Study on the synthesis of melem catalyst and its application in synthesis of cyclic carbonate

ZHANG Yuan-ping; LI Xiao-yun; DI Ya-li; ZHAO Yu-hua; KANG Mao-qing; LI Qi-feng; WANG Jun-wei

doi:10.19906/j.cnki.JFCT.2021020

Volume 49 Issue 3

Mar. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(3): 379-386

ZHANG Yuan-ping, LI Xiao-yun, DI Ya-li, ZHAO Yu-hua, KANG Mao-qing, LI Qi-feng, WANG Jun-wei. Study on the synthesis of melem catalyst and its application in synthesis of cyclic carbonate[J]. Journal of Fuel Chemistry and Technology, 2021, 49(3): 379-386. doi: 10.19906/j.cnki.JFCT.2021020

Citation:

ZHANG Yuan-ping, LI Xiao-yun, DI Ya-li, ZHAO Yu-hua, KANG Mao-qing, LI Qi-feng, WANG Jun-wei. Study on the synthesis of melem catalyst and its application in synthesis of cyclic carbonate[J]. Journal of Fuel Chemistry and Technology, 2021, 49(3): 379-386. doi: 10.19906/j.cnki.JFCT.2021020

Citation:

ZHANG Yuan-ping, LI Xiao-yun, DI Ya-li, ZHAO Yu-hua, KANG Mao-qing, LI Qi-feng, WANG Jun-wei. Study on the synthesis of melem catalyst and its application in synthesis of cyclic carbonate[J]. Journal of Fuel Chemistry and Technology, 2021, 49(3): 379-386. doi: 10.19906/j.cnki.JFCT.2021020

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Study on the synthesis of melem catalyst and its application in synthesis of cyclic carbonate

doi: 10.19906/j.cnki.JFCT.2021020

1.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
General Design Department of Mechanical and Electrical Engineering, Beijing 100000, China

Funds: The project was supported by Key Research and Development Program of Shanxi Province (20181101012), Key Research and Development Program of Shanxi Province (201903D121104) and Shanxi Province Science Foundation for Youths (201901D211586)

Received Date: 2020-10-14
Rev Recd Date: 2020-11-25

Available Online: 2021-03-19

Publish Date: 2021-03-19

Abstract

Abstract

In this paper, a series of mesoporous melem materials were prepared from melamine by solid-phase reaction using nano-silica (SiO₂) as the template. The mesoporous melem materials with high specific surface area (40−92 m²/g) and pore volume (0.179−0.407 cm³/g) were obtained by adjusting the ratio of SiO₂ template and melamine. The obtained melem was used as catalyst for the cycloaddition reaction between BDODGE and CO₂. The results showed that the catalytic activity was greatly improved with the increase of specific surface area of the catalysts. The catalyst mp-CN-450-2 showed the best performance. After 20 h reaction at 130 ºC, 2.0 MPa, 99.3% of BDODGE conversion and 99.5% of cyclic carbonate selectivity were acquired, respectively.
- melamine,
- mesoporous melem materials,
- epoxide,
- cyclic carbonate,
- CO₂

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References(27)

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