Ni<sub>0.6</sub>Cu<sub>0.4</sub>O/NC催化剂的制备及其催化氨硼烷水解制氢性能研究

李蓉; 左佑华; 花俊峰; 郝思雨; 许立信; 叶明富; 万超

doi:10.1016/S1872-5813(24)60436-6

Ni_0.6Cu_0.4O/NC催化剂的制备及其催化氨硼烷水解制氢性能研究

doi: 10.1016/S1872-5813(24)60436-6

李蓉^1,,
左佑华¹,
花俊峰^2,,
郝思雨^1,,
许立信^1, ,,
叶明富^{1, 3, 4, 5,},
万超^{1, 4, 6, 7, ,}

1.
安徽工业大学化学与化工学院, 安徽马鞍山 243032
2.
浙江省环境科技有限公司浙江杭州 310027
3.
安徽工业大学生物膜法水质净化及利用技术教育部工程研究中心, 安徽马鞍山 243032
4.
南开大学先进能源材料化学教育部重点实验室, 天津 300071
5.
宁德师范学院绿色能源与环境催化福建高校重点实验室, 福建宁德 352100
6.
常州大学江苏省绿色催化材料与技术重点实验室, 江苏常州 213164
7.
浙江大学化学工程与生物工程学院, 浙江杭州 310058

基金项目: 国家自然科学基金青年基金(22108238)和联合项目(U22A20408)，安徽省自然科学基金青年基金(1908085QB68)，中国博士后面上项目(2019M662060)、派出项目(PC2022046)和特别资助站中项目(2020T130580)，江苏省绿色催化材料与技术重点实验室(BM2012110)，绿色能源与环境催化福建省高校重点实验室开放课题(FJ-GEEC202204)，2022、2023年国家级大学生创新创业训练计划项目(202210360037、S202310260212)，生物膜法水质净化及利用技术教育部工程研究中心开放基金(BWPU2023KF06)资助

详细信息

通讯作者:
E-mail: lxxu@hotmail.com

wanchao@zju.edu.cn

中图分类号: O643.36
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- 文章访问数: 26
- HTML全文浏览量: 6
- PDF下载量: 7
- 被引次数: 0
出版历程
- 收稿日期: 2023-12-04
- 修回日期: 2024-01-22
- 录用日期: 2024-01-22
- 网络出版日期: 2024-03-25

Preparation of Ni_0.6Cu_0.4O/NC catalyst and its catalytic performance for hydrogen production from hydrolysis of ammonia borane

LI Rong^1
,,
ZUO Youhua¹,
HUA Junfeng^2
,,
HAO Siyu^1
,,
XU Lixin^{1
, ,},
YE Mingfu^{1, 3, 4, 5
,},
WAN Chao^{1, 4, 6, 7
, ,}

1.
School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma’anshan 243032, China
2.
Zhejiang Environment Technology Co., Ltd, Hangzhou 310027, China
3.
Engineering Research Center of Biofilm Water Purification and Utilization Technology of Ministry of Education, Anhui University of Technology, Ma’anshan 243032, China
4.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
5.
Key Laboratory of Green Energy and Environment Catalysis, Ningde Normal University, Ningde 352100, China
6.
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, China
7.
College of Chemical Engineering and Biological Engineering, Zhejiang University, Hangzhou 310058, China

Funds: The project was supported by the National Natural Science Foundation of China (22108238、U22A20408), Anhui Provincial Natural Science Foundation (1908085QB68), China Postdoctoral Science Foundation (2019M662060, PC2022046, 2020T130580), Open Research Funds of Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology(BM2012110), Open Research Funds of Key Laboratory of Green Energy and Environment Catalysis(FJ-GEEC202204)and 2022、2023 National Undergraduate Innovation and entrepreneurship training program (202210360037、S202310260212), Supported by the Open Project of Engineering Research Center of Biofilm Water Purification and Utilization Technology of Ministry of Education (BWPU2023KF06).

