Wet ball-milling method to prepare nanocrystalline Li4SiO4 materials for CO2 capture at high temperatures

HUANG Xue-qin; XIAO Qiang; ZHONG Yi-jun; ZHU Wei-dong

Volume 44 Issue 9

Sep. 2016

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Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(9): 1119-1124

HUANG Xue-qin, XIAO Qiang, ZHONG Yi-jun, ZHU Wei-dong. Wet ball-milling method to prepare nanocrystalline Li4SiO4 materials for CO2 capture at high temperatures[J]. Journal of Fuel Chemistry and Technology, 2016, 44(9): 1119-1124.

Citation:

HUANG Xue-qin, XIAO Qiang, ZHONG Yi-jun, ZHU Wei-dong. Wet ball-milling method to prepare nanocrystalline Li₄SiO₄ materials for CO₂ capture at high temperatures[J]. Journal of Fuel Chemistry and Technology, 2016, 44(9): 1119-1124.

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Wet ball-milling method to prepare nanocrystalline Li₄SiO₄ materials for CO₂ capture at high temperatures

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China

Funds:

the National Natural Science Foundation of China 21303166

the National Natural Science Foundation of China 21471131

Received Date: 2016-03-16
Rev Recd Date: 2016-05-24

Available Online: 2021-01-23

Publish Date: 2016-09-10

Abstract

Abstract

A wet ball-milling method followed by calcination was adopted to prepare nanocrystalline Li₄SiO₄ materials by using different silicon and lithium sources. X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM) were applied to characterize the structure and morphology of the as-prepared Li₄SiO₄ materials. CO₂ uptakes and recycle stability of the prepared Li₄SiO₄ materials were investigated on a thermogravity (TG) analyzer. Absorption equilibrium of 27.9% was achieved within 10 min at 550℃ and CO₂ partial pressure of 2.5×10⁴ Pa. The prepared nanocrystalline Li₄SiO₄ material kept the original absorption properties after 5 capture-regeneration cycles, indicating the good cycle stability. A mixture of 25% CO₂-25% N₂-50% He was introduced through the Li₄SiO₄ absorption bed, showing that CO₂ can be efficiently captured at 550℃. The adsorption capacity showed no significant decrease in the presence of 10% humidity.
- Li₄SiO₄,
- wet ball-milling,
- CO₂ capture,
- high temperature,
- moisture

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References(23)

