吸热型碳氢燃料五环[6.3.1.02,7.03,5.09,11]十二烷的催化合成

LI Chunying; LI Fengxian; DU Yongmei; LU jian

Volume 35 Issue 05

Oct. 2007

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Article Navigation > Journal of Fuel Chemistry and Technology > 2007 > 35(05): 637-640

LI Chunying, LI Fengxian, DU Yongmei, LU jian. 吸热型碳氢燃料五环[6.3.1.02,7.03,5.09,11]十二烷的催化合成[J]. Journal of Fuel Chemistry and Technology, 2007, 35(05): 637-640.

Citation:

LI Chunying, LI Fengxian, DU Yongmei, LU jian. 吸热型碳氢燃料五环[6.3.1.02,7.03,5.09,11]十二烷的催化合成[J]. Journal of Fuel Chemistry and Technology, 2007, 35(05): 637-640.

LI Chunying, LI Fengxian, DU Yongmei, LU jian. 吸热型碳氢燃料五环[6.3.1.02,7.03,5.09,11]十二烷的催化合成[J]. Journal of Fuel Chemistry and Technology, 2007, 35(05): 637-640.

Citation:

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吸热型碳氢燃料五环[6.3.1.02,7.03,5.09,11]十二烷的催化合成

Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

Received Date: 2006-12-21
Rev Recd Date: 2007-03-24
Publish Date: 2007-10-30

Abstract

Abstract

As an endothermic hydrocarbon fuel, pentacyclo[6.3.1.02,7.03,5.09,11]dodecane has been synthesized from dicyclopentadiene catalyzed by Zn(Cu). Effects of catalyst ingredients, catalyst amount, temperature on yield of titled compound were investigated. The optimal conditions were: 15℃, n(DCPD)∶n(Zn(Cu))∶n(CH2I2)=1∶4∶8. Under the above conditions the conversion of dicyclopentadiene was 99.7% and the yield of pentacyclodocane reached 91.5%.
- endothermic hydrocarbon fuel,
- dicyclopentadiene,
- pentacyclo[6.3.1.02,7.03,5.09,11]dodecane,
- synthesis