摘要

摘要: 氨硼烷（NH₃BH₃，AB）是一种理想的制氢原料，具有较高的储氢能力。本研究在氮气气氛下高温碳化Ni/Cu-ZIF前驱体制备了一种含氮炭材料（Ni_0.6Cu_0.4O/NC）催化剂，并采用多种表征方法对所制备催化剂的微观结构以及组成成分进行了研究。此外，通过控制变量法探究了催化剂的催化性能以及变化规律。研究结果表明，Ni_0.6Cu_0.4O/NC催化AB水解制氢的活化能（E_a）为56.8 kJ/mol，TOF值高达1572.2 h⁻¹。该催化剂催化AB水解制氢速率对于AB自身浓度可近似看作零级反应，而相对于催化剂的用量可近似看作一级反应。催化剂经过10次循环后仍然保持良好的催化活性，表明其具有良好的稳定性。
- 含氮炭材料 /
- 氨硼烷 /
- 水解制氢
Abstract: Ammonia borane (NH₃BH₃, AB) is an ideal feedstock for hydrogen production with high hydrogen storage capacity. In this paper, a nitrogen-containing carbon material (Ni_0.6Cu_0.4O/NC) catalyst was prepared by high-temperature carbonization of Ni/Cu-ZIF precursor under nitrogen atmosphere, and the microstructure as well as the composition of the prepared catalyst were investigated by various characterization methods. In addition, the catalytic performance of the catalyst and the variation rule were investigated by the controlled variable method. The results showed that the activation energy (E_a) of Ni_0.6Cu_0.4O/NC catalyzed hydrolysis of AB for hydrogen production was 56.8 kJ∙mol⁻¹, and the TOF value was as high as 1572.2 h⁻¹. The rate of hydrogen production from AB hydrolysis catalyzed by this catalyst could be approximated as a zero-order reaction with respect to the concentration of AB itself, and a one-order reaction with respect to the amount of catalyst. The catalyst still maintained good catalytic activity after ten cycles, indicating its good stability.
- nitrogen-containing carbon material /
- ammonia borane /
- hydrogen hydrolysis

HTML全文

图 1 Ni_0.6Cu_0.4O/NC催化剂的TEM图像

Figure 1 Ni_0.6Cu_0.4O/NC catalyst of TEM image

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图 2 Ni_0.6Cu_0.4O/NC催化剂的XRD谱图

Figure 2 XRD spectra of Ni_0.6Cu_0.4O/NC catalyst

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图 3 （a）Ni_0.6Cu_0.4O/NC催化剂的XPS全谱图；（b）N 1s精细谱图；（c）Cu 2p精细谱图；（d）Ni 2p精细谱图

Figure 3 (a) XPS survey spectra of Ni_0.6Cu_0.4O/NC catalyst; (b) N 1s fine spectrum; (c) Cu 2p fine spectrum; (d) Ni 2p fine spectrum

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图 4 （a）Ni_0.6Cu_0.4O/NC催化剂的N₂吸附-脱附曲线；（b）Ni_0.6Cu_0.4O/NC催化剂的孔径分布

Figure 4 (a) N₂ adsorption-desorption curves of Ni_0.6Cu_0.4O/NC catalyst; (b) Pore size distribution of Ni_0.6Cu_0.4O/NC catalyst

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图 5 （a）不同Ni/Cu物质的量比催化剂催化AB水解制氢速率曲线；（b）对应不同物质的量比的TOF值

Figure 5 (a) Rate profiles of hydrogen production from AB hydrolysis catalyzed by catalysts with different Ni/Cu molar ratios; (b) TOF values corresponding to different molar ratios

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图 6 （a）不同用量的Ni_0.6Cu_0.4O/NC催化AB水解制氢速率曲线；（b）ln k-ln cat.拟合曲线

Figure 6 (a) Rate profiles of hydrogen production by catalytic AB hydrolysis with different amounts of Ni_0.6Cu_0.4O/NC;(b) The fitting curve of ln k-ln cat.

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图 7 （a）Ni_0.6Cu_0.4O/NC催化AB水解制氢速率随自身浓度变化关系曲线；（b）ln k-ln AB拟合曲线

Figure 7 (a) Hydrogen production rate of Ni_0.6Cu_0.4O/NC-catalyzed AB hydrolysis as a function of its own concentration curve;(b) The fitting curve of ln k-ln AB

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图 8 （a）不同反应温度对Ni_0.6Cu_0.4O/NC催化AB水解制氢速率曲线；（b）ln k-1/T的Arrhenius图

Figure 8 (a) Rate profiles of hydrogen production from Ni_0.6Cu_0.4O/NC-catalyzed AB hydrolysis with different reaction temperatures; (b) Arrhenius diagram for ln k-1/T

