Research progress of Fischer-Tropsch synthesis reaction mechanism

SU Jun-chao; LIU Le; HAO Qing-lan; LIU Xing-chen; TENG Bo-tao

doi:10.19906/j.cnki.JFCT.2023034

Volume 51 Issue 11

Nov. 2023

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SU Jun-chao, LIU Le, HAO Qing-lan, LIU Xing-chen, TENG Bo-tao. Research progress of Fischer-Tropsch synthesis reaction mechanism[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1565-1575. doi: 10.19906/j.cnki.JFCT.2023034

Citation:

SU Jun-chao, LIU Le, HAO Qing-lan, LIU Xing-chen, TENG Bo-tao. Research progress of Fischer-Tropsch synthesis reaction mechanism[J]. Journal of Fuel Chemistry and Technology, 2023, 51(11): 1565-1575. doi: 10.19906/j.cnki.JFCT.2023034

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Research progress of Fischer-Tropsch synthesis reaction mechanism

doi: 10.19906/j.cnki.JFCT.2023034

SU Jun-chao^1
,,
LIU Le^1
,,
HAO Qing-lan^1
,,
LIU Xing-chen^2
,,
TENG Bo-tao^{1
,
,}

1.
College of Chemical Engineering and Materials, Tianjin University of Science and Technology, Tianjin 300457, China
2.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Funds: The project was supported by the National Natural Science Foundation of China (21872125)

Received Date: 2023-03-28
Accepted Date: 2023-04-23
Rev Recd Date: 2023-04-19

Available Online: 2023-05-06

Publish Date: 2023-11-13

Abstract

Abstract

Synthesis gas (CO + H₂) conversion into clean fuels and chemicals through Fischer-Tropsch Synthesis (FTS) is an important way to clean utilization of coal and ensure China energy security. Investigation of FTS reaction mechanism at the molecular level, including of activation of synthesis gas on catalyst surface, the chain growth via C_nH_x* and C_nH_xO_y*, as well as the chain termination into alkanes, olefins, alcohols, and acids, is the key to the regulation of FTS products, the rational design and development of high-performance catalysts. It is also a hot and difficult point in catalysis science. To study FTS reaction mechanism, intermediate detection, modeling compound addition, steady-state kinetics based on reaction mechanism, steady-state isotope transient kinetic analysis (SSITKA), first-principles calculations, and reaction networks, etc. have been applied to reveal the mechanism of synthesis gas conversion. This paper systematically summarizes the research results of reaction mechanism over the past century, proposes a reasonable route map for FTS reaction, and gives a prospection of the research on FTS mechanism.
- Fischer-Tropsch Synthesis (FTS),
- reaction mechanism,
- CO hydrogenation,
- iron-based catalyst

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References(106)

References

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