Catalytic performance of Fe-modified Ru/Al<sub>2</sub>O<sub>3</sub> in the hydrogenation of dimethyl maleate

WANG Lei; NUERMAIMAITI Abudukelimu; MA Yu-bo; QING Shao-jun; GAO Zhi-xian; WUMANJIANG Eli

Volume 42 Issue 07

Jul. 2014

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Article Navigation > Journal of Fuel Chemistry and Technology > 2014 > 42(07): 839-844

WANG Lei, NUERMAIMAITI Abudukelimu, MA Yu-bo, QING Shao-jun, GAO Zhi-xian, WUMANJIANG Eli. Catalytic performance of Fe-modified Ru/Al2O3 in the hydrogenation of dimethyl maleate[J]. Journal of Fuel Chemistry and Technology, 2014, 42(07): 839-844.

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WANG Lei, NUERMAIMAITI Abudukelimu, MA Yu-bo, QING Shao-jun, GAO Zhi-xian, WUMANJIANG Eli. Catalytic performance of Fe-modified Ru/Al₂O₃ in the hydrogenation of dimethyl maleate[J]. Journal of Fuel Chemistry and Technology, 2014, 42(07): 839-844.

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Catalytic performance of Fe-modified Ru/Al₂O₃ in the hydrogenation of dimethyl maleate

1.
Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Ulumqi 830011, China;
2.
University of Chinese Academy of Sciences, Beijing 100049, China;
3.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Received Date: 2013-12-30
Rev Recd Date: 2014-03-27
Publish Date: 2014-07-30

Abstract

Abstract

Fe-modified Ru/Al₂O₃ (Ru-Fe/Al₂O₃) catalysts were prepared by adsorption-precipitation (AP) method with alumina as the support and characterized by H₂-TPR, XRD and XPS; the effect of Fe modification on the catalytic performance of Ru-Fe/Al₂O₃ was investigated in the selective hydrogenation of dimethyl meleate (DMM) to dimethyl succinate (DMS). The results indicated that through the modification with a Fe/Ru atomic ratio above 2, the catalytic performance of Ru-Fe/Al₂O₃ and its stability towards high temperature oxidation-reduction treatment is obviously enhanced. Under 70℃, 1.0 MPa and with a stirring speed of 600 r/min, the conversion of DMM and the selectivity to DMS were both nearly 100%. The XPS and H₂-TPR results suggest that the promoting effect of Fe on Ru-Fe/Al₂O₃ may be ascribed to an increase of Ru dispersion as well as a change in Ru electronic state through the modification with Fe.
- Ru-Fe/Al₂O₃,
- dimethyl maleate,
- catalytic hydrogenation,
- dimethyl succinate,
- Fe modification

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References(26)

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