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图 9 Ni_0.6Cu_0.4O/NC催化AB水解制氢循环性能

Figure 9 Cyclic performance diagram of Ni_0.6Cu_0.4O/NC catalyzed AB hydrolysis for hydrogen production

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表 1 室温下水溶液中AB水解制氢各种金属催化剂的催化活性

Table 1 Catalytic activity of various metal catalysts for hydrogen production by AB hydrolysis in aqueous solution at room temperature

Catalyst	TOF/h⁻¹	E_a/(kJ∙mol⁻¹)	Ref.
Ni_0.6Cu_0.4O/NC	1572.2	56.8	this work
Ni_0.3Co_0.3Cu_0.4	66	58.9	[36]
Cu_0.64Ni_0.36-TiO₂ (B) NTs	954	36.14	[37]
NiCu/SiO₂	1518	34.2	[38]
Ni/Cu-c	540	23.7	[39]
Ni/Cu-t	282	35	[39]
Ni/Cu-o	204	62	[39]
Ni/g-C₃N₄	1122	36	[40]
Ni/TiN-TiO₂	480	60.7	[41]
CoCu-NC-5	487.2	34.25	[42]
SCo_0.43Cu_0.57	340.8	31.06	[43]
Cu₂Ni₁@MIL-101	1254	32.2	[44]
Cu_0.4Co_0.6/BNNFs	505.2	21.8	[45]
Ni/BN	72	63.2	[46]
Ni/CeO₂	504	28.9	[47]

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参考文献(49)

