Volume 40 Issue 05
May  2012
Turn off MathJax
Article Contents
SUN Ting-ting, WU Zheng-shun, LIU Xiao-yan, TANG Ning-lu. Experimental study on Li4SiO4 adsorption capability for CO2 capture[J]. Journal of Fuel Chemistry and Technology, 2012, 40(05): 636-640.
Citation: SUN Ting-ting, WU Zheng-shun, LIU Xiao-yan, TANG Ning-lu. Experimental study on Li4SiO4 adsorption capability for CO2 capture[J]. Journal of Fuel Chemistry and Technology, 2012, 40(05): 636-640.

Experimental study on Li4SiO4 adsorption capability for CO2 capture

Funds:  国家自然科学基金(51076058);煤燃烧国家重点实验室开放基金。
  • Received Date: 2011-07-13
  • Rev Recd Date: 2011-10-09
  • Publish Date: 2012-05-31
  • Li4SiO4 used as a revolving CO2 absorbent at determinate temperature can be synthesized with SiO2 and Li2CO3 by solid state reaction at high temperature. The crystal structure and microstructure of Li4SiO4 were characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM), respectively. The CO2-adsorption capability of Li4SiO4 was studied by TGA preliminarily, and then was tested in a small experimental apparatus. The results show that the CO2-adsorption capability is influenced by the preparation temperature of Li4SiO4 synthesis, and it was the largest at 700 ℃. The maximum adsorption capability could achieve 34%. Besides, the adsorption capability increases as the adsorption temperature going up and longer time. When CO2 concentration was 75%, 67%, 60%, the adsorption capability could respectively reach 6.68 mmol/g, 3.37 mmol/g, 2.02 mmol/g.
  • loading
  • 李新春, 孙永斌. 二氧化碳捕集现状和展望[J]. 能源技术经济, 2010, 22(4): 21-26. (LI Xin-chun, SUN Yong-bin. Status quo and prospect of the carbon dioxide capture[J]. Energy Technology and Economics, 2010, 22(4):21-26.)
    韩玉杰. CO2的捕集和封存技术的现状、 前景与挑战[J]. 应用能源技术, 2009, (6): 38-40. (HAN Yu-jie. Present state, prospect and challenge of CO2 capture and sequestration[J]. Applied Energy Technology, 2009, (6): 38-40.)
    全浩, 温雪峰, 郭琳琳. CO2捕集和地下封存技术的现状及发展趋势(一)[J]. 煤炭工程,2007, (12): 75-78. (QUAN Hao, WEN Xue-feng, GUO Lin-lin. Present state and development tendency of CO2 capture and geologic sequestration (一)[J]. Coal Engineering, 2007, (12):75-78.)
    MIRACCA I, SEN K I, ASSINK J, COULTER C, CURRAN L, LOWE C, MOURE G T, SCHLASNER S. The CO2 capture project (CCP): Results from phase Ⅱ (2004-2009)[J]. Energy Procedia, 2009, 1(1): 55-62.
    WANG J, MANOVIC V, WU Y, ANTHONY E J. A study on the activity of CaO-based sorbents for capturing CO2 in clean energy processes[J]. Appl Energy, 2010, 87(4): 1453-1458.
    MANOVIC V, ANTHONY E J. Sintering and formation of a nonporous carbonate shell at the surface of CaO-based sorbent particles during CO2-capture cycles[J]. Energy Fuels, 2010, 24(10):5790-5796.
    FLORIN N H, HARRIS A T. Reactivity of CaO derived from nano-sized CaCO3 particles through multiple CO2 capture-and-release cycles[J]. Chem Eng Sci, 2009, 64(2):187-191.
    OLICARES-MARíN M, DRAGE T C, MERCEDES MAROTO-VALER M. Novel lithium-based sorbents from fly ashes for CO2 capture at high temperatures[J]. Int J Greenhouse Gas Control, 2010, 4(4): 623-629.
    YAMAGUCHI T, NIITSUMA T, NAIR B N, NAKAGAWA K. Lithium silicate based membranes for high temperature CO2 separation[J]. J Membr Sci, 2007, 294(1/2): 16-21.
    ESCOBEDO BRETADO M, GUZMN VELDERRAIN V, LARDIZBAL GUTIRREZ D, COLLINS-MARTíNEZ V, LOPEZ ORTIZ A. A new synthesis route to Li4SiO4 as CO2 catalytic/sorbent[J]. Catal Today, 2005, 107-108: 863-867.
    袁文辉, 梁杰, 李莉. Li4SiO4的制备表征及CO2吸附与模拟[J]. 化工进展,2009, 28(Suppl): s306-s309. (YUAN Wen-hui, LIANG Jie, LI Li. The preparation of Li4SiO4 characterization and CO2 adsorption/simulation[J]. Chemical Industry and Engineering Progress, 2009, 28(Suppl): s306-s309.)
    王银杰, 其鲁, 江卫军. 高温下硅酸锂吸收CO2的研究[J]. 无机化学学报, 2006, 22(2):268-272. (WANG Yin-jie, QI Lu, JIANG Wei-jun. CO2 absorption of Li4SiO4 at high temperature[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(2): 268-272.)
    FAUTH D J, FROMMELL E A, HOFFMAN J S, REASBECK R P, PENNLINE H W. Eutectic salt promoted lithium zirconate: Novel high temperature sorbent for CO2 capture[J]. Fuel Process Technol, 2005, 86(14/15): 1503-1521.
    王银杰, 代克化, 冯华君, 朱永双, 其鲁. 锆酸锂的合成及其吸收CO2性能研究[J]. 北京大学学报(自然科学版), 2006, 42(Suppl): s87-s90. (WANG Yin-jie, DAI Ke-hua, FENG Hua-jun, ZHU Yong-shuang, QI Lu. Synthesis and CO2-absorption properties of lithium zirconate[J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2006, 42(Suppl): s87-s90.)
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1414) PDF downloads(727) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return