LIU Ping, REN Jie, SUN Yu-han. Effect of template content on the physicochemical characterization and catalytic performance of SAPO-11 for the hydroisomerization of n-tetradecane[J]. Journal of Fuel Chemistry and Technology, 2008, 36(05): 610-615.
Citation:
LIU Ping, REN Jie, SUN Yu-han. Effect of template content on the physicochemical characterization and catalytic performance of SAPO-11 for the hydroisomerization of n-tetradecane[J]. Journal of Fuel Chemistry and Technology, 2008, 36(05): 610-615.
LIU Ping, REN Jie, SUN Yu-han. Effect of template content on the physicochemical characterization and catalytic performance of SAPO-11 for the hydroisomerization of n-tetradecane[J]. Journal of Fuel Chemistry and Technology, 2008, 36(05): 610-615.
Citation:
LIU Ping, REN Jie, SUN Yu-han. Effect of template content on the physicochemical characterization and catalytic performance of SAPO-11 for the hydroisomerization of n-tetradecane[J]. Journal of Fuel Chemistry and Technology, 2008, 36(05): 610-615.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China|2.Graduate School of the Chinese Academy of Sciences, Beijing 100039, China
Different SAPO-11 have been synthesized hydrothermally using the mixed template of di-n-propylamine (DPA) and di-iso-propylamine (DIPA) by varying the template content or the ratio of DPA/DIPA. Products were characterized using X-ray diffraction (XRD), N2 adsorption, NH3temperatureprogramed desorption (TPD) and 29Si MAS NMR, and evaluated towards n-tetradecane skeletal isomerization. The results indicated that the template had strong influence on the crystallinity, the Si distribution and thus the acidity of SAPO11. The sample prepared at template content of 1.5 and w (DPA) of 66% possessed small silicon domains and large amount of Si(n Al)(0 < n < 4) sites, and the catalyst obtained with this method performed highest catalytic activity in the hydroisomerization of n-tetradecane due to the high acidity.