[1]	SUN Z, SUN Z. Hydrogen generation from methanol reforming for fuel cell applications: A review[J]. J Cent South Univ,2020,27(4):1074−1103. doi: 10.1007/s11771-020-4352-8
[2]	吴慧, 郑君宁, 左佑华, 等. NiPd/TiO₂催化剂的制备及催化甲酸分解制氢[J]. 精细化工, 2023. WU Hui, ZHENG Junning, ZUO Youhua, et al. Preparation of NiPd/TiO₂ catalysts and catalytic hydrogen production from formic acid decomposition[J]. Fine Chem, 2023.)
[3]	张唯怡, 张议洁, 王进伟, 等. 电解水制氢技术及大电流析氧反应研究与展望[J]. 工程科学学报,2023,45(7):1057−1070. ZHANG Weiyi, ZHANG Yijie, WANG Jinwei, et al. Research and perspectives on electrocatalytic water splitting and large current density oxygen evolution reaction[J]. Chin J Eng,2023,45(7):1057−1070.
[4]	LE P A, TRUNG V D, NGUYEN P L, et al. The current status of hydrogen energy: an overview[J]. RSC Adv,2023,13(40):28262−20287. doi: 10.1039/D3RA05158G
[5]	WEI Y, YANG G, XU X, et al. Ultrafine Ru nanoparticles anchored on core–shell structured zeolite-carbon for efficient catalysis of hydrogen generation[J]. Rare Met,2023,42(7):2324−2334. doi: 10.1007/s12598-022-02246-0
[6]	ALPTEKIN F M, CELIKTAS M S. Review on catalytic biomass gasification for hydrogen production as a sustainable energy form and social, technological, economic, environmental, and political analysis of catalysts[J]. ACS Omega,2022,7(29):24918−24941. doi: 10.1021/acsomega.2c01538
[7]	王小燕, 张若凡, 司航, 等. 椰壳炭负载钌催化剂的制备及其催化氨硼烷水解制氢性能[J]. 石油炼制与化工,2023,54(7):64−70. doi: 10.3969/j.issn.1005-2399.2023.07.012 WANG Xiaoyan, ZHANG Ruofan, SI Hang, et al. Preparation of coconut shell charcoal-loaded ruthenium catalysts and their catalytic performance for hydrogen production from hydrolysis of ammonia borane[J]. Pet Process Petrochem,2023,54(7):64−70. doi: 10.3969/j.issn.1005-2399.2023.07.012
[8]	HUO J, ZHANG K, WEI H, et al. A review on hydrogen production from ammonia borane: Experimental and theoretical studies[J]. Chin Chem Lett,2023,34(12):108280. doi: 10.1016/j.cclet.2023.108280
[9]	WANG M, WANG J, ZHAO X, et al. CuCo₂O₄-NiO heterostructure catalysts for hydrogen production from ammonia borane[J]. Int J Hydrogen Energy,2023,48(51):19543−19553. doi: 10.1016/j.ijhydene.2023.02.068
[10]	曹云钟, 郑君宁, 吴慧, 等. Pt基催化剂催化氨硼烷水解产氢的研究进展[J]. 稀有金属,2023,47(8):1122−1131. CAO Yunzhong, ZHENG Junning, WU Hui, et al. Advances in hydrogen production by ammonia borane hydrolysis over Pt-based catalysts[J]. Rare Met,2023,47(8):1122−1131.
[11]	ZHANG J, LI J, YANG L, et al. Efﬁcient hydrogen production from ammonia borane hydrolysis catalyzed by TiO₂-supported RuCo catalysts[J]. Int J Hydrogen Energy,2021,46(5):3964−3973. doi: 10.1016/j.ijhydene.2020.10.234
[12]	WAN C, LI G, WANG J, et al. Modulating electronic metal-support interactions to boost visible-light-driven hydrolysis of ammonia borane: Nickel-Platinum nanoparticles supported on phosphorus-doped titania[J]. Angew Chem Int Ed,2023,62(40):e202305371. doi: 10.1002/anie.202305371
[13]	邱小魁, 张若凡, 王小燕, 等. 竹茹丝炭负载钌催化剂光催化氨硼烷水解产氢研究[J]. 无机盐工业, 2023, 55(10): 153-158. QIU Xiaokui, ZHANG Ruofan, WANG Xiaoyan, et al. Hydrogen production by photocatalytic hydrolysis of ammonia borane over Bamboo Rhizoma Pinelliae silk charcoal loaded ruthenium catalysts[J]. 2023, 55(10): 153-158.)
[14]	LI J, REN X, LV H, et al. Highly efficient hydrogen production from hydrolysis of ammonia borane over nanostructured Cu@CuCoO_x supported on graphene oxide[J]. J Hazard Mater,2020,391:122199. doi: 10.1016/j.jhazmat.2020.122199
[15]	李贵, 梁雨, 郑君宁, 等. Rh/N-GMCs纳米催化剂的制备及其催化氨硼烷水解产氢性能研究[J]. 燃料化学学报,2023,51(4):528−537. LI Gui, LIANG Yu, ZHENG Junning, et al. Preparation of Rh/N-GMCs nanocatalyst and its catalytic performance for the hydrolytic dehydrogenation of ammonia borane[J]. J Fuel Chem Technol,2023,51(4):528−537.
[16]	WAN C, LIANG Y, ZHOU L, et al. Integration of morphology and electronic structure modulation on cobalt phosphide nanosheets to boost photocatalytic hydrogen evolution from ammonia borane hydrolysis[J]. Green Energy Environ, 2022.
