Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst

LIANG Chang-ming; ZAHNG An-dong; LI Zhi-he; LI Yu-feng; WANG Shao-qing; YI Wei-ming

doi:10.19906/j.cnki.JFCT.2021016

Volume 49 Issue 2

Feb. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(2): 168-177

LIANG Chang-ming, ZAHNG An-dong, LI Zhi-he, LI Yu-feng, WANG Shao-qing, YI Wei-ming. Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 168-177. doi: 10.19906/j.cnki.JFCT.2021016

Citation:

LIANG Chang-ming, ZAHNG An-dong, LI Zhi-he, LI Yu-feng, WANG Shao-qing, YI Wei-ming. Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 168-177. doi: 10.19906/j.cnki.JFCT.2021016

Citation:

LIANG Chang-ming, ZAHNG An-dong, LI Zhi-he, LI Yu-feng, WANG Shao-qing, YI Wei-ming. Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst[J]. Journal of Fuel Chemistry and Technology, 2021, 49(2): 168-177. doi: 10.19906/j.cnki.JFCT.2021016

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Hydrogen production from wood vinegar reforming over cobalt modified nickel-based catalyst

doi: 10.19906/j.cnki.JFCT.2021016

LIANG Chang-ming^{1, 2
,},
ZAHNG An-dong^{1, 2},
LI Zhi-he^{1, 2
,
,},
LI Yu-feng^{1, 2},
WANG Shao-qing^{1, 2},
YI Wei-ming^{1, 2}

1.
College of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China
2.
Shandong Research Center of Engineering & Technology for Clean Energy, Zibo 255000, China

Funds: The project was supported by National Key Research and Development Program of China (2019YFD1100600), National Natural Science Foundation of China (51606113) and Natural Science Foundation of Shandong Province (ZR2020ME185)

More Information

Corresponding author: Tel: 18678191880, E-mail: lizhihe@sdut.edu.cn
Received Date: 2020-10-15
Rev Recd Date: 2020-11-20
Publish Date: 2021-02-08

Abstract

Abstract

In order to realize high value utilization of wood vinegar, a series of Ni based catalysts with different Co contents prepared by impregnation method were tested in a fixed bed reactor. The effects of liquid space-time velocity, reaction temperature and Ni/Co ratio on hydrogen production, carbon conversion, H₂ selectivity and carbon deposition were investigated. The catalysts were characterized by XRF, H₂-TPR, SEM and elemental analysis. The results show that the gas production increases with the increase of space-time velocity of liquid, but the catalyst deactivation is accelerated when the space-time velocity of liquid is too high. High temperature is conducive to the catalytic reforming of wood vinegar to produce hydrogen. When the temperature reaches 900 °C, the hydrogen yield is the highest. With the increase of cobalt content, the carbon deposition and hydrogen yield decrease. Therefore, when the liquid space velocity is 60 h⁻¹ and the temperature is 800 °C, the Ni-0.5Co/Al₂O₃ catalyst is most conducive to the hydrogen production experiment of wood vinegar.
- wood vinegar,
- hydrogen from reforming,
- nickel-based catalyst,
- carbon deposition

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References(31)

References

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