Volume 41 Issue 02
Feb.  2013
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WANG Yu-rong, WANG Shu-rong, WANG Xiang-yu, GUO Zuo-gang. Molecular distillation separation characteristic of bio-oil under different pressures[J]. Journal of Fuel Chemistry and Technology, 2013, 41(02): 177-182.
Citation: WANG Yu-rong, WANG Shu-rong, WANG Xiang-yu, GUO Zuo-gang. Molecular distillation separation characteristic of bio-oil under different pressures[J]. Journal of Fuel Chemistry and Technology, 2013, 41(02): 177-182.

Molecular distillation separation characteristic of bio-oil under different pressures

  • Received Date: 2012-06-12
  • Rev Recd Date: 2012-08-06
  • Publish Date: 2013-02-28
  • The separation properties of sensitive bio-oil using molecular distillation technology were investigated under different distillation pressures. Crude bio-oil is divided into distillate fraction and residual fraction after the molecular distillation process. The yield of distillate fraction increases obviously with the decline of pressure, which achieves the highest value of 56.50% under 700Pa. Most of water is enriched in the distillate fraction while water in residual fractions is effectively removed; water content in the residual fraction under 700Pa is reduced to 4.20%. The distribution of some typical compounds, including acetic acid, phenol, furfural, levoglucosan, etc, under different distillation pressures was studied and the separation characteristic of these typical compounds was obtained; based on that, a separation factor model was proposed and a quantitative evaluation was made on the enrichment behaviors of 14 compounds in bio-oil.
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  • VENDERBOSCH R H, PRINS W. Fast pyrolysis technology development[J]. Biofuel Bioprod Bior, 2010, 4(2): 178-208.
    王琦, 刘倩, 贺博, 王树荣, 骆仲泱, 岑可法. 流化床生物质快速热解制取生物油试验研究[J]. 工程热物理学报, 2008, 29(5): 885-888. (WANG Qi, LIU Qian ,HE Bo, WANG Shu-rong, LUO Zhong-yang, CEN Ke-fa. Experimental research on biomass flash pyrolysis for bio-oil in a fluidized bed reactor[J]. Journal of Engineering Thermophysics, 2008, 29(5): 885-888.)
    TAMIDI M, HEW K L, YUSUP S, LEE K T. Catalytic cracking of bio-oil to organic liquid product (OLP)[J]. Bioresour Technol, 2010, 101(22): 8855-8858.
    郭晓亚, 颜涌捷. 生物质快速裂解油的催化裂解精制[J]. 化学反应工程与工艺, 2005, 21(3): 227-233. (GUO Xiao-ya, YAN Yong-jie. Catalytic cracking of biomass fast pyrolysis oil[J]. Chemical Reaction Engineering and Technology. 2005, 21(3): 227-233.)
    郭春霞, 蒋晓原, 楼辉, 郑小明. 微波条件下固体酸催化剂催化酯化生物油的研究[J]. 燃料化学学报, 2011, 39(2): 103-108. (GUO Chun-xia, JIANG Xiao-yuan, LOU Hui, ZHENG Xiao-ming. Catalytic upgrading of bio-oil over solid acid catalysts under microwave heating [J]. Journal of Fuel Chemistry and Technology, 2011, 39(2): 103-108.)
    张琦, 常杰, 王铁军, 吴创之, 徐莹, 朱锡锋. 固体酸改质生物油的研究[J]. 燃料化学学报, 2006, 34(6): 680-684. (ZHANG Qi, CHANG Jie, WANG Tie-jun, WU Chuang-zhi, XU Ying, ZHU Xi-feng. Study on upgrading of bio-oil catalyzed over solid acids[J]. Journal of Fuel Chemistry and Technology, 2006, 34(6): 680-684.)
    姚燕, 王树荣, 骆仲泱, 岑可法. 生物油轻质馏分加氢试验研究[J]. 工程热物理学报, 2008, 29(4): 715-719. (YAO Yan, WANG Shu-rong, LUO Zhong-yang, CEN Ke-fa. Experimental research on catalytic hydrogenation of light fraction of bio-oil[J]. Journal of Engineering Thermophysics, 2008, 29(4): 715-719.)