[17]	FANG M J, LIN Y C, JAN J Y, et al. Au@Cu₂O core@shell nanocrystals as sustainable catalysts for efficient hydrogen production from ammonia borane[J]. Appl Catal B Environ,2023,324:122198. doi: 10.1016/j.apcatb.2022.122198
[18]	牛曦若, 张怡菲, 徐靖涵, 等. MOF衍生物(Fe/NC)活化过硫酸盐对土霉素的高效降解[J]. 环境化学, 2023. NIU Ruoxi, ZHANG Yifei, XU Jinghan, et al. Efficient degradation of oxytetracycline by persulfate activated by MOF derivative (Fe/NC)[J]. Environ Chem, 2023.)
[19]	VILLENOISY T D, ZHENG X, WONG V, et al. Principles of design and synthesis of metal derivatives from MOFs[J]. Adv Mater,2023,35(24):2210166. doi: 10.1002/adma.202210166
[20]	SONG G, SHI Y, JIANG S, et al. Recent progress in MOF-derived porous materials as electrodes for high-performance Lithium-ion batteries[J]. Adv Funct Mater,2023,33(42):2303121. doi: 10.1002/adfm.202303121
[21]	LI Y-X, HAN Y C, WANG C C. Fabrication strategies and Cr(VI) elimination activities of the MOF-derivatives and their composites[J]. Chem Eng J,2021,405:126648. doi: 10.1016/j.cej.2020.126648
[22]	ABDELHAMID H, MEKHEMER I M. A. , GABER A-A M. Metal-organic frameworks (MOFs)-derived ZrOSO₄@C for photocatalytic synthesis of benzimidazole derivatives[J]. Mol Catal, 2023, 548 : 113418.
[23]	XIAO T, LIU D. The most advanced synthesis and a wide range of applications of MOF-74 and its derivatives[J]. Micropor Mesopor Mater,2019,283:88−103. doi: 10.1016/j.micromeso.2019.03.002
[24]	SHEN M, MA H. Metal-organic frameworks (MOFs) and their derivative as electrode materials for lithium-ion batteries[J]. Coord Chem Rev,2022,470:214715. doi: 10.1016/j.ccr.2022.214715
[25]	KUMAR G, DUTTA A, GOSWAMI M, et al. Synthesis of Zr-MOF/rGO-nanocomposites used for spirooxindole scaffolds derivatives[J]. J Mol Struct,2023,1287:135653. doi: 10.1016/j.molstruc.2023.135653
[26]	CAO L, CHEN B, YAN J, et al. Nickel nanoparticle-embedded N-doped carbon catalysts formed by MOF derivatives for the oxygen evolution reaction[J]. New J Chem,2023,47(27):12799−12805. doi: 10.1039/D3NJ01102J
[27]	PÜSCHEL D, HÉDÉ S, MAISULS I, et al. Enhanced solid-state fluorescence of flavin derivatives by incorporation in the metal-organic frameworks MIL-53(Al) and MOF-5[J]. Molecules,2023,28(6):2877. doi: 10.3390/molecules28062877
[28]	FEREJA S L, ZHANG Z, FANG Z. High-entropy oxide derived from metal-organic framework as a bifunctional electrocatalyst for efficient urea oxidation and oxygen evolution reactions[J]. ACS Appl Mater Interfaces,2022,14(34):38727−38738. doi: 10.1021/acsami.2c09161
[29]	LI C, LIU X, WANG H, et al. Metal-organic framework derived hexagonal layered cobalt oxides with {112} facets and rich oxygen vacancies: High efﬁciency catalysts for total oxidation of propane[J]. Adv Powder Technol,2022,33(1):103373. doi: 10.1016/j.apt.2021.11.025
[30]	KOTEESWARI P, SAGADEVAN S, FATIMAH I, et al. Green synthesis and characterization of copper oxide nanoparticles and their photocatalytic activity[J]. Inorg Chem Commun,2022,144:109851. doi: 10.1016/j.inoche.2022.109851
[31]	张兴, 刘浩宇, 朱明路. 碳化Ni@MOF808催化剂在甲烷干重整中的研究[J]. 山东化工,2023,52(10):9−11. doi: 10.3969/j.issn.1008-021X.2023.10.003 ZHANG Xing, LIU Haoyu, ZHU Minglu. Study on carbonized Ni@MOF808 catalyst in methane dry reforming[J]. Shandong Chem Ind,2023,52(10):9−11. doi: 10.3969/j.issn.1008-021X.2023.10.003
[32]	YAN J, ZHOU Y, SHEN J, et al. Facile synthesis of S, N-co-doped carbon dots for bio-imaging, Fe³⁺ detection and DFT calculation[J]. Spectrochim Acta A Mol Biomol Spectrosc,2023,302:123105. doi: 10.1016/j.saa.2023.123105
[33]	Rana L K, Kaur P, Bavandsavadkouhi A, et al. Isostructural coordination polymers of the tethering naphthalene anchored bis (2-methylpyridinecarboxamide) ligand: single crystal, XPS, EDS and theoretical studies[J]. New J Chem,2023,47(11):5477−5487. doi: 10.1039/D3NJ00038A
