Volume 42 Issue 04
Apr.  2014
Turn off MathJax
Article Contents
ZENG Shang-hong, SU Hai-quan, DING Ning, YU Shi-yong, LIU Ke-wei. Co/SBA-16:Highly selective Fischer-Tropsch synthesis catalyst towards diesel fraction[J]. Journal of Fuel Chemistry and Technology, 2014, 42(04): 449-454.
Citation: ZENG Shang-hong, SU Hai-quan, DING Ning, YU Shi-yong, LIU Ke-wei. Co/SBA-16:Highly selective Fischer-Tropsch synthesis catalyst towards diesel fraction[J]. Journal of Fuel Chemistry and Technology, 2014, 42(04): 449-454.

Co/SBA-16:Highly selective Fischer-Tropsch synthesis catalyst towards diesel fraction

Funds:  Supported by the National Natural Science Foundation of China (21061008).
  • Received Date: 2013-12-17
  • Rev Recd Date: 2014-02-17
  • Publish Date: 2014-04-30
  • A series of Co/SBA-16 catalysts were prepared by the incipient wetness impregnation method and characterized with N2 physisorption,X-ray diffraction,H2-temperature programmed reduction,hydrogen chemisorption and transmission electron microscopy techniques. It was found that the Co0 dispersion decreased with increasing cobalt loading,being consistent with the increase of Co3O4 crystallite sizes and the decrease of BET surface area. The Co/SBA-16 catalysts show high CO conversion,low C1 selectivity,high C5+ hydrocarbon selectivity,and especially high selectivity towards diesel fraction.
  • loading
  • JALAMA K, KABUBA J, XIONG H, JEWELL L L. Co/TiO2 Fischer-Tropsch catalyst activation by synthesis gas[J]. Catal Commun, 2012, 17(1): 154-159.
    LIRA E, LOPEZ CM, OROPEZA F, BARTOLINI M, ALVAREZ J, GOLDWASSER M, LINARES FL, LAMONIER J F, ZURITA M J P. HMS mesoporous silica as cobalt support for the Fischer-Tropsch synthesis: Pretreatment, cobalt loading and particle size effects[J]. J Mol Catal A: Chem, 2008, 281(1/2): 146-153.
    JANBROERS S, CROZIER P A, ZANDBERGEN H W, KOOYMAN P J. A model study on the carburization process of iron-based Fischer-Tropsch catalysts using in situ TEM-EELS[J]. Appl Catal B: Environ, 2011, 102(3/4): 521-527.
    SUZUKI Y, KUCHIDA M, SAKAMA Y, SAIKI H, KARUBE I, TSUBAKI N. Promotion effect of the addition of Eu to Co/silica catalyst for Fischer-Tropsch synthesis[J]. Catal Commun, 2013, 36(1): 75-78.
    KRESGE C T, LEONOWICZ M E, ROTH W J, VARTULI J C, BECK J S. Ordered mesoporous molecular sieves synthesized by a liquidcrystal template mechanism[J]. Nature, 1992, 359(22): 710-712.
    PANPRANOT J, Jr GOODWIN JG, SAYARI A. CO hydrogenation on Ru-promoted Co/MCM-41 catalysts[J]. J Catal, 2002, 211(2): 530-539.
    WANG Y, NOGUCHI M, TAKAHASHI Y, OHTSUKA Y. Synthesis of SBA-15 with different pore sizes and the utilization as supports of high loading of cobalt catalysts[J]. Catal Today, 2001, 68(1/3): 3-9.
    LI H L, WANG S G, LING F X, LI J L. Studies on MCM-48 supported cobalt catalyst for Fischer-Tropsch synthesis[J]. J Mol Catal A: Chem, 2006, 244(1/2): 33-40.
    GRIBOVAL-CONSTANT A, KHODAKOV A Y, BECHARA R, ZHOLOBENKO V L. Support mesoporosity: A tool for better control of catalytic behavior of cobalt supported Fischer Tropsch catalysts[J]. Stud Surf Sci Catal, 2002, 144(1): 609-616.
    KHODAKOV A Y, GRIBOVAL-CONSTANT A, BECHARA R, VILLAIN F. Pore-size control of cobalt dispersion and reducibility in mesoporous silicas[J]. J Phys Chem B, 2001, 105(40): 9805-9811.
    XIONG H F, ZHANG Y H, LIEW K Y, LI J L. Ruthenium promotion of Co/SBA-15 catalysts with high cobalt loading for Fischer-Tropsch synthesis[J]. Fuel Process Technol, 2009, 90(2): 237-246.
    KIM T W, RYOO R, KRUK M, GIERSZAL K P, JARONIEC M, KAMIYA S, TERASAKI O. Tailoring the pore structure of SBA-16 silica molecular sieve through the use of copolymer blends and control of synthesis temperature and time[J]. J Phys Chem B, 2004, 108(31): 11480-11489.
    ZHAO Y X, ZHANG Y H, CHEN J, LI J L, LIEW K Y, NORDIN M R B. SBA-16 supported cobalt catalyst with high activity and stability for the Fischer-Tropsch synthesis[J]. ChemCatChem, 2012, 4(2): 265-272.
    KLIMOVA T, LIZAMA L, AMEZCUA J C, ROQUERO P, TERRES E, NAVARRETE J, DOMINGUEZ J M. New NiMo catalysts supported on Al-containing SBA-16 for 4, 6-DMDBT hydrodesulfurization effect of the alumination method[J]. Catal Today, 2004, 98(1/2): 141-150.
    LAPIDUS A, KRYLOVA A, KAZANSKII V, BOROVKOV V, ZAITSEV A, RATOUSKY J, ZULAL A, JANCALKOVA M. Hydrocarbon synthesis from carbon monoxide and hydrogen on impregnated cobalt catalysts Part I. Physico-chemical properties of 10% cobalt/alumina and 10% cobalt/silica[J]. Appl Catal, 1991, 73(1): 65-82.
    JACOBS G, DAS T K, ZHANG Y, LI J, RACOILLET G, DAVIS B H. Fischer-Tropsch synthesis: Support, loading, and promoter effects on the reducibility of cobalt catalysts[J]. Appl Catal A: Gen, 2002, 233(1/2): 263-281.
    PARK S J, BAE J W, OH J H, CHARY K V R, SAI PRASAD P S, JUN K W, RHEE Y W. Influence of bimodal pore size distribution of Ru/Co/ZrO2-Al2O3 during Fischer-Tropsch synthesis in fixed-bed and slurry reactor[J]. J Mol Catal A: Chem, 2009, 298(1/2): 81-87.
    JIA L H, JIA L T, LI D B, HOU B, WANG J G, SUN Y H. Silylated Co/SBA-15 catalysts for Fischer-Tropsch synthesis[J]. J Solid State Chem, 2011, 184(3): 488-493.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (904) PDF downloads(551) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return