-4151663,E-mail:zpzhu@sxicc.ac.cn.

  • 中图分类号: O643.3

Effect of noble metals loaded TiO2 on the selectivity of photocatalytic CO2 reduction

  • 摘要: 利用光沉积方法在TiO2表面分别负载1%(质量分数) Pt、Pd、Au和Ag助催化剂.用TEM、XRD、UV-vis等技术对催化剂进行了表征,并利用连续瞬态电流时间响应和线性扫描伏安法等电化学方法,对贵金属负载的TiO2光催化剂在光照条件下的电流响应强度及电催化析氢电位等特性加以测试.分析了贵金属助催化剂对光催化还原CO2性能的差异.结果表明,负载贵金属助催化剂能显著加速光生电子空穴的分离,降低复合率;另外,助催化剂对还原CO2选择性的顺序为Ag>Au>Pd>Pt.贵金属助催化剂还原CO2的加氢选择性和析氢过电位存在相关性,即越不利于析氢过程的助催化剂,其催化CO2加氢还原产物的选择性越高.
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出版历程
  • 收稿日期:  2014-09-25
  • 修回日期:  2014-10-22
  • 刊出日期:  2015-01-30

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