Co3O4 supported on Sr doped hydroxyapatite as catalysts for N2O catalytic decomposition

LIU Xiao-li; WANG Yong-zhao; ZHAO Yong-xiang

doi:10.19906/j.cnki.JFCT.2021047

Volume 49 Issue 8

Aug. 2021

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Article Navigation > Journal of Fuel Chemistry and Technology > 2021 > 49(8): 1190-1200

LIU Xiao-li, WANG Yong-zhao, ZHAO Yong-xiang. Co3O4 supported on Sr doped hydroxyapatite as catalysts for N2O catalytic decomposition[J]. Journal of Fuel Chemistry and Technology, 2021, 49(8): 1190-1200. doi: 10.19906/j.cnki.JFCT.2021047

Citation:

LIU Xiao-li, WANG Yong-zhao, ZHAO Yong-xiang. Co₃O₄ supported on Sr doped hydroxyapatite as catalysts for N₂O catalytic decomposition[J]. Journal of Fuel Chemistry and Technology, 2021, 49(8): 1190-1200. doi: 10.19906/j.cnki.JFCT.2021047

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Co₃O₄ supported on Sr doped hydroxyapatite as catalysts for N₂O catalytic decomposition

doi: 10.19906/j.cnki.JFCT.2021047

1.
Engineering Research Center of Ministry of Education for Fine Chemicals, Shanxi University, Taiyuan 030006, China
2.
School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China

Funds: The project was supported by the National Natural Science Foundation of China (U1710221) and Natural Science Foundation of Shanxi Province (201801D121043)

Received Date: 2021-01-22
Rev Recd Date: 2021-02-20

Available Online: 2021-03-16

Publish Date: 2021-08-31

Abstract

Abstract

Hydroxyapatite (HAP) and a series of Sr-doped HAP supports (Ca₉Sr₁, Ca₈Sr₂ and Ca₇Sr₃) were synthesized by co-precipitation method, and the supported Co₃O₄ catalysts were prepared by impregnation method. The prepared samples were characterized by XRD, N₂-physisorption, Raman, FT-IR, H₂-TPR, XPS, O₂-TPD and CO₂-TPD, and the N₂O decomposition performance of the catalysts were studied using a continuous flow microreactor. The experiment results show that the order of catalytic activity is Co/Ca₈Sr₂ > Co/Ca₉Sr₁ > Co/HAP > Co/Ca₇Sr₃. When the Sr/Ca ratios are 1∶9 and 2∶8, the structure of the HAP carrier is better maintained. Sr doping not only promotes the dispersion of Co₃O₄, but also increases the number of Co²⁺ and surface oxygen vacancies on the catalysts. Furthermore, an appropriate amount of Sr doping can increase the surface alkali content and basic site density of the catalyst, which is more conducive to N₂O activation and O₂ desorption.
- Sr doped,
- hydroxyapatite,
- Co₃O₄,
- N₂O decomposition

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References(45)

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