Reaction kinetics of ammonia decomposition over La-CoMoN<sub><em>x</em></sub>/CNTs catalyst

ZHAO Zhao-hui; ZOU Han-bo; LIN Wei-ming

Volume 42 Issue 06

Jun. 2014

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ZHAO Zhao-hui, ZOU Han-bo, LIN Wei-ming. Reaction kinetics of ammonia decomposition over La-CoMoNx/CNTs catalyst[J]. Journal of Fuel Chemistry and Technology, 2014, 42(06): 758-762.

Citation:

ZHAO Zhao-hui, ZOU Han-bo, LIN Wei-ming. Reaction kinetics of ammonia decomposition over La-CoMoN_x/CNTs catalyst[J]. Journal of Fuel Chemistry and Technology, 2014, 42(06): 758-762.

ZHAO Zhao-hui, ZOU Han-bo, LIN Wei-ming. Reaction kinetics of ammonia decomposition over La-CoMoNx/CNTs catalyst[J]. Journal of Fuel Chemistry and Technology, 2014, 42(06): 758-762.

Citation:

ZHAO Zhao-hui, ZOU Han-bo, LIN Wei-ming. Reaction kinetics of ammonia decomposition over La-CoMoN_x/CNTs catalyst[J]. Journal of Fuel Chemistry and Technology, 2014, 42(06): 758-762.

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Reaction kinetics of ammonia decomposition over La-CoMoN_x/CNTs catalyst

School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

Received Date: 2013-12-03
Rev Recd Date: 2014-03-27
Publish Date: 2014-06-30

Abstract

Abstract

The reaction kinetics of ammoniade composition over La-CoMoN_x/CNTs catalyst were studied. The effect of N₂ concentration, H₂ concentration, NH₃ concentration and reaction temperature on the rate of ammonia decomposition were investigated. According to the experimental data, the correlative kinetic parameters were determined based on an exponential equation. The intrinsic kinetic equation was obtained. The activation energy of the reaction was 93.948 kJ/mol. The reaction mechanism was also discussed. The reaction rate of ammonia decomposition over La-CoMoN_x/CNTs was controlled by the combination desorption of nitrogen on the surface of the catalyst.
- supported metallic nitride,
- catalysis,
- ammonia decomposition,
- hydrogen production,
- reaction kinetic

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References(13)

References

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