[34]	JOHNSON E, KRISHNAN R, CHANDRAN S, et al. Green mediated sol-gel synthesis of copper oxide nanoparticle: An efﬁcient candidate for waste water treatment and antibacterial agent[J]. J Sol-Gel Sci Technol,2023,107:697−710. doi: 10.1007/s10971-023-06172-0
[35]	ZHANG L, ZHOU L, YANG K, et al. Pd-Ni nanoparticles supported on MIL-101 as high-performance catalysts for hydrogen generation from ammonia borane[J]. J Alloys Compd,2016,677:87−95. doi: 10.1016/j.jallcom.2016.03.234
[36]	YANG X, WANG C, GAO R, et al. Non-noble metallic nanoparticles supported on titania spheres as catalysts for hydrogen generation from hydrolysis of ammonia borane under ultraviolet light irradiation[J]. Int J Hydrogen Energy,2018,43(34):16556−16565. doi: 10.1016/j.ijhydene.2018.07.049
[37]	WANG C, SUN D, YU X, et al. Cu/Ni nanoparticles supported on TiO₂ (B) nanotubes as hydrogen generation photocatalysts via hydrolysis of ammonia borane[J]. Inorg Chem Front,2018,5(8):2038−2044. doi: 10.1039/C8QI00492G
[38]	GUO K, DING Y, LUO J, et al. NiCu bimetallic nanoparticles on silica support for catalytic hydrolysis of ammonia borane: composition-dependent activity and support size effect[J]. ACS Appl Energy Mater,2019,2(8):5851−5861. doi: 10.1021/acsaem.9b00997
[39]	LI X, ZHANG J, WANG S, et al. Exposed facet tailoring of Ni/Cu catalysts for boosting dehydrogenation of ammonia borane[J]. ACS Appl Nano Mater,2023,6(20):19136−19147. doi: 10.1021/acsanm.3c03621
[40]	GAO M, YU Y, YANG W, et al. Ni nanoparticles supported on graphitic carbon nitride as visible light catalysts for hydrolytic dehydrogenation of ammonia borane[J]. Nanoscale,2019,11(8):3506−3513. doi: 10.1039/C8NR09005J
[41]	LI X, LIU Y, XU P, et al. Enhanced hydrogen production from ammonia borane over Ni nanoparticles supported on TiN-TiO₂ composites under sunlight[J]. Energy Fuels,2022,36(5):2901−2909. doi: 10.1021/acs.energyfuels.1c04255
[42]	SONG Y, GAO C, LIU J, et al. Fabrication of multiatomic structure of Cu-CoO/Co interface for efﬁcient hydrogen generation from ammonia borane hydrolysis[J]. Int J Hydrogen Energy,2023,48(67):26162−26172. doi: 10.1016/j.ijhydene.2023.03.270
[43]	WANG C, LI L, YU X, et al. Regulation of d-band electrons to enhance the activity of Co-based non-noble bimetal catalysts for hydrolysis of ammonia borane[J]. ACS Sustain Chem Eng,2020,8(22):8256−8266. doi: 10.1021/acssuschemeng.0c01475
[44]	GAO D, ZHANG Y, ZHOU L, et al. CuNi NPs supported on MIL-101 as highly active catalysts for the hydrolysis of ammonia borane[J]. Appl Surf Sci,2018,427:114−122. doi: 10.1016/j.apsusc.2017.08.167
[45]	YANG X, LI Q, LI L, et al. CuCo binary metal nanoparticles supported on boron nitride nanofibers as highly efficient catalysts for hydrogen generation from hydrolysis of ammonia borane[J]. J Power Sources,2019,431:135−143. doi: 10.1016/j.jpowsour.2019.05.038
[46]	YANG X, LI L, SANG W, et al. Boron nitride supported Ni nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane[J]. J Alloys Compd,2017,693:642−649. doi: 10.1016/j.jallcom.2016.09.204
[47]	YAO Q, LU Z, YANG Y, et al. Facile synthesis of graphene-supported Ni-CeO_x nano-composites as highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane[J]. Nano Res,2018,11(8):4412−4422. doi: 10.1007/s12274-018-2031-y
[48]	吴慧, 郑君宁, 李蓉, 等. NiPt/CeO₂催化剂的制备及其催化水合肼分解制氢性能研究[J]. 中国稀土学报, 2023. WU Hui, ZHENG Junning, LI Rong, et al. Preparation of NiPt/CeO₂ catalyst and its catalytic performance for hydrogen production from hydrazine hydrate decomposition[J]. J Chin Soc Rare Earths, 2023.)
[49]	KARATAS Y, GÜLCAN M, ZAHMAKIRAN M. Silica supported ternary NiRuPt alloy nanoparticles: Highly efficient heterogeneous catalyst for H₂ generation via selective decomposition of hydrous hydrazine in alkaline solution[J]. Int J Hydrogen Energy,2020,45(51):27098−27113. doi: 10.1016/j.ijhydene.2020.07.048