Volume 51 Issue 7
Jul.  2023
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ZOU Ai-hua, LIN Lu-he, ZHOU Lang, KANG Zhi-bing, CAO Li-hua, HAN Qing-dong. Research progress on the synthesis and characterization of ammonia borane and metal nanocatalysts for hydrogen production the hydrolysis of ammonia borane[J]. Journal of Fuel Chemistry and Technology, 2023, 51(7): 909-920. doi: 10.1016/S1872-5813(23)60347-0
Citation: ZOU Ai-hua, LIN Lu-he, ZHOU Lang, KANG Zhi-bing, CAO Li-hua, HAN Qing-dong. Research progress on the synthesis and characterization of ammonia borane and metal nanocatalysts for hydrogen production the hydrolysis of ammonia borane[J]. Journal of Fuel Chemistry and Technology, 2023, 51(7): 909-920. doi: 10.1016/S1872-5813(23)60347-0

Research progress on the synthesis and characterization of ammonia borane and metal nanocatalysts for hydrogen production the hydrolysis of ammonia borane

doi: 10.1016/S1872-5813(23)60347-0
Funds:  The project was supported by Doctoral Program of Jiangxi Province(2017KY45), PhD Research Startup Foundation (EA201801216) and Jiangxi Provincial Department of Education Fund (GJJ2204306)
  • Received Date: 2022-10-23
  • Accepted Date: 2022-12-07
  • Rev Recd Date: 2022-12-01
  • Available Online: 2023-03-14
  • Publish Date: 2023-07-01
  • Ammonia borane (AB) is a promising chemical hydrogen storage material with high hydrogen storage density (19.6%), which can release three molar equivalents of hydrogen through catalytic hydrolysis at room temperature. However, AB releases hydrogen slowly in water, it is necessary to develop highly active metal nanocatalysts to accelerate the process of hydrolysis. This article provides an overview of the synthesis and characterization methods of ammonia borane, the mechanism of hydrolysis and catalytic hydrogen production using the unique dihydrogen key in the ammonia borane structure, and the various factors that affect the hydrogen release performance of AB.
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