Volume 40 Issue 09
Sep.  2012
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GAO Zheng-yang, YIN Li-bao, ZHOU Li-ming, ZHONG Jun, ZHENG Shuang-qing. Formation characteristics of Hg particulates during combustion of different coals[J]. Journal of Fuel Chemistry and Technology, 2012, 40(09): 1135-1141.
Citation: GAO Zheng-yang, YIN Li-bao, ZHOU Li-ming, ZHONG Jun, ZHENG Shuang-qing. Formation characteristics of Hg particulates during combustion of different coals[J]. Journal of Fuel Chemistry and Technology, 2012, 40(09): 1135-1141.

Formation characteristics of Hg particulates during combustion of different coals

  • Received Date: 2011-12-23
  • Rev Recd Date: 2012-03-23
  • Publish Date: 2012-09-29
  • Combustion experiments (3 coals, 3 coals with addition of 1%, 3%, 5% CaBr2 and Ca(CH3COO)2, and a coal with addition of Fe2O3) were conducted on a high temperature electric heating reactor at 1 250℃. The fly ashes were collected and the particulate Hg (Hgp) contents were analyzed. The specific surface area, EDS, and XRD analysis were performed. It is indicated that the Hgp formations characteristics of the 3 coals were rather different. The ash of coal 3 has the largest specific surface area, but the lowest Hg content and Hgp ratio in its ash. CaBr2 addition leads to significant increment of Hg content in ash and Hgp ratio. Ca (H3COO)2 and Fe2O3 addition do not lead to prominent increase of Hgp.
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  • SRIVASTAVA R, HUTSON N, MARTIN B, PRINCIOTTA F, STAUDT J. Control of mercury emissions from coal-fired electric utility boilers: An overview of the status of mercury control technologies[J]. Environ Sci Technol, 2006, 40(5): 1385-1393.
    YUDOVICH Y E, KETRIS M P. Mercury in coal: A review Part 2. Coal use and environmental problem[J]. Int J Coal Geol, 2005, 62(3): 135-165.
    PAVLISH J H, SONDREAL E A, MANN M D, OLSON E S, GALBREATH K C, LAUDAL D L, BENSON S A. Status review of mercury control options for coal-fired power plant[J]. Fuel Process Technol, 2003, 82(2/3): 89-165.
    WILCOX J, RUPP E, YING S-C, LIM D-H, NEGREIRA A S, KIRCHOFER A, FENG F, LEE K. Mercury adsorption and oxidation in coal combustion and gasification processes[J].Int J Coal Geol, 2012, 90/91: 4-20.
    PUDASAINEE D, KIM J-H, YOON Y-S, SEO Y-C. Oxidation, reemission and mass distribution of mercury in bituminous coal fired power plants with SCR, CS ESP and wet FGD[J]. Fuel, 2012, 93(3): 312-318.
    ABAD-VALLE P, LOPEZ-ANTON M A,DIAZ-SOMOANO M, MARTINEZ-TARAZONA M R.The role of unburned carbon concentrates from fly ashes in the oxidation and retention of mercury[J]. Chem Eng J, 2011, 174(1): 86-92.
    PAVLISH J H, HAMRE L L, ZHUANG Y. Mercury control technologies for coal combustion and gasification systems[J]. Fuel, 2010, 89(4): 838-847.
    ANTONIA LPEZ-ANTN M, ABAD-VALLE P, DAZ-SOMOANO M, SUREZ-RUIZ I, ROSA MARTNEZ-TARAZONA M. The influence of carbon particle type in fly ashes on mercury adsorption[J]. Fuel, 2009, 88(7): 1194-1200.
    KOSTOVA I J, HOWER J C, MASTALERZ M, VASSILEV S V. Mercury capture by selected Bulgarian fly ashes: Influence of coal rank and fly ash carbon pore structure on capture efficiency[J]. Appl Geochem, 2011, 26(1): 18-27.
    HUGHES K J, MA L, PORTER R T J, POURKASHANIAN M. Mercury transformation modelling with bromine addition in coal derived flue gases[J]. Comp Aided Chem Eng, 2011, 29(1): 171-175.
    ZHUANG Y, CHEN C, TIMPE R, PAVLISH J. Investigations on bromine corrosion associated with mercury control technologies in coal flue gas[J]. Fuel, 2009, 88(9):1692-1697.
    LIU S-H, YAN N-Q, LIU Z-R, QU Z, PAUL WANG H, CHANG S-G, MILLER C. Using bromine gas to enhance mercury removal from flue gas of coal-fired power plants. [J]. Environ Sci Technol,2007, 41(4): 1405-1412.
    YAN N-Q, LIU S-H, CHANG S-G. Method for the study of gaseous oxidants for the oxidation of mercury gas[J]. Ind Eng Chem Res, 2005, 44(15): 5567-5574.
    NIMMO W, PATSIAS A A, HAMPARTSOUMIAN E, GIBBS B M, WILLIAMS P T. Simultaneous reduction of NOx and SO2 emissions from coal combustion by calcium magnesium acetate[J]. Fuel, 2004, 83(2): 149-155.
    SLIGER R N, KRAMLICH J C, MARINOV N M. Towards the development of a chemical kinetic model for the homogeneous oxidation of mercury by chlorine species[J]. Fuel Process Technol, 2000, 65-66: 423-438.
    HALL B, LINDQVIST O, LJUNGSTROEM E. Mercury chemistry in simulated flue gases related to waste incineration conditions[J]. Environ Sci Technol, 1990, 24(1): 108-111.
    ZHUANG Y, THOMPSON J S, ZYGARLICKE C J, PAVLISH J H. Impact of calcium chloride addition on mercury transformations and control in coal flue gas[J]. Fuel, 2007, 84(15): 2351-2359.
    XIN G, ZHAO P, ZHENG C.Theoretical study of different speciation of mercury adsorption on CaO (001) surface[J]. Proc Combust Inst, 2009, 32(2): 2693-2699.
    PAVLISH J H, SONDREAL E A, MANN1 M D, OLSON E S,GALBREATH K C, LAUDAL D L, BENSON S A. Status review of mercury control options for coal-fired power plants[J]. Fuel Process Technol, 2003, 82(2/3): 89-165.
    SUBIR M, ARIYA P A, DASTOOR A P. A review of uncertainties in atmospheric modeling of mercury chemistry:I Uncertainties in existing kinetic parameters-Fundamental limitations and the importance of heterogeneous chemistry[J]. Atmos Eviron, 2011, 45(32): 5664-5676.
    GALBREATH K C, ZYGARLICKE C J, TIBBETTS J E, SCHULZ R L, DUNHAM G E. Effects of NOx, α-Fe2O3, γ-Fe2O3, and HCl on mercury transformations in a 7-kW coal combustion system[J]. Fuel Process Technol, 2004, 86(4): 429-448.
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