Volume 42 Issue 03
Mar.  2014
Turn off MathJax
Article Contents
LIU Hong-ying, GAO Xiang, ZHANG Ming-yang, ZHU Yan-ming, ZHU Shu-quan. Study on lignite modified by hydrothermal and the interaction between the oxygen containing functional groups and water[J]. Journal of Fuel Chemistry and Technology, 2014, 42(03): 284-289.
Citation: LIU Hong-ying, GAO Xiang, ZHANG Ming-yang, ZHU Yan-ming, ZHU Shu-quan. Study on lignite modified by hydrothermal and the interaction between the oxygen containing functional groups and water[J]. Journal of Fuel Chemistry and Technology, 2014, 42(03): 284-289.

Study on lignite modified by hydrothermal and the interaction between the oxygen containing functional groups and water

  • Received Date: 2013-08-22
  • Rev Recd Date: 2013-11-06
  • Publish Date: 2014-03-31
  • An Mengdong lignite was modified by hydrothermal method. The water binding energy between the coal surface skeleton molecules and various oxygen containing functional groups was determined and analyzed by means of micro calorimeter. The results show that carboxyl and carbonyl significantly reduced with the increase of temperature, while the change of hydroxyl is complex. The order of hydrophilic ability from large to small for oxygen containing functional groups on coal surface is carboxyl, phenolic hydroxyl, carbonyl, large molecular of the coal.
  • loading
  • 戴和武, 谢可玉. 褐煤利用技术[M]. 北京: 煤炭工业出版社, 1999. (DAI He-wu, XIE Ke-yu. The utilization technology of lignite[M]. Beijing: China Coal Industry Press, 1999.)
    尹立群. 我国褐煤资源及其利用前景[J]. 煤炭科学技术, 2004, 32(8): 12-15. (YING Li-qun. Lignite resources in china and its prospect[J]. Coal Science and Technology, 2004, 32(8): 12-15.)
    ALLARDICE D J, EVANS D G. The-brown coal/water system: Part 2. Water sorption isotherms on bed-moist Yallourn brown coal[J]. Fuel, 1971, 50(2): 236-253.
    MURRAY J B, EVANS D G. The brown-coal/water system: Part 3. Thermal dewatering of brown coal[J]. Fuel, 1972, 51(4): 290-296.
    陈文敏. 煤化学基础[M]. 北京: 煤炭工业出版社, 1990. (CHEN Wen-ming. The base of coal chemistry[M]. Beijing: China Coal Industry Press, 1990.)
    张双全. 煤化学[M]. 中国矿业大学出版社, 2009. (ZHANG Shuang-quan. Coal chemistry[M]. Xuzhou: China University of Mining and Technology Press, 2009.)
    SCHAFER H N S. Carboxyl groups and ion exchange in low-rank coals[J]. Fuel, 1970, 49(2): 197-213.
    SCHAFER H N S. Determination of the total acidity of low-rank coals[J]. Fuel, 1970, 49(3): 271-280.
    ALLARDICE D J, CLEMOW L M, JACKSON W R. Determination of the acid distribution and total acidity of low-rank coals and coal-derived materials by an improved barium exchange technique[J]. Fuel, 2003, 82(1): 35-40.
    MURATA S, HOSOKAWA M, KIDENA K, NOMURA M. Analysis of oxygen-functional groups in brown coals[J]. Fuel Process Technol, 2000, 67(3): 231-243.
    ERDENETSOGT B O, LEE I, LEE S K, KO Y J, DELEGⅡN B E. Solid-state C-13 CP/MAS NMR study of Baganuur coal, Mongolia: Oxygen-loss during coalification from lignite to subbituminous rank[J]. Int J Coal Geol, 2010, 82(1/2): 37-44.