    崔洪友, 王景华, 魏书芹, 禚淑萍, 李志合, 王丽红, 易维明. 生物油超临界CO2酯化反应研究[J]. 燃料化学学报, 2010, 38(6): 673-678. (CUI Hong-you, WANG Jing-hua, WEI Shu-qin, ZHUO Shu-ping, LI Zhi-he, WANG Li-hong, YI Wei-ming. Upgrading bio-oil by esterification under supercritical CO2 conditions[J]. Journal of Fuel Chemistry and Technology, 2010, 38(6): 673-678.)
    CZERNIK S, BRIDGWATER A V. Overview of applications of biomass fast pyrolysis oil[J]. Energy Fuels, 2004, 18(2): 590-598.
    GAYUBO A, AGUAYO A, ATUTXA A, AGUADO R, OLAZAR M, BIBAO J. Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite: II Aldehydes, ketones, and acids[J]. Ind Eng Chem Res, 2004, 24(11): 2619-2626.
    SRINIVAS S, DALAI A, BAKHSHI N. Thermal and catalytic upgrading of a biomass-derived oil in a dual reaction system[J]. Can J Chem Eng, 2000, 78(2): 343-354.
    FURIMSKY E. Catalytic hydrodeoxygenation[J]. Appl Catal A, 2000, 199(2): 147-190.
    GRAÇA I, RIBEIRO F, CERQUEIRA H, LAM Y L, ALMEIDA M. Catalytic cracking of mixtures of model bio-oil compounds and gasoil[J]. Appl Catal B, 2009, 90(3/4): 556-563.
    陈尔旺, 陈明强, 王君, 刘少敏,王华. 生物油分离技术的研究进展[J]. 广州化工, 2011, 39(3): 3-5. (CHEN Er-wang, CHEN Ming-qiang, WANG Jun, LIU Shao-min, WANG Hua. Research progress of bio-oil separation[J]. Guangzhou Chemical Industry, 2011, 39(3): 3-5.)
    徐绍平, 刘娟, 李世光, 刘淑琴, 路庆花. 杏核热解生物油萃取-柱层析分离分析和制备工艺[J]. 大连理工大学学报, 2005, 54(4): 505-510. (XU Shao-ping, LIU Juan, LI Shi-guang, LIU Shu-qin, LU Qing-hua. Solvent extraction-column chromatographic separation of bio-oil from fast pyrolysis of apricot stone and manufacture technology[J]. Journal of Dalian University of Technology, 2005, 45(4): 505-510.)
    BOUCHER M, CHAALA A, ROY C. Bio-oils obtained by vacuum pyrolysis of softwood bark as a liquid fuel for gas turbines: Part I Properties of bio-oil and its blends with methanol and a pyrolytic aqueous phase[J]. Biomass Bioenergy, 2000, 19(5): 337-350.
    郭祚刚, 王树荣, 朱颖颖, 岑可法. 生物油酸性组分分离精制研究[J]. 燃料化学学报, 2009, 37(1): 49-52. (GUO Zuo-gang, WANG Shu-rong,ZHU Ying-ying,LUO Zhong-yang,CEN Ke-fa. Separation of acid compounds for refining biomass pyrolysis oil[J]. Journal of Fuel Chemistry and Technology, 2009, 37(1): 49-52.)
    WANG S, GU Y, LIU Q, YAO Y, GUO Z, LUO Z, CEN K. Separation of bio-oil by molecular distillation[J]. Fuel Process Technol, 2009, 90(5): 738-745.
    GUO Z, WANG S, GU Y, XU G, LI X, LUO Z. Separation characteristics of biomass pyrolysis oil in molecular distillation[J]. Sep Purif Technol, 2010, 76(1): 52-57.
    LUO Z Y, WANG S R, LIAO Y F, ZHOU J S, GU Y L, CEN K F. Research on biomass fast pyrolysis for liquid fuel[J]. Biomass Bioenergy, 2004, 26(5): 455-462.
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