References

[1]	《联合国气候变化框架公约》京都议定书[Z].联合国:日本京都, 1998. 《United Nations Framework Convention on Climate Change》 Kyoto Protocol[Z]. UN: Kyoto, Japan, 1998.
[2]	陈长虹, 鲍仙华.全球能源消费与CO₂排放量[J].上海环境科学, 1999, 18(2): 62-64. CHEN Chang-hong, BAO Xian-hua. Global energy consumption and CO₂ emission[J]. Shanghai Environ Sci, 1999, 18(2): 62-64.
[3]	LI H, HELENE B, DE C. Approaching sustainable H₂ production: Sorption enhanced steam reforming of ethanol[J]. J Phy Chem A, 2010, 114(11): 3834-3844. doi: 10.1021/jp906146y
[4]	张元卓, 于兹瀛, 张富民, 肖强, 钟依均, 朱伟东.纳米Li₂ZrO₃吸收剂原位移除CO₂强化水煤气变换反应制氢[J].催化学报, 2012, 33(9): 1572-1577. ZHANG Yun-zhuo, YU Zi-ying, ZHANG Fu-ming, XIAO Qiang, ZHONG Yi-jun, ZHU Wei-dong. Li₂ZrO₃ nanoparticles as absorbent for in-situ removal of CO₂ in water-gas shift reaction to enhance H₂ production[J]. Chin J Catal, 2012, 33(9): 1572-1577.
[5]	LI H, PAARA J M S, BLEKKAN E A, DE C. Towards efficient hydrogen production from glycerol by sorption enhanced steam reforming[J]. Energy Environ Sci, 2010, 3(8): 1046-1056. doi: 10.1039/b922355j
[6]	高峰, 李存梅, 王媛, 孙国华, 李开喜.树脂基球状活性炭的制备及对二氧化碳吸附性能的研究[J].燃料化学学报, 2014, 42(1): 116-120. http://www.wenkuxiazai.com/doc/dfc8895816fc700aba68fc48.html GAO Feng, LI Cun-mei, WANG Yuan, SUN Guo-hua, LI Kai-xi. Preparation of resin-base spherical activated carbon and study on adsorption properties towards CO₂[J]. J Fuel Chem Technol, 2014, 42(1): 116-120. http://www.wenkuxiazai.com/doc/dfc8895816fc700aba68fc48.html
[7]	HU J X, SHANG H, WANG J G, LUO L, XIAO Q, ZHONG Y J, ZHU W D. Highly enhanced selectivity and easy regeneration for the separation of CO₂ over N₂ on melamine-based microporous organic polymers[J]. Ind Eng Chem Res, 2014, 53(29): 11828-11837. doi: 10.1021/ie501736t
[8]	ZHAO J, SIMEON F, WANG Y, LUO G, HATTON T A. Polyethylenimine-impregnated siliceous mesocellular foam particles as high capacity CO₂ adsorbents[J]. RSC Adv, 2012, 2(16): 6509-6519. doi: 10.1039/c2ra20149f
[9]	李勇, 李磊, 闻霞, 王峰, 赵宁, 肖福魁, 魏伟, 孙予罕.二次嫁接法制备氨基修饰的硅基二氧化碳吸附剂[J].燃料化学学报, 2013, 41(9): 1122-1128. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18261.shtml LI Yong, LI Lei, WEN Xia, WANG Feng, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Synthesis of amine modified silica for the capture of carbon dioxide by a twice grafting method[J] J Fuel Chem Technol, 2013, 41(9): 1122-1128. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18261.shtml
[10]	杨刚胜, 曾淦宁, 赵强, 陈徐, 陈盛积, 艾宁.负载型氨基酸离子液体的制备及其对二氧化碳的吸附性能[J].燃料化学学报, 2016, 44(1): 106-112. YANG Gang-sheng, ZENG Gan-ning, ZHAO Qiang, CHEN Xu, CHEN Sheng-ji, AI Ning. Preparation of silica gel supported amino acid ionic liquids and their performance capacity towards carbon dioxide[J]. J Fuel Chem Technol, 2016, 44(1): 106-112.
[11]	LI J R, SCULLEY J, ZHOU H C. Metal-organic frameworks for separations[J]. Chem Rev, 2011, 112(2): 869-932. https://www.researchgate.net/publication/51704912_Metal-Organic_Frameworks_for_Separations
