Effect of support on catalytic performance for metathesis of butene to propene

HUA De-run; CHEN Sheng-li; ZHOU Zheng; CHEN Ai-cheng; LIU Hong-bo; HUANG Qing; LU Xin-ning

Volume 42 Issue 07

Jul. 2014

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Article Navigation > Journal of Fuel Chemistry and Technology > 2014 > 42(07): 865-869

HUA De-run, CHEN Sheng-li, ZHOU Zheng, CHEN Ai-cheng, LIU Hong-bo, HUANG Qing, LU Xin-ning. Effect of support on catalytic performance for metathesis of butene to propene[J]. Journal of Fuel Chemistry and Technology, 2014, 42(07): 865-869.

Citation:

HUA De-run, CHEN Sheng-li, ZHOU Zheng, CHEN Ai-cheng, LIU Hong-bo, HUANG Qing, LU Xin-ning. Effect of support on catalytic performance for metathesis of butene to propene[J]. Journal of Fuel Chemistry and Technology, 2014, 42(07): 865-869.

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Effect of support on catalytic performance for metathesis of butene to propene

1.
Gannan Normal University, Chemical Institute of Chemical Industry, Ganzhou 341000, China;
2.
China University of Petroleum, State Key of Heavy Oil Processing, Beijing 102249, China;
3.
Natural Gas Treating Plant, Sinopec Zhongyuan Oilfield Branch, Puyang 457001, China

Received Date: 2013-11-27
Rev Recd Date: 2014-03-11
Publish Date: 2014-07-30

Abstract

Abstract

The catalysts with SBA-15, MCM-48, SiO₂, and MTS-9 as supports were synthesized with 8% WO₃, and their catalytic performance for metathesis of butene to propene were carried out. The conversion of butene is 30%~37% on the catalysts with SBA-15, MCM-48, and SiO₂ as supports, and that of butene is 37%~42% on WO₃/MTS-9 catalyst. The catalyst characterization results show that the catalytic activities depend on the acidic numbers of catalysts prepared and the distribution of tungstens on the supports used. As a result, the performance of 8% WO₃/MTS-9 catalyst for the titled reaction is best.
- propene,
- metathesis,
- support,
- WO₃

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References(29)

References

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