Cu1.5Mn1.5O4 spinel type composite oxide modified with CuO for synergistic catalysis of CO oxidation

SUN Ruo-lin; ZHANG Si-ran; AN Kang; SONG Peng-fei; LIU Yuan

doi:10.1016/S1872-5813(21)60032-4

Volume 49 Issue 6

Jun. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(6): 799-808

SUN Ruo-lin, ZHANG Si-ran, AN Kang, SONG Peng-fei, LIU Yuan. Cu1.5Mn1.5O4 spinel type composite oxide modified with CuO for synergistic catalysis of CO oxidation[J]. Journal of Fuel Chemistry and Technology, 2021, 49(6): 799-808. doi: 10.1016/S1872-5813(21)60032-4

Citation:

SUN Ruo-lin, ZHANG Si-ran, AN Kang, SONG Peng-fei, LIU Yuan. Cu_1.5Mn_1.5O₄ spinel type composite oxide modified with CuO for synergistic catalysis of CO oxidation[J]. Journal of Fuel Chemistry and Technology, 2021, 49(6): 799-808. doi: 10.1016/S1872-5813(21)60032-4

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Cu_1.5Mn_1.5O₄ spinel type composite oxide modified with CuO for synergistic catalysis of CO oxidation

doi: 10.1016/S1872-5813(21)60032-4

SUN Ruo-lin^{1, 2
,},
ZHANG Si-ran^{1, 2
,
,},
AN Kang^{1, 2},
SONG Peng-fei^{1, 2},
LIU Yuan^{1, 2
,
,}

1.
Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering, Tianjin University, Tianjin 300072, China
2.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

Funds: The project was supported by the Natural Science Foundation of China (21872101, 21576192), Science and Technology Program of Tianjin, China (18ZXSZSF00070)

Received Date: 2020-11-23
Rev Recd Date: 2021-01-08

Available Online: 2021-03-30

Publish Date: 2021-06-30

Abstract

Abstract

Composite oxides of copper and manganese are widely used in oxidation reactions, and the main active component is copper-manganese spinel, whereas the copper oxide and manganese oxide show extremely low activity, despite that they are beneficial for CO oxidation. In this paper, it was found that the synergistic effect of Cu_1.5Mn_1.5O₄ and CuO could promote the catalytic oxidation of CO. The catalysts were prepared using the citric acid complexation method and they were characterized through combined the techniques of N₂-adsorption desorption, XRD, H₂-TPR, TEM, CO-TPD and O₂-TPD. The catalytic performance of various catalysts in CO oxidation was then evaluated. The results confirmed that Cu_1.5Mn_1.5O₄ modified with CuO exhibited the best catalytic performance and the highest unit surface activity (defined as the CO conversion rate per unit surface area of catalyst). CuO and Cu_1.5Mn_1.5O₄ had a synergistic effect, where O₂ was activated by CuO and it then interacted with CO, activated by Cu_1.5Mn_1.5O₄, to form CO₂, thus increasing the catalytic activity.
- spinel type composite oxide,
- copper oxide,
- synergy effect,
- catalytic oxidation,
- manganese oxide

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References(48)

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