Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite

ZHOU Jie; ZHAO Ning; XIAO Fu-kui; WEI Wei; SUN Yu-han

Volume 40 Issue 11

Nov. 2012

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Article Navigation > Journal of Fuel Chemistry and Technology > 2012 > 40(11): 1323-1327

ZHOU Jie, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite[J]. Journal of Fuel Chemistry and Technology, 2012, 40(11): 1323-1327.

Citation:

ZHOU Jie, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite[J]. Journal of Fuel Chemistry and Technology, 2012, 40(11): 1323-1327.

ZHOU Jie, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite[J]. Journal of Fuel Chemistry and Technology, 2012, 40(11): 1323-1327.

Citation:

ZHOU Jie, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite[J]. Journal of Fuel Chemistry and Technology, 2012, 40(11): 1323-1327.

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Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite

1.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;
2.
Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
3.
Low Carbon Energy Conversion Center, Shanghai Advanced Research Institute of Chinese Academy of Sciences, Shanghai 201203, China

Received Date: 2012-03-31
Rev Recd Date: 2012-06-01
Publish Date: 2012-11-30

Abstract

Abstract

Selective oxidation of glycerol (GLY) to dihydroxyacetone (DHA) was studied over Bi-Pt/H-mordenite catalyst. The results indicated that the surface area has little effect on the performance of the supported catalysts. H-mordenite as support inhibits the cracking of GLY and thus promotes the selectivity to DHA. Protic solvents such as ethanol and water favor the formation of DNA from GLY. Over the Bi-Pt/H-mordenite catalyst of optimum composition (1% Bi and 5% Pt by weight) and under the optimum reaction conditions (353 K, reaction time of 2~4 h, air flow rate of 20 mL/min, and GLY concentration of 10%), the conversion of GLY and selectivity to DHA reach 70.6% and 61.0%, respectively.
- glycerol,
- selective oxidation,
- Bi-Pt/H-mordenite,
- dihydroxyacetone

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References(30)

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