Synthesis of propylene carbonate from CO<sub>2</sub> catalyzed by supported imidazoles ionic liquids

HUA Shu-qing; WANG Jing-yun; SUN Jing; ZHOU Ming-dong

doi:10.19906/j.cnki.JFCT.2023027

Volume 51 Issue 10

Oct. 2023

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HUA Shu-qing, WANG Jing-yun, SUN Jing, ZHOU Ming-dong. Synthesis of propylene carbonate from CO2 catalyzed by supported imidazoles ionic liquids[J]. Journal of Fuel Chemistry and Technology, 2023, 51(10): 1506-1513. doi: 10.19906/j.cnki.JFCT.2023027

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HUA Shu-qing, WANG Jing-yun, SUN Jing, ZHOU Ming-dong. Synthesis of propylene carbonate from CO₂ catalyzed by supported imidazoles ionic liquids[J]. Journal of Fuel Chemistry and Technology, 2023, 51(10): 1506-1513. doi: 10.19906/j.cnki.JFCT.2023027

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Synthesis of propylene carbonate from CO₂ catalyzed by supported imidazoles ionic liquids

doi: 10.19906/j.cnki.JFCT.2023027

School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, China

Received Date: 2023-02-23
Accepted Date: 2023-03-22
Rev Recd Date: 2023-03-21

Available Online: 2023-04-06

Publish Date: 2023-10-10

Abstract

Abstract

Carbon dioxide is one of the most main greenhouse gases causing the global warming, however, as a rich C1 resource, the high value utilization of CO₂ has attracted wide attention. Cyclic carbonate is an excellent medium for batteries and capacitors, which is widely used in industrial production. Therefore, it is of great significance to convert CO₂ into cyclic carbonate from the viewpoint of environmental protection and resource utilization. In this paper, we synthesized a series of imidazole heterogeneous catalysts supported on polystyrene resin, and the catalytic activity for cycloaddition reaction of CO₂ in high pressure reactor was studied. The results showed that PS-TBIM-PCIMBr₂ exhibited the excellent and stable catalytic activity. PS-TBIM-PCIMBr₂ was also used to prepare propylene carbonate in the continuous fixed-bed reactor and the yield of PC was still 91% after 500 h.
- carbon dioxide,
- propylene oxide,
- cyclic carbonate,
- imidazole ionic liquid,
- heterogeneous catalyst

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References(27)

References

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