Pd(OAc)<sub>2</sub> and chloranil-catalyzed oxidation of low-concentration coal mine gases to methanol

XU Feng; LICh uang; JIA Shao-yang; WU Yang; ZHU Li-hua

Volume 44 Issue 2

Feb. 2016

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(2): 239-243

XU Feng, LICh uang, JIA Shao-yang, WU Yang, ZHU Li-hua. Pd(OAc)2 and chloranil-catalyzed oxidation of low-concentration coal mine gases to methanol[J]. Journal of Fuel Chemistry and Technology, 2016, 44(2): 239-243.

Citation:

XU Feng, LICh uang, JIA Shao-yang, WU Yang, ZHU Li-hua. Pd(OAc)₂ and chloranil-catalyzed oxidation of low-concentration coal mine gases to methanol[J]. Journal of Fuel Chemistry and Technology, 2016, 44(2): 239-243.

Citation:

PDF( 694 KB)

Pd(OAc)₂ and chloranil-catalyzed oxidation of low-concentration coal mine gases to methanol

College of Safety Engineering, Heilongjiang University of Science and Technology, Harbin 150022, China

Funds:

The project was supported by the National Natural Science Foundation of China 51374098

Scientific Research Foundation for Innovation Talents of Harbin City, China 2013RFQXJ085

Financial Assistance from Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province LBH-Q14143

Training Program of the Major Research Plan of the Heilongjiang University of Science and Technology aq2013-2

More Information

Corresponding author: E-mail: xufeng79_79@163.com
Received Date: 2015-09-18
Rev Recd Date: 2015-11-26

Available Online: 2022-03-23

Publish Date: 2016-06-01

Abstract

Abstract

A self-made experimental system was used to study the catalytic oxidation of low-concentration coal mine gases to methanol in acetic acid solution.With Pd(OAc)₂ as catalyst, addition of p-benzoquinone or chloranil in the reaction system provides a beneficial environment for activation of methane, and chloranil shows a more positive effect.Chloranil amount and reaction temperature and pressure are the key factors influencing the catalytic properties.The target product yield has a positive relationship with these three factors.CH₃OH is formed from the reaction of generated H₂O₂ and CH₄.CH₃COOCH₃ is generated via two routes;one is direct oxidation of Pd²⁺ and CH₄, the other is esterification of CH₃OH and CH₃COOH.
- palladium acetate,
- chloranil,
- mine gases,
- methanol

FullText(HTML)

References(21)

