Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl<sub>2</sub>

LIU Hai-chao; LIU Ji-quan; GUO Qi-wen; LI Lian-di; LI Hong-guang; WEN Xia; XIAO Fu-kui; ZHAO Ning; WEI Wei; SUN Yu-han

Volume 41 Issue 09

Sep. 2013

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Article Navigation > Journal of Fuel Chemistry and Technology > 2013 > 41(09): 1146-1152

LIU Hai-chao, LIU Ji-quan, GUO Qi-wen, LI Lian-di, LI Hong-guang, WEN Xia, XIAO Fu-kui, ZHAO Ning, WEI Wei, SUN Yu-han. Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl2[J]. Journal of Fuel Chemistry and Technology, 2013, 41(09): 1146-1152.

Citation:

LIU Hai-chao, LIU Ji-quan, GUO Qi-wen, LI Lian-di, LI Hong-guang, WEN Xia, XIAO Fu-kui, ZHAO Ning, WEI Wei, SUN Yu-han. Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl₂[J]. Journal of Fuel Chemistry and Technology, 2013, 41(09): 1146-1152.

Citation:

LIU Hai-chao, LIU Ji-quan, GUO Qi-wen, LI Lian-di, LI Hong-guang, WEN Xia, XIAO Fu-kui, ZHAO Ning, WEI Wei, SUN Yu-han. Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl₂[J]. Journal of Fuel Chemistry and Technology, 2013, 41(09): 1146-1152.

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Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl₂

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;
2.
University of Chinese Academy of Sciences, Beijing 100049, China;
3.
Feicheng Acid Chemical Co., Ltd, Feicheng 271600, China;
4.
Low Carbon Conversion Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, China

Received Date: 2012-11-12
Rev Recd Date: 2013-03-15
Publish Date: 2013-09-30

Abstract

Abstract

Immobilized ZnCl₂ (Silzic) catalyst was prepared and used in the synthesis of 3-methyl-3-buten-1-ol (MBOH) from isobutylene and formaldehyde; the effects of the reaction parameters, such as temperature, molar ratio of isobutene to formaldehyde, reaction time and catalyst content on the reaction behavior were investigated. The results showed that the conversion of formaldehyde is over 99% under various conditions. The reaction temperature as well as the catalyst acidity and the amount of the acid sites are dominant factors in influencing the selectivity to MBOH. Under the optimum reaction conditions, i.e. 210 ℃, 8 g 1,4-dioxane, 1.5 g polyoxymethylene, n(isobutylene)/n(polyoxymethylene) ratio of 7, 30 mg Silzic (1 mmol/g), and reaction time of 2 h, the selectivity and yield of MBOH reach 93.8% and 93.4%, respectively. The Silzic catalyst exhibits certain reusability; the yield of MBOH remains 85.2% after reusing the catalyst for 5 times.
- Prins reaction,
- formaldehyde,
- isobutene,
- 3-methyl-3-buten-1-ol,
- SiO₂-ZnCl₂(Silzic)

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References(24)

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