YAO Yao, Zhang-Shu-Le, Zhong- Qin, Liu-Xiao-Xiao. Low temperature selective catalytic reduction of NO over manganese supported on TiO2 nanotubes[J]. Journal of Fuel Chemistry and Technology, 2011, 39(09): 694-701.
Citation:
YAO Yao, Zhang-Shu-Le, Zhong- Qin, Liu-Xiao-Xiao. Low temperature selective catalytic reduction of NO over manganese supported on TiO2 nanotubes[J]. Journal of Fuel Chemistry and Technology, 2011, 39(09): 694-701.
YAO Yao, Zhang-Shu-Le, Zhong- Qin, Liu-Xiao-Xiao. Low temperature selective catalytic reduction of NO over manganese supported on TiO2 nanotubes[J]. Journal of Fuel Chemistry and Technology, 2011, 39(09): 694-701.
Citation:
YAO Yao, Zhang-Shu-Le, Zhong- Qin, Liu-Xiao-Xiao. Low temperature selective catalytic reduction of NO over manganese supported on TiO2 nanotubes[J]. Journal of Fuel Chemistry and Technology, 2011, 39(09): 694-701.
Titanate nanotubes were synthesized hydrothermally with commercial TiO2 nanoparticles in NaOH; after calcination at 400℃, TiO2 nanotubes were obtained and used as the support to prepare manganese catalyst (MnOx/TiNT) by wet-impregnation for low temperature selective catalytic reduction of NO (SCR). The results of BET, TEM, XRD and TG measurements showed that TiO2 nanotubes exhibit well-defined TiO2 anatase phase after calcination at 400℃ and manganese particles are highly dispersed on the wall of TiO2 nanotubes. The effects of active component loading, space velocity, oxygen content, \[NH3\]/\[NO\] ratio and NO concentration on the SCR performance of MnOx/TiNT were investigated in a simulated flue gas. Under the reaction conditions of 150℃, \[NH3\]/\[NO\] of 1.2, \[O2\] of 3%, \[NO\] of 0.06%, GHSV of 23613.8h-1 and Mn loading of 5%~15%(mass ratio), NO conversion exceeds 95%. The catalyst is deactivated in the presence of H2O at 180℃, but its activity can be recovered almost completely when cutting off H2O; higher resistance to H2O is observed at higher temperature. The presence of SO2 can also deactivate the catalyst gradually; however, the catalyst exhibits better resistance toward SO2 in the presence of H2O than that without H2O. The SCR activity of MnOx/TiNT catalyst deactivated by SO2 rises gradually after cutting off H2O + SO2, but cannot be recovered to its initial level.