Volume 42 Issue 04
Apr.  2014
Turn off MathJax
Article Contents
ZHANG Qian, LI Qing-feng, ZHANG Lin-xian, JING Xu-liang, YU Zhong-liang, SONG Shuang-shuang, WANG Zhi-qing, FANG Yi-tian. Experimental study on co-pyrolsysis/gasification of deoiled asphalt with different rank of coal[J]. Journal of Fuel Chemistry and Technology, 2014, 42(04): 392-398.
Citation: ZHANG Qian, LI Qing-feng, ZHANG Lin-xian, JING Xu-liang, YU Zhong-liang, SONG Shuang-shuang, WANG Zhi-qing, FANG Yi-tian. Experimental study on co-pyrolsysis/gasification of deoiled asphalt with different rank of coal[J]. Journal of Fuel Chemistry and Technology, 2014, 42(04): 392-398.

Experimental study on co-pyrolsysis/gasification of deoiled asphalt with different rank of coal

  • Received Date: 2013-10-27
  • Rev Recd Date: 2013-12-16
  • Publish Date: 2014-04-30
  • In order to find an efficient and feasible technological route to dispose and utilize deoiled asphalt (DOA, a byproduct of solvent deasphalting process), the co-pyrolysis/gasification of DOA with different rank of coal was investigated. A series of isothermal co-pyrolysis experiments were conducted in a fixed bed reactor to observe the characteristics of the char yields and the pattern of the blends. Then a set of non-isothermal experiments were performed by thermogravimetric system to evaluate the gasification characteristics of the chars of coal, DOA and the blends. It is observed that the co-pyrolysis char formed as blocks, while the char yields show that the co-pyrolysis process has no interaction between the two resources. The gasification reactivity of the DOA char is lower than that of lignite and bituminous coal char, and is a bit higher than that of anthracite char. The gasification reactivity of the blended char of DOA with lignite/bituminous coal is found higher than that of the calculated, which clearly demonstrating that the synergetic effect existed during the gasification process, and that is mainly caused by the minerals such as Ca, Fe contained in coal char.
  • loading
  • HUSSEIN A, JOAO F, SHAWN T, BOB B, CHAD B, BRENT B, et al. Highlighting heavy oil[J]. Oilfield Review, 2006, 18(2): 34-53.
    程之光. 重油加工技术[M]. 北京: 中国石化出版社, 1994. (CHENG Zhi-guang. Heavy oils processing technology[M]. Beijing: China Petrochemical Press, 1994.)
    RANA M, SAMANO V, ANCHEYTA J, DIAZ J. A review of recent advances on process technologies for upgrading of heavy oils and residua[J]. Fuel, 2007, 86(9): 1216-1231.
    CHEN S, JIA S, LUO Y, ZHAO S. Mild cracking solvent deasphalting: A new method for upgrading petroleum residue[J]. Fuel, 1994, 73(3): 439-442.
    孙显锋, 孙学文, 许志明, 赵锁奇, 徐春明. 辽河稠油减压深度戊烷脱沥青的研究[J]. 燃料化学学报, 2010, 38(5): 565-570. (SUN Xian-feng, SUN Xue-wen, XU Zhi-ming, ZHAO Suo-qi, XU Chun-ming. Solvent deep deasphalting of Liaohe heavy oil vacuum residuum[J]. Journal of Fuel Chemistry and Technology, 2010, 38(5): 565-570.)
    RONALD W. Gasification process old and new: A basic review of the major technologies[J]. Energies, 2010, 3(2): 216-240.
    张乾, 李庆峰, 房倚天, 张林仙. 重油残渣焦水蒸气气化反应特性的研究[J]. 燃料化学学报, 2012, 40(9): 1074-1080. (ZHANG Qian, LI Qing-feng, FANG Yi-tian, ZHANG Lin-xian. Study on steam gasification reactivity of chars from heavy oil residue[J]. Journal of Fuel Chemistry and Technology, 2012, 40(9): 1074-1080.)
    孙显锋, 孙学文, 许志明, 赵锁奇, 徐春明. PGSS法用于脱油沥青颗粒的制备[J]. 高校化学工程学报, 2010, 24(2): 290-295. (SUN Xian-feng, SUN Xue-wen, XU Zhi-ming, ZHAO Suo-qi, XU Chun-ming. Preparation of de-oiled asphalt particles by PGSS proces[J]. Journal of Chemical Engineering of Chinese Universities, 2010, 24(2): 290-295.)
    ZHANG Q, LI Q, ZHANG L, FANG Y, WANG Z. Experimental and kinetic investigation of the pyrolysis, combustion, and gasification of deoiled asphalt[J]. J Therm Anal Calorim, 2014, 115: 1929-1938.
    李庆峰, 房倚天, 张建民, 王洋, 时铭显, 孙国刚. 石油焦水蒸气气化反应特性[J]. 燃料化学学报, 2003, 31(3): 204-208. (LI Qing-feng, FANG Yi-tian, ZHANG Jian-min, WANG Yang, SHI Ming-xian, SUN Guo-gang. Steam gasification characteristics of pertroleum coke[J]. Journal of Fuel Chemistry and Technology, 2003, 31(3): 204-208.)
    ZHAN X, ZHOU Z, WANG F. Catalytic effect of black liquor on the gasification of petroleum coke[J]. Appl Energy, 2010, 87(5): 1710-1715.
    李庆峰, 房倚天, 张建民, 王洋, 时铭显, 孙国刚. 煤灰对石油焦水蒸气气化的影响[J]. 燃烧科学与技术, 2004, 10(4): 359-362. (LI Qing-feng, FANG Yi-tian, ZHANG Jian-min, WANG Yang, SHI Ming-xian, SUN Guo-gang. Gasification of petroleum coke with additional coal ash[J]. Journal of Combustion Science and Technology, 2004, 10(4): 359-362.)
    SUELVES I, MOLINER R, LAZARO M. Synergetic effects in the co-pyrolysis of coal and petroleum residues: Influences of coal mineral matter and petroleum residue mass ratio[J]. J Anal Appl Pyrolysis, 2000, 55(1): 29-41.
    ZHAN X, JIA J, ZHOU Z, WANG F. Influence of blending methods on the co-gasification reactivity of petroleum coke and lignite[J]. Energy Convers Manage, 2011, 52(4): 1810-1814.
    REN H, ZHANG Y, FANG Y, WANG Y. Co-gasification behavior of meat and bone meal char and coal char[J]. Fuel Process Technol, 2011, 92(3): 298-307.
    FERMOSO J, GIL M, PEVIDA C, PIS J, RUBIERA F. Kinetic models comparison for non-isothermal steam gasification of coal-biomass blend chars[J]. Chem Eng J, 2010, 161(1): 276-284.
    胡荣祖, 史启祯. 热分析动力学[M]. 北京: 科学出版社, 2001. (HU Rong-zu, SHI Qi-zhen. Thermal analysis kinetics[M]. Beijing: Science Press, 2001.)
    VYAZOVKIN S, BURNHAM A, CRIADO J, PEREZ L, POPESCU C, SBIRRAZZOULI N. ICTAC kinetics committee recommendations for performing kinetic computations on thermal analysis data[J]. Thermo Acta, 2011, 520(1): 1-19.
    林世雄. 石油炼制工程[M]. 北京: 石油工业出版社, 2000. (LIN Shi-xiong. Petroleum refining engineering[M]. Beijing: Petroleum Industry Press, 2000.)
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (1062) PDF downloads(594) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return