Synthesis of ZSM-22/ZSM-23 intergrowth zeolite as the catalyst support for hydroisomerization of <i>n</i>-hexadecane

SONG Cheng-ye; MENG Ji-peng; LI Chuang; ZEYAODONG Pahaer; LIANG Chang-hai

doi:10.1016/S1872-5813(21)60061-0

Volume 49 Issue 5

May 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(5): 712-726

SONG Cheng-ye, MENG Ji-peng, LI Chuang, ZEYAODONG Pahaer, LIANG Chang-hai. Synthesis of ZSM-22/ZSM-23 intergrowth zeolite as the catalyst support for hydroisomerization of n-hexadecane[J]. Journal of Fuel Chemistry and Technology, 2021, 49(5): 712-726. doi: 10.1016/S1872-5813(21)60061-0

Citation:

SONG Cheng-ye, MENG Ji-peng, LI Chuang, ZEYAODONG Pahaer, LIANG Chang-hai. Synthesis of ZSM-22/ZSM-23 intergrowth zeolite as the catalyst support for hydroisomerization of n-hexadecane[J]. Journal of Fuel Chemistry and Technology, 2021, 49(5): 712-726. doi: 10.1016/S1872-5813(21)60061-0

Citation:

SONG Cheng-ye, MENG Ji-peng, LI Chuang, ZEYAODONG Pahaer, LIANG Chang-hai. Synthesis of ZSM-22/ZSM-23 intergrowth zeolite as the catalyst support for hydroisomerization of n-hexadecane[J]. Journal of Fuel Chemistry and Technology, 2021, 49(5): 712-726. doi: 10.1016/S1872-5813(21)60061-0

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Synthesis of ZSM-22/ZSM-23 intergrowth zeolite as the catalyst support for hydroisomerization of n-hexadecane

doi: 10.1016/S1872-5813(21)60061-0

1.
State Key Laboratory of Fine Chemicals & Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
2.
Dushanzi Petrochemical Company, PetroChina Company Limited, Karamay 833699, China

Funds: The project was supported by the National Key Research & Development Program of China (2016YFB0600305), the National Natural Science Foundation of China (22038008) and the China Postdoctoral Science Foundation (2019M651119).

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Corresponding author: chuangli@dlut.edu.cn; Tel: +86-0411-84986353, Fax: +86-0411-84986353, E-mail: changhai@dlut.edu.cn
Received Date: 2020-12-30
Rev Recd Date: 2021-01-23

Available Online: 2021-03-15

Publish Date: 2021-05-28

Abstract

Abstract

ZSM-22/ZSM-23 intergrowth zeolite was successfully synthesized by hydrothermal method with diethylamine and dimethylamine as co-structure directing agents at a dimethylamine/diethylamine molar ratio of 24. The physicochemical properties of ZSM-22/ZSM-23 intergrowth zeolite including the crystallinity, crystal morphology, texture and acidity were determined by XRD, FE-SEM, TEM, N₂-physisorption, NH₃-TPD, Py-FTIR, and so on; the performance of Pt/ZSM-22/ZSM-23 catalyst prepared by impregnation in the hydroisomerization of n-hexadecane was then investigated. The results indicate that the ZSM-22/ZSM-23 intergrowth zeolite displays the needle-like morphology with the topological structures of both ZSM-22 and ZSM-23, which is rather different from pure ZSM-22 and ZSM-23 and their mechanical mixture. After loading 0.5% Pt, the bi-functional Pt/ZSM-22/ZSM-23 catalyst exhibits excellent performance in the hydroisomerization of n-hexadecane, with a much higher yield of i-C₁₆ products (dominated by mono-branched isomers) than those obtained over Pt supported on ZSM-22 and ZSM-22 and their mechanical mixture.
- ZSM-22/ZSM-23,
- intergrowth zeolite,
- n-hexadecane,
- hydroisomerization

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References(47)

References

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