Influence of pretreatment conditions on the structure and catalytic performance of supported cobalt catalysts derived from metal-organic frameworks

SUN Jia-qiang; ZHENG Shen-ke; CHEN Jian-gang

doi:10.1016/S1872-5813(23)60352-4

Volume 51 Issue 9

Sep. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(9): 1291-1297

SUN Jia-qiang, ZHENG Shen-ke, CHEN Jian-gang. Influence of pretreatment conditions on the structure and catalytic performance of supported cobalt catalysts derived from metal-organic frameworks[J]. Journal of Fuel Chemistry and Technology, 2023, 51(9): 1291-1297. doi: 10.1016/S1872-5813(23)60352-4

Citation:

SUN Jia-qiang, ZHENG Shen-ke, CHEN Jian-gang. Influence of pretreatment conditions on the structure and catalytic performance of supported cobalt catalysts derived from metal-organic frameworks[J]. Journal of Fuel Chemistry and Technology, 2023, 51(9): 1291-1297. doi: 10.1016/S1872-5813(23)60352-4

Citation:

SUN Jia-qiang, ZHENG Shen-ke, CHEN Jian-gang. Influence of pretreatment conditions on the structure and catalytic performance of supported cobalt catalysts derived from metal-organic frameworks[J]. Journal of Fuel Chemistry and Technology, 2023, 51(9): 1291-1297. doi: 10.1016/S1872-5813(23)60352-4

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Influence of pretreatment conditions on the structure and catalytic performance of supported cobalt catalysts derived from metal-organic frameworks

doi: 10.1016/S1872-5813(23)60352-4

SUN Jia-qiang^{1, 2
,},
ZHENG Shen-ke^{3
,
,},
CHEN Jian-gang^{1
,
,}

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, China

Funds: The project was supported by the National Natural Science Foundation of China (21503256, 22072175), “Strategic Priority Research Program” of the Chinese Academy of Sciences (XDA21021000), Sanju Environmental Protection New Material Company and the Research Foundation of Huanggang Normal University (2042020026)

More Information

Corresponding author: E-mail: zhengshenke@hgnu.edu.cn; chenjg@sxicc.ac.cn
Received Date: 2023-01-12
Accepted Date: 2023-02-06
Rev Recd Date: 2023-02-06

Available Online: 2023-03-24

Publish Date: 2023-09-30

Abstract

Abstract

Supported cobalt catalysts (Co@C-ZnZrO₂ and Co/ZnZrO₂) were prepared through a metal-organic frameworks (MOFs)-mediated synthesis strategy. The influence of MOFs pyrolysis on the structure and Fischer-Tropsch synthesis performance of supported cobalt catalysts was investigated. The crystalline phase and microstructure of supported cobalt catalysts were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), N₂ adsorption-desorption and X-ray photoelectron spectroscopy (XPS). The Co/ZnZrO₂ showed the CO conversion of 18.1% and the C_{5 +} selectivity of 77.4%, whereas the Co@C-ZnZrO₂ exhibited the CO conversion of 8.5% and the C_{5 +} selectivity of 35.2%. The excellent CO conversion for Co/ZnZrO₂ was attributed to the more exposure of active Co sites. Meanwhile, the activity of Co sites on Co@C-ZnZrO₂ catalyst was restricted by the carbon layer, suppressing the adsorption and activation of syngas on Co sites.
- pyrolysis,
- metal-organic frameworks,
- supported cobalt catalysts,
- Fischer-Tropsch synthesis

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References(32)

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