Hydrogenation of naphthalene to decalin catalyzed by Pt supported on WO<sub>3</sub> of different crystallinity at low temperature

ZHAO Tong; ZHAO Bin-bin; NIU Yu-feng; LIANG Yu; LIU Lei; DONG Jin-xiang; TANG Ming-xing; LI Xue-kuan

doi:10.1016/S1872-5813(21)60069-5

Volume 49 Issue 8

Aug. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(8): 1181-1189

ZHAO Tong, ZHAO Bin-bin, NIU Yu-feng, LIANG Yu, LIU Lei, DONG Jin-xiang, TANG Ming-xing, LI Xue-kuan. Hydrogenation of naphthalene to decalin catalyzed by Pt supported on WO3 of different crystallinity at low temperature[J]. Journal of Fuel Chemistry and Technology, 2021, 49(8): 1181-1189. doi: 10.1016/S1872-5813(21)60069-5

Citation:

ZHAO Tong, ZHAO Bin-bin, NIU Yu-feng, LIANG Yu, LIU Lei, DONG Jin-xiang, TANG Ming-xing, LI Xue-kuan. Hydrogenation of naphthalene to decalin catalyzed by Pt supported on WO₃ of different crystallinity at low temperature[J]. Journal of Fuel Chemistry and Technology, 2021, 49(8): 1181-1189. doi: 10.1016/S1872-5813(21)60069-5

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Hydrogenation of naphthalene to decalin catalyzed by Pt supported on WO₃ of different crystallinity at low temperature

doi: 10.1016/S1872-5813(21)60069-5

1.
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Funds: The project was supported by the National Natural Science Foundation of China (U1910202, 21978194), the Fund for Shanxi "1331 Project", and Program for the Shanxi Young Sanjin Scholar

Received Date: 2021-01-20
Rev Recd Date: 2021-03-03

Available Online: 2021-03-29

Publish Date: 2021-08-31

Abstract

Abstract

Two tungsten oxides (WO₃-500 and WO₃-900) were prepared at different calcination temperatures by using ammonium mettungstate as tungsten source. The physicochemical properties of WO₃ before and after Pt loading were systematically characterized by XRD, SEM, TEM, XPS, H₂-TPR, and NH₃-TPD. The influence of the crystallization degree of WO₃ on the hydrogenation of naphthalene was studied under low-temperature reaction conditions. Compared with the WO₃-900 support, WO₃-500 obtained by calcination at lower temperature exhibited a lower crystallization degree with a large amount of W⁵⁺ species, which resulted in strong interactions with Pt. The strong interaction between W species and Pt contributed to the high acidic strength. The Pt/WO₃-500 catalyst demonstrated excellent catalytic performance for naphthalene hydrogenation to decalin at low reaction temperature (70 ℃) with full conversion and 100% decalin selectivity. Under identical conditions, conversion and decalin selectivity were only 26.7% and 1.7% over the Pt/WO₃-900 catalyst. Combining the characteristics of the catalysts and their catalytic results, we revealed the promoting role of oxygen defects in WO₃-supported Pt catalysts in the hydrogenation of naphthalene to decalin, which will provide theoretical guidance for designing efficient WO₃-supported Pt catalysts for hydrogenation reactions.
- naphthalene,
- decalin,
- platinum,
- tungsten oxide,
- hydrogenation,
- catalyst,
- crystallization

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References(42)

References

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