Construction of core-shell MOFs@ionic liquid materials and their performance for CO<sub>2</sub> cycloaddition reaction under atmospheric pressure

HU Feng-qun; QIU Ming-yue; YI Qun; ZHANG Ding; LI Xiang-yuan; LI Jian-chuan; SHI Li-juan; DUAN Xiao-chuan

doi:10.19906/j.cnki.JFCT.2023028

Volume 51 Issue 11

Nov. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(11): 1673-1682

HU Feng-qun, QIU Ming-yue, YI Qun, ZHANG Ding, LI Xiang-yuan, LI Jian-chuan, SHI Li-juan, DUAN Xiao-chuan. Construction of core-shell MOFs@ionic liquid materials and their performance for CO2 cycloaddition reaction under atmospheric pressure[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1673-1682. doi: 10.19906/j.cnki.JFCT.2023028

Citation:

HU Feng-qun, QIU Ming-yue, YI Qun, ZHANG Ding, LI Xiang-yuan, LI Jian-chuan, SHI Li-juan, DUAN Xiao-chuan. Construction of core-shell MOFs@ionic liquid materials and their performance for CO₂ cycloaddition reaction under atmospheric pressure[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1673-1682. doi: 10.19906/j.cnki.JFCT.2023028

Citation:

HU Feng-qun, QIU Ming-yue, YI Qun, ZHANG Ding, LI Xiang-yuan, LI Jian-chuan, SHI Li-juan, DUAN Xiao-chuan. Construction of core-shell MOFs@ionic liquid materials and their performance for CO₂ cycloaddition reaction under atmospheric pressure[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1673-1682. doi: 10.19906/j.cnki.JFCT.2023028

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Construction of core-shell MOFs@ionic liquid materials and their performance for CO₂ cycloaddition reaction under atmospheric pressure

doi: 10.19906/j.cnki.JFCT.2023028

HU Feng-qun^1
,,
QIU Ming-yue^2
,,
YI Qun^{2, 3
,},
ZHANG Ding^2
,,
LI Xiang-yuan^4
,,
LI Jian-chuan^4
,,
SHI Li-juan^{2, 4
,
,},
DUAN Xiao-chuan^{1
,
,}

1.
State Key Laboratory of Clean and Efficient Utilization of Coal-based Energy, Taiyuan university of technology, Taiyuan 030021, China
2.
School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China
3.
Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering
4.
Shanxi Tianji Coal Chemical Industry Group Co.Ltd, Changzhi 046000, China

Funds: The project was supported by the National Natural Science Foundation of China (22272125), the Joint Fund of the Yulin University and the Dalian National Laboratory for Clean Energy (YLU-DNL Fund 2021021), the Knowledge Innovation Program of Wuhan -Basic Research (2022020801010354) and Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering (2022SXTD015)

Received Date: 2023-01-17
Accepted Date: 2023-04-03
Rev Recd Date: 2023-03-29

Available Online: 2023-04-13

Publish Date: 2023-11-13

Abstract

Abstract

A flexible polymer (DP) was prepared by in-situ covalent assembly of dual-amino-functionalized ionic liquids and terephthalaldehyde. A core-shell composite (MIL-101@DP) was constructed by coating DP on the surface of metal-organic frame material MIL-101 (Cr) by post-synthesis modification, and was applied to catalyze the cycloaddition reaction of CO₂ and epichlorohydrin (ECH). MIL-101@DP retains the advantage of high specific surface area and high porosity of MIL-101 (Cr), and combines the nucleophilic site Cl⁻ and Lewis acidic site Cr^{3 +}. Under the synergistic interaction of Lewis acid sites and Lewis base sites, MIL-101@DP could efficiently catalyze activity the conversion of CO₂ and ECH reaction (ECH conversion rate can reach 99%) at atmospheric pressure, 80 ℃, 24 h and without cocatalyst. The activity did not decrease significantly after four cycles.
- MOFs@ILs composites,
- core-shell structure,
- CO₂,
- cycloaddition reaction,
- epichlorohydrin

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References(38)

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