Adsorptive performance of benzothiophene using metal organic framework material MOF-5

GONG Rui; ZHOU Li-mei; MA Na; HU Jue; CHEN Jian-rong; HU Xin; DAI Wei

Volume 41 Issue 05

May 2013

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GONG Rui, ZHOU Li-mei, MA Na, HU Jue, CHEN Jian-rong, HU Xin, DAI Wei. Adsorptive performance of benzothiophene using metal organic framework material MOF-5[J]. Journal of Fuel Chemistry and Technology, 2013, 41(05): 607-612.

Citation:

GONG Rui, ZHOU Li-mei, MA Na, HU Jue, CHEN Jian-rong, HU Xin, DAI Wei. Adsorptive performance of benzothiophene using metal organic framework material MOF-5[J]. Journal of Fuel Chemistry and Technology, 2013, 41(05): 607-612.

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Adsorptive performance of benzothiophene using metal organic framework material MOF-5

1.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China;
2.
College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004, China

Received Date: 2012-10-31
Rev Recd Date: 2013-01-02
Publish Date: 2013-05-30

Abstract

Abstract

Removal of benzothiophenic compounds from fuels plays a key role in deep desulfurization. The adsorptive performance of benzothiophene with typical Metal-Organic Frameworks material MOF-5 was investigated using batch experiments. Results showed that the adsorption kinetics data of benzaothiophene onto MOF-5 from model fuel could be well described by a pseudo-second-order model. The adsorption equilibrium data of benzaothiophene onto MOF-5 fitted well to the Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models (Freundlich>D-R>Langmuir). Thermodynamic parameters showed that the adsorption of benzaothiophene onto MOF-5 was spontaneous and endothermic in nature.
- MOF-5,
- benzothiophene,
- adsorptive performance

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References(19)

References

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