[12]	左臣盛, 周思宇, 孙成志, 王兴之, 刘道胜, 徐煇旼, 朴容起, 桂建舟, 刘丹.变温镁基CO₂吸附剂的制备及应用I. Na/Mg物质的量比[J].燃料化学学报, 2014, 42(7): 884-889. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18461.shtml ZUO Cheng-sheng, ZHOU Si-yu, SUN Cheng-zhi, WANG Xing-zhi, LIU Dao-sheng, XU Hui-min, PIAO Rong-qi, GUI Jian-zhou, LIU Dan. Preparation and application of magnesium-based CO₂ sorbent for temperature swing absorption I. Na/Mg mol ratio[J]. J Fuel Chem Technol, 2014, 42(7): 884-889. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18461.shtml
[13]	FLORIN N H, HAARRIS A T. Reactivity of CaO derived from nano-sized CaCO₃ particles through multiple CO₂capture-and-release cycles[J]. Chem Eng Sci, 2009, 64(2): 187-191. doi: 10.1016/j.ces.2008.10.021
[14]	XIAO Q, LIU Y F, ZHONG Y J, ZHU W D. A citrate sol-gel method to synthesize Li₂ZrO₃ nanocrystals with improved CO₂ capture properties[J]. J Mater Chem, 2011, 21(11): 3838-3842. doi: 10.1039/c0jm03243c
[15]	XIAO Q, TANG X D, LIU Y F, ZHONG Y J, ZHU W D. Comparison study on strategies to prepare nanocrystalline Li₂ZrO₃-based absorbents for CO₂ capture at high temperatures[J]. Front Chem Sci Eng, 2013, 7(3): 297-302. doi: 10.1007/s11705-013-1346-1
[16]	XIAO Q, TANG X D, ZHONG Y J, ZHU W D. A facile starch-assisted sol-gel method to synthesize K-doped Li₂ZrO₃ sorbents with excellent CO₂ capture properties[J]. J Am Ceram Soc, 2012, 95(5): 1544-1548. doi: 10.1111/jace.2012.95.issue-5
[17]	SHAN S, JIA Q, JIANG L, LI Q, WANG Y, PENG J. Preparation and kinetic analysis of Li₄SiO₄ sorbents with different silicon sources for high temperature CO₂ capture[J]. Chin Sci Bull, 2012, 57(19): 2475-2479. doi: 10.1007/s11434-012-5188-x
[18]	YIN Z, WANG K, ZHAO P, TANG X. Enhanced CO₂ chemisorption properties of Li₄SO₄, using a water hydration-calcination technique[J]. Ind Eng Chem Res, 2016, 55(4): 1142-1146. doi: 10.1021/acs.iecr.5b03746
[19]	唐晓丹.纳米Li₂ZrO₃和Li₄SiO₄二氧化碳吸收材料制备与表征[D].金华:浙江师范大学, 2012. TANG Xiao-dan. Synthesis and characterization of nanosized Li₂ZrO₃ and Li₄SiO₄ materials as carbon dioxide sorbents[D]. Jinhua: Zhejiang Normal University, 2012.
[20]	悦灵丽, 肖强, 钟依均, 朱伟东.金属元素掺杂对硅酸锂材料二氧化碳吸收性能的影响[J].现代化工, 2014, (34): 70-73. http://www.cnki.com.cn/Article/CJFDTOTAL-XDHG201408020.htm YUE Ling-li, XIAO Qiao, ZHONG Yi-jun, ZHU Wei-dong. Influence of metallic element dopant on CO₂, absorption properties of Li₄SiO₄ materials[J] Modern Chem Ind, 2014, (34): 70-73. http://www.cnki.com.cn/Article/CJFDTOTAL-XDHG201408020.htm
[21]	童沂, 黄雪芹, 许春慧, 肖强, 钟依均, 朱伟东.液相法结合冷冻干燥技术制备Li₄SiO₄材料及其高温二氧化碳吸收性能[J].物理化学进展, 2015, 04(2): 77-83. doi: 10.12677/JAPC.2015.42010 TONG Yi, HUANG Xue-qin, XU Chun-hui, XIAO Qiang, ZHONG Yi-jun, ZHU Wei-dong. A liquid phase method combined with freeze-drying technique to lithium silicate materials and their carbon dioxide absorption properties at high temperatures[J]. J Adv Phys Chem, 2015, 04(2): 77-83. doi: 10.12677/JAPC.2015.42010
[22]	VENEGAS M J, FREGOSO-ISRAEL E, ESCAMILLA R, PFEIFFER H. Kinetic and reaction mechanism of CO₂ sorption on Li₄SiO₄: Study of the particle size effect[J]. Ind Eng Chem Res, 2007, 46(8): 2407-2412. doi: 10.1021/ie061259e
[23]	CHEN D L, SHANG H, ZHU W D, KRISHNA R. Transient breakthroughs of CO₂/CH₄ and C₃H₆/C₃H₈ mixtures in fixed beds packed with Ni-MOF-74[J]. Chem Eng Sci, 2014, 117: 407-415. doi: 10.1016/j.ces.2014.07.008