Catalytic hydrodeoxygenation of vegetable oil over Ni catalysts to produce second-generation biodiesel

ZUO Hua-liang; LIU Qi-ying; WANG Tie-jun; SHI Na; LIU Jian-guo; MA Long-long

Volume 40 Issue 09

Sep. 2012

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Article Navigation > Journal of Fuel Chemistry and Technology > 2012 > 40(09): 1067-1073

ZUO Hua-liang, LIU Qi-ying, WANG Tie-jun, SHI Na, LIU Jian-guo, MA Long-long. Catalytic hydrodeoxygenation of vegetable oil over Ni catalysts to produce second-generation biodiesel[J]. Journal of Fuel Chemistry and Technology, 2012, 40(09): 1067-1073.

Citation:

ZUO Hua-liang, LIU Qi-ying, WANG Tie-jun, SHI Na, LIU Jian-guo, MA Long-long. Catalytic hydrodeoxygenation of vegetable oil over Ni catalysts to produce second-generation biodiesel[J]. Journal of Fuel Chemistry and Technology, 2012, 40(09): 1067-1073.

Citation:

ZUO Hua-liang, LIU Qi-ying, WANG Tie-jun, SHI Na, LIU Jian-guo, MA Long-long. Catalytic hydrodeoxygenation of vegetable oil over Ni catalysts to produce second-generation biodiesel[J]. Journal of Fuel Chemistry and Technology, 2012, 40(09): 1067-1073.

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Catalytic hydrodeoxygenation of vegetable oil over Ni catalysts to produce second-generation biodiesel

1.
Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
2.
Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 2011-11-09
Rev Recd Date: 2012-01-27
Publish Date: 2012-09-29

Abstract

Abstract

A series of Ni catalysts supported on HY, SiO₂, γ-Al₂O₃ and SAPO-11 were prepared by incipient-wetness impregnation and characterized by XRD, NH₃-TPD, H₂-TPR, BET and SEM techniques. Their catalytic performance in hydrodeoxygenation (HDO) of vegetable oil to produce the second-generation biodiesel was evaluated in a semi-batch reactor by using methyl palmitate as a model compound. Owning to the weak and medium acidic properties of SAPO-11, the Ni/SAPO-11 catalyst exhibits high activity in the HDO of methyl palmitate and capability of inhibiting the feedstock and long-chain alkanes from being cracked. The effect of Ni loading, reaction temperature and pressure on the HDO behavior over Ni/SAPO-11 catalyst was considered. Under 220℃ and 2 MPa, Ni/SAPO-11 catalyst with a Ni loading of 7% performs best in HDO; the conversion of methyl palmitate and the selectivity towards C_9~16 alkanes reach 99.8% and 92.71%, respectively.
- vegetable oil,
- methyl palmitate,
- hydrodeoxygenation,
- Ni catalysts,
- second-generation biodiesel

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References(32)

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