Research progress in the direct, nonoxidative conversion of methane to olefins/aromatics (II)

HUANG Xin; JIAO Xi; WANG Xiao-bo; ZHAO Ning

doi:10.19906/j.cnki.JFCT.2021073

Volume 50 Issue 1

Jan. 2022

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HUANG Xin, JIAO Xi, WANG Xiao-bo, ZHAO Ning. Research progress in the direct, nonoxidative conversion of methane to olefins/aromatics (II)[J]. Journal of Fuel Chemistry and Technology, 2022, 50(1): 44-53. doi: 10.19906/j.cnki.JFCT.2021073

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HUANG Xin, JIAO Xi, WANG Xiao-bo, ZHAO Ning. Research progress in the direct, nonoxidative conversion of methane to olefins/aromatics (II)[J]. Journal of Fuel Chemistry and Technology, 2022, 50(1): 44-53. doi: 10.19906/j.cnki.JFCT.2021073

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Research progress in the direct, nonoxidative conversion of methane to olefins/aromatics (II)

doi: 10.19906/j.cnki.JFCT.2021073

HUANG Xin^1
,,
JIAO Xi²,
WANG Xiao-bo^{1
,
,},
ZHAO Ning³

1.
College of Safety and Emergency Management Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2.
Taiyuan University of Technology, Taiyuan 030024, China
3.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Funds: The project was supported by the National Natural Science Foundation of China (21805300)

Received Date: 2021-06-11
Rev Recd Date: 2021-07-16

Available Online: 2021-08-10

Publish Date: 2022-01-25

Abstract

Abstract

Direct, nonoxidative conversion of methane towards olefins/aromatics is a hot topic in the background of “carbon peak, carbon neutrality”, owing to zero CO₂ emissions, high carbon atom utilization efficiency and hydrogen production. In the present paper, the advances of methane dehydroaromatization (MDA) and direct nonoxidative conversion of methane to olefins, aromatics, and hydrogen (MTOAH) are reviewed, based on our research works and the publications from 2018 to 2021. The determination of active sites, reaction intermediates, reaction mechanism, catalyst modification and improvement were considered. Finally, the future prospect was given for the direct nonoxidative conversion of methane to olefins/aromatics.
- methane,
- nonoxidative conversion,
- reaction mechanism,
- aromatics,
- single-atom catalysis

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References(78)

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