Study on the catalytic performance of CO-PROX catalyzed by CuO-NiO/CeO2 in H2/CO2 rich atmosphere

CAO Dongliang; LIU Shu; JIANG Yaxin; HAN Jiao; ZHANG Caishun; WANG Honghao; HOU Xiaoning; ZHANG Lei; GAO Zhixian

doi:10.19906/j.cnki.JFCT.2023077

Volume 52 Issue 4

Apr. 2024

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Article Navigation > Journal of Fuel Chemistry and Technology > 2024 > 52(4): 577-585

CAO Dongliang, LIU Shu, JIANG Yaxin, HAN Jiao, ZHANG Caishun, WANG Honghao, HOU Xiaoning, ZHANG Lei, GAO Zhixian. Study on the catalytic performance of CO-PROX catalyzed by CuO-NiO/CeO2 in H2/CO2 rich atmosphere[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 577-585. doi: 10.19906/j.cnki.JFCT.2023077

Citation:

CAO Dongliang, LIU Shu, JIANG Yaxin, HAN Jiao, ZHANG Caishun, WANG Honghao, HOU Xiaoning, ZHANG Lei, GAO Zhixian. Study on the catalytic performance of CO-PROX catalyzed by CuO-NiO/CeO₂ in H₂/CO₂ rich atmosphere[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 577-585. doi: 10.19906/j.cnki.JFCT.2023077

Citation:

CAO Dongliang, LIU Shu, JIANG Yaxin, HAN Jiao, ZHANG Caishun, WANG Honghao, HOU Xiaoning, ZHANG Lei, GAO Zhixian. Study on the catalytic performance of CO-PROX catalyzed by CuO-NiO/CeO₂ in H₂/CO₂ rich atmosphere[J]. Journal of Fuel Chemistry and Technology, 2024, 52(4): 577-585. doi: 10.19906/j.cnki.JFCT.2023077

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Study on the catalytic performance of CO-PROX catalyzed by CuO-NiO/CeO₂ in H₂/CO₂ rich atmosphere

doi: 10.19906/j.cnki.JFCT.2023077

CAO Dongliang^1
,,
LIU Shu^1
,,
JIANG Yaxin^{1, 2
,},
HAN Jiao^1
,,
ZHANG Caishun^1
,,
WANG Honghao^1
,,
HOU Xiaoning^3
,,
ZHANG Lei^{1
,
,},
GAO Zhixian^{1
,
,}

1.
College of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, China
2.
Institute of Medical Laboratory Technology, Beijing University of Chinese medicine DongFang College, Cangzhou 061108, China
3.
School of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030000, China

Funds: The project was supported by National Natural Science Foundation of China (22379059), Applied Basic Research Program Project of Liaoning Province (2023JH2/101300224), Service Local Project of the Education Department of Liaoning Province (Enlisting and Leading) (LJKFZ20220201), General Project of the Educational Department of Liaoning Province (LJKMZ20220728) and Fundamental Research Program (Free Exploration) of Shanxi Province (20210302124338)

More Information

Corresponding author: E-mail: lnpuzhanglei@163.com; gaozx@lnpu.edu.cn
Received Date: 2023-09-02
Accepted Date: 2023-10-29
Rev Recd Date: 2023-10-26

Available Online: 2023-11-21

Publish Date: 2024-04-03

Abstract

Abstract

The CuO-NiO/CeO₂ catalyst was prepared by step impregnation method. The catalyst was characterized by XRD, BET, H₂-TPR, Raman and XPS, and the effects of the calcination temperature of NiO-CeO₂ precursor on the physicochemical properties of the catalyst and the selective oxidation of CO in H₂/CO₂ rich atmosphere were investigated. The results showed that the precursor calcination temperature mainly affected the reduction performance and oxygen vacancy content of the catalyst. When the calcination temperature is 500 ℃, the content of oxygen vacancy in the catalyst is higher, and the catalytic performance is better. When the reaction temperature is 130 ℃, the oxygen excess coefficient is 1.2, and the air speed is 20266 mL/(g·h), the CO conversion rate is 95.9%, and the CO oxidation selectivity is 86.3%.
- calcination temperature,
- CuO-NiO/CeO₂,
- CO-PROX,
- oxygen vacancy

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References(41)

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