LI Cui-qing, SUN Gui-da, LI Feng-yan, JI Ying, ZHOU Zhi-jun. 还原温度对氧化铝负载的磷化钨催化剂咔唑加氢脱氮活性影响(英)[J]. Journal of Fuel Chemistry and Technology, 2008, 36(02): 202-207.
Citation:
LI Cui-qing, SUN Gui-da, LI Feng-yan, JI Ying, ZHOU Zhi-jun. 还原温度对氧化铝负载的磷化钨催化剂咔唑加氢脱氮活性影响(英)[J]. Journal of Fuel Chemistry and Technology, 2008, 36(02): 202-207.
LI Cui-qing, SUN Gui-da, LI Feng-yan, JI Ying, ZHOU Zhi-jun. 还原温度对氧化铝负载的磷化钨催化剂咔唑加氢脱氮活性影响(英)[J]. Journal of Fuel Chemistry and Technology, 2008, 36(02): 202-207.
Citation:
LI Cui-qing, SUN Gui-da, LI Feng-yan, JI Ying, ZHOU Zhi-jun. 还原温度对氧化铝负载的磷化钨催化剂咔唑加氢脱氮活性影响(英)[J]. Journal of Fuel Chemistry and Technology, 2008, 36(02): 202-207.
A series of WP/Al2O3 catalysts with WO3 loading of 30% were prepared by impregnation and reduced in H2 for 4h at different temperatures. The catalysts were characterized by XRD, BET, TG and 31P MASNMR. Over these catalysts, the hydrodenitrogenation (HDN) of carbazole was performed at 633K and 3.0MPa. The results indicated that the active species of WP was accumulated on the support surface at a reduction temperature above 1023K. Only phosphate was detected at the chemical shift of -2.4×10-5 in the catalyst reduced at 923K. WP species was observed at the chemical shift of 2.55×10-4 with low speed of sample rotation in the catalyst reduced at 1073K, while another peak was also detected with the chemical shift of 6.88×10-4 at high speed of sample rotation; this was probably related to a similar structure of —Al—O—W—P owing to the strong interaction of active species with support, which corresponded to the species with the peak at 2θ of 40.44° by XRD. The phosphiding degree of catalyst precursor could be improved by increasing reduction temperature. WP/Al2O3 prepared at 923K exhibited the highest HDN activity with a carbazole HDN conversion of 79%. Three reaction paths of carbazole HDN were derived, which suggested that hydrodenitrogenation was superior to the direct denitrogenation.