References

[1]	徐锋, 赵晓鹏, 朱丽华, 王珏.瓦斯部分氧化制甲醇的实验研究[J].黑龙江科技学院学报, 2012, 22(6):558-561. http://www.cnki.com.cn/Article/CJFDTOTAL-HLJI201206002.htm XU Feng, ZHAO Xiao-peng, ZHU Li-hua, WANG Jue.Experimental investigation on partial oxidation of mine gas to methanol in liquid phase[J].J Heilongjiang Inst Sci Technol, 2012, 22(6):558-561. http://www.cnki.com.cn/Article/CJFDTOTAL-HLJI201206002.htm
[2]	XU F, ZHU L H.Synthesis of methanol from oxygen-containing coalbed methaneand environmental benefit analysis[J].Disa Adv, 2010, 3(4):407-410.
[3]	谢和平, 周宏伟, 薛东杰, 高峰.我国煤与瓦斯共采:理论、技术与工程[J].煤炭学报, 2014, 39(8):1391-1397. http://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201408003.htm XIE He-ping, ZHOU Hong-wei, XUE Dong-jie, GAO Feng.Theory, technology and engineering of simultaneous exploitation of coal and gas in China[J].J China Coal Soc, 2014, 39(8):1391-1397. http://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201408003.htm
[4]	代华明, 林柏泉, 李庆钊, 张军凯, 邹全乐.水汽对多孔介质中低浓度瓦斯燃烧特性的影响[J].北京科技大学学报, 2013, 35(10):1375-1381. http://www.cnki.com.cn/Article/CJFDTOTAL-BJKD201310018.htm DAI Hua-ming, LIN Bai-quan, LI Qing-zhao, ZHANG Jun-kai, ZOU Quan-le.Effect of aqueous vapor on the combustion characteristics of low concentration coal mine gas in a porous media burner[J].J Univ Sci Technol Beijing, 2013, 35(10):1375-1381. http://www.cnki.com.cn/Article/CJFDTOTAL-BJKD201310018.htm
[5]	MITROVICA J X, GOMEZ N, CLARK P U.The sea-level fingerprint of west antarctic collapse[J].Science, 2009, 323(5915):753. doi: 10.1126/science.1166510
[6]	徐锋, 朱丽华.甲烷液相部分氧化制甲醇的动力学影响因素[J].石油化工, 2012, 41(10):1137-1142. XU Feng, ZHU Li-hua.Kinetic influencing factors for partial oxidation of methane to methanol in liquid phase[J].Petrkchem Technol, 2012, 41(10):1137-1142.
[7]	CHEN L Y, YANG B L, ZHANG X C, DONG W, CAO K, ZHANG X P.Methane oxidation over a V₂O₅ catalyst in the liquid phase[J].Energy Fuels, 2006, 20(3):915-918. doi: 10.1021/ef050280+
[8]	SHILOV A E, SHULPIN G B.Activation of C-H bonds by metal complex[J].Chem Rev, 1997, 97(8):2879-2932. doi: 10.1021/cr9411886
[9]	STAHI S S, LABINGRE J A, BERCAW J E.Homogeneous oxidation of alkanes by electrophilic late transiytion metal[J].Angew Chem Int Ed, 1998, 37(16):2180-2192. doi: 10.1002/(ISSN)1521-3773
[10]	ARAKAWA H, ARESTA M, ARMOR J N, BARTEAU M A, BECKMAN E J, BELL A T, BERCAW J E, CREUTZ C, DINJUS E, DIXON D A, DOMEN K, DUBOIS D L, ECKERT J, FUJITA E, GIBSON D H, GODDARD W A, GOODMAN D W, KELLER J, KUBAS G J, KUNG H H, LYONS J E, MANZER L E, MARKS T J, MOROKUMA K, NICHOLAS K M, PERIANA R, QUE L, ROSTRUP-NIELSON J, SACHTLER W M, SCHMIDT L D, SEN A, SOMORJAI G A, STAIR P C, STULTS B R, TUMAS W.Catalysis research of relevance to carbon management:Progress, challenges, and opportunities[J].Chem Rev, 2001, 101(4):953-996. doi: 10.1021/cr000018s
[11]	ISTVA T H, RAYAOND A C, JOHN M M.Low-temperature methane chlonation with aqueous platinum chlorides in the presence of chlorine[J].Orgnometallies, 1993, 12(1):8-10. doi: 10.1021/om00025a004
[12]	MUKHOPADHYAY S, BELL A T.Direct catalytic sulfonation of methane with SO₂ to methanesulfonic acid(MSA) in the presence of molecular O₂[J].Chem Commun, 2003, 13(13):1590-1591.
[13]	PERIANA R A, DOUGLAS J T, GAMBLE S, TAUBE H, SATOH T, FUJⅡ H.Platinum catalysts for the high-yield oxidation of methane to a methanol derivative[J].Science, 1998, 280(5363):560-564. doi: 10.1126/science.280.5363.560
[14]	MICHALKIEWICZ B, KALUCKI K, SOSNICKI J G.Catalytic system containing metallic palladium in the process of methane partial oxidation[J].J Catal, 2003, 215(1):14-19. doi: 10.1016/S0021-9517(02)00088-X
[15]	AN Z J, PAN X L, LIU X M, HAN X W, BAO X H.Combined redox couples for catalytic oxidation of methane by dioxygen at low temperatures[J].J Am Chem Soc, 2006, 128(50):16028-16029. doi: 10.1021/ja0647912
[16]	YUAN J L, WANG L L, WANG Y.Direct oxidation of methane to a methanol derivative using molecular oxygen[J].Ind Eng Chem Res, 2011, 50:6513-6516. doi: 10.1021/ie1018113
[17]	徐锋, 朱丽华, 侯凤才, 沈斌.醋酸溶液中Pd(OAc)₂-对苯醌-CO催化甲烷选择氧化制甲醇[J].燃料化学学报, 2012, 40(9):1098-1102. doi: 10.1016/S1872-5813(12)60040-1 XU Feng, ZHU Li-hua, HOU Feng-cai, SHEN Bin.Selective oxidation of methane to methanol over Pd(OAc)₂-p-benzoquinone-CO catalyst system in acetic acid solvent[J].J Fuel Chem Technol, 2012, 40(9):1098-1102. doi: 10.1016/S1872-5813(12)60040-1
[18]	朱丽华, 徐锋, 王珏, 赵晓鹏.醋酸溶液中Pd-CuPc/Y催化甲烷选择氧化制甲醇[J].燃料化学学报, 2013, 41(8):985-990. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18240.shtml ZHU Li-hua, XU Feng, WANG Jue, ZHAO Xiao-peng.Selective oxidation of methane to methanol in acetic acid solvent over Pd-CuPc/Y catalyst[J].J Fuel Chem Technol, 2013, 41(8):985-990. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18240.shtml
[19]	ZHU L H, XU F, BI Y W, SHEN B.Influencing factors for catalytic oxidation of mine gas to methanol in liquid phase[J].Chin J Geochem, 2014, 33(2):183-186. doi: 10.1007/s11631-014-0676-0
[20]	徐锋, 李创, 王珏, 贾韶洋, 赵晓鹏, 朱丽华.瓦斯液相催化氧化制甲醇实验研究[J].黑龙江科技大学学报, 2014, 24(1):48-52. http://www.cnki.com.cn/Article/CJFDTOTAL-HLJI201401012.htm XU Feng, LI Chuang, WANG Jue, JIA Shao-yang, ZHAO Xiao-peng, ZHU Li-hua.Experiment of catalytic oxidation of mine gas to methanol in liquid phase[J].J Heilongjiang Univ Sci Technol, 2014, 24(1):48-52. http://www.cnki.com.cn/Article/CJFDTOTAL-HLJI201401012.htm
[21]	安增建.温和条件下的甲烷液相选择氧化[D].大连:中国科学院大连化学物理研究所, 2008. AN Zeng-jian.Selective oxidation of methane at mild conditions and liquid phase[D].Dalian:Dalian Instiute of Chemical Physics, Chinese Academy of Sciences, China, 2008.