    水恒福, 裴占宁, 王知彩. 水热处理对神华煤液化性能的影响[J]. 燃料化学学报, 2007, 35(6): 655-659. (SHUI Hen-fu, PEI Zan-ning, WANG Zhi-cai. Effect of hydrothermal treatment on the hydrolique faction property of Shenhua coal[J]. Journal of Fuel Chemistry and Technology, 2007, 35(6): 655-659.)
    孙成功, 吴家珊, 李保庆. 低温热改质煤表面性质变化及其对浆体流变性的影响[J]. 燃料化学学报, 1996, 24(1): 173-180. (SUN Cheng-gong, WU Jia-shan, LI Bao-qing. Surface properties of thermally upgraded low-rank coals and their effect on the rheological behavior of coal water slurry[J]. Journal of Fuel Chemistry and Technology, 1996, 24(1): 173-180.)
    赵卫东, 刘建忠, 周俊虎, 曹晓哲, 张光学, 岑可法. 低阶煤高温高压水热处理改性及其成浆特性[J]. 化工学报, 2009, 60(6): 1560-1567. (ZHAO Wei-dong, LIU Jian-zhong, ZHOU Jun-hu, CAO Xiao-zhe, ZHANG Guang-xue, CEN Ke-fa. Hot water treatment of low rank coal in high temperature and high pre ssure reactor and it s slurry ability[J]. Journal of Chemistry Industry, 2009, 60(6): 1560-1567.)
    KREVELEN D W. Coal, 3rd ed[M]. Holland: Elsevier Science Publishers, 1993.
    KRÖGER C, DARSOW G, FUHR K. Physikalisch-chemischeeigenschaften von braunkohlen und braunkohlenkomponenten. V. Die carbonylgruppen und thersauerstoffBestimmung[J]. ErdÖl und KohleErdgasPetrochemie, 1965, 18(n): 701-710.
    严宝珍. 核磁共振在分析化学中的应用[M]. 北京: 化学工业出版社, 1995. (YAN Bao-zhen. NMR application in analytical chemistry[M]. Beijing: Chemical Industry Press, 1995.)
    虞育杰. 褐煤水热脱水提质制备高浓度水煤浆的基础研究[D]. 浙江大学, 2013. (WU yu-jie. The study on lignite hydrothermal dehydration upgrading of the preparation of high concentration coal water slurry[D]. Zhejiang University, 2013.)
    LI C Z. Advances in the science of victorian brown coal[M]. Oxford: Elsevier Itd, 2004.
    谢克昌. 煤的结构与反应性[M]. 北京: 科学出版社, 2002. (XIE Ke-chang. Coal structure and reactivity[M]. Beijing: Science Press, 2002.
    韩德馨, 任德贻, 王廷斌. 中国煤岩学[M]. 徐州: 中国矿业大学出版社, 1996. (HAN De-xin, REN De-yi, WANG Yan-bing. China coal petrology[M]. Xuzhou: China University of Mining and Technology Press, 1996.)
    FAVAS G, JACKSON W R. Hydrothermal dewatering of lower rank coals. 1. Effects of process conditions on the properties of dried product[J]. Fuel, 2003, 82(1): 53-57.
    FAVAS G, JACKSON W R, MARSHALL M. Hydrothermal dewatering of lower rank coals. 3. High-concentration slurries from hydrothermally treated lower rank coals[J]. Fuel, 2003, 82(1): 71-79.
    YU J L, TAHMASEBI A, HAN Y, YIN F K, LI X C. A review on water in low rank coals: The existence, interaction with coal structure and effects on coal utilization[J]. Fuel Process Technol, 2013, 106: 9-20.
    BARTON S S, HARRISON B H. Surface studies on graphite: Immersional energetics[J]. Carbon, 1972, 10(3): 245-251.
    赵卫东. 低阶煤水热改性制浆的微观机理及燃烧特性研究[D]. 浙江大学, 2009. (ZHAO Wei-dong. Micromechanism and combustion characteristics of low-rank coal water slurry upgraded by hot water treatment[D]. Zhejing Unversity, 2009.)
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1065) PDF downloads(761) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return