Volume 42 Issue 10
Oct.  2014
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WEI Li-hong, MA Ting-ting, LI Run-dong, YANG Tian-hua, LI Yan-ji, WEN Li-na. Effect of acidic compositions on ash fusion temperatures[J]. Journal of Fuel Chemistry and Technology, 2014, 42(10): 1205-1211.
Citation: WEI Li-hong, MA Ting-ting, LI Run-dong, YANG Tian-hua, LI Yan-ji, WEN Li-na. Effect of acidic compositions on ash fusion temperatures[J]. Journal of Fuel Chemistry and Technology, 2014, 42(10): 1205-1211.

Effect of acidic compositions on ash fusion temperatures

  • Received Date: 2014-05-29
  • Rev Recd Date: 2014-07-30
  • Publish Date: 2014-10-30
  • Ash fusion characteristic parameters of 129 typical original ash samples were collected locally and abroad, which included coals, sewage sludge and blends of sewage sludge/coal. These data were used to study the effect of acidic oxides including SiO2, Al2O3, TiO2 and P2O5 on ash fusion temperatures (AFTs). The refractory minerals such as quartz, metakaolin, mullite and rutile formed by SiO2, Al2O3 and TiO2 improve the AFTs. The results show that Al2O3 is a main factor in determining AFTs. Furthermore, the non-metal oxides P2O5 has a significant correlation with the FT of sewage sludge and sewage sludge/coal blends and its increase can obviously reduce AFTs, which might be caused by the higher P2O5 content in sewage sludge.
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  • VASSILEV S V, KITANO K, TAKEDA S, TSURUE T. Influence of mineral and chemical composition of coal ashes on their fusibility[J]. Fuel Process Technol, 1995, 45(1): 27-51.
    VANDYK J C, BENSON S A, LAUMB M L, WAANDERS B. Coal and coal ash characteristics to understand mineral transformations and slag formation[J]. Fuel, 2009, 88(6): 1057-1063.
    LI Q H, ZHANG Y G, MENG A H, LI L, LI G X. Study on ash fusion temperature using original and simulated biomass ashes[J]. Fuel Process Technol, 2013, 107: 107-112.
    QIU J R, LI F, ZHENG Y, ZHENG C G, ZHOU H C. The influences of mineral behaviour on blended coal ash fusion characteristics[J]. Fuel, 1999, 78(8): 963-969.
    JING N J, WANG Q H, CHENG L M, LUO Z Y, CEN K F, ZHANG D K. Effect of temperature and pressure on the mineralogical and fusion characteristics of Jincheng coal ash in simulated combustion and gasification environments[J]. Fuel, 2013, 104: 647-655.
    LIU B, HE Q H, JIANG Z H, XU R F, HU B X. Relationship between coal ash composition and ash fusion temperatures[J]. Fuel, 2013, 105: 293-300.
    WUX J, ZHANG Z X, CHEN Y S, ZHOU T, FAN J J, PIAO G L, KOBAYASHI N, MORI S, ITAYA Y. Main mineral melting behavior and mineral reaction mechanism at molecular level of blended coal ash under gasification condition[J]. Fuel Process Technol, 2010, 91(11): 1591-1600.
    SONGW J, TANGL H, ZHU X D, WU Y Q, ZHU Z B, KOYAMA S. Effect of coal ash composition on ash fusion temperatures[J]. Energy Fuels, 2009, 24(1): 182-189.
    李继炳, 沈本贤, 李寒旭, 赵基钢, 王基铭. 铁基助熔剂对皖北刘桥二矿煤的灰熔融特性影响研究[J]. 燃料化学学报, 2009, 37(3): 262-265. (LI Ji-bing, SHEN Ben-xian, LI Han-xu, ZHAO Ji-gang, WANG Ji-ming. Effect of ferrum-based flux on the melting characteristics of coal ash from coal blends using the Liu-qiao No. 2 coal mine in Wan-bei[J]. Journal of Fuel Chemistry and Technology, 2009, 37(3): 262-265.)
    孔令学, 白进, 李文, 白宗庆, 郭振兴. 氧化钙含量对灰渣流体性质影响的研究[J]. 燃料化学学报, 2011, 39(6): 407-411. (KONG Ling-xue, BAI Jin, LI Wen, BAI Zong-qing, GUO Zhen-xing. Effect of lime addition on slag fluidity of coal ash[J]. Journal of Fuel Chemistry and Technology, 2011, 39(6): 407-411.)
    KONG L X, BAI J, BAI Z Q, GUO Z, LI W. Effects of CaCO3 on slag flow properties at high temperatures[J]. Fuel, 2013, 109: 76-85.
    KUPKA T, MANCINI M, IRMER M, WEBER R. Investigation of ash deposit formation during co-firing of coal with sewage sludge, saw-dust and refuse derived fuel[J]. Fuel, 2008, 87(12): 2824-2837.
    ZHANG Q, LIU H F, QIAN Y P, XU M H, LI W F, XU J L. The influence of phosphorus on ash fusion temperature of sludge and coal[J]. Fuel Process Technol, 2013, 110: 218-226.
    WANG L, SKJEVRAK G, HUSTAD J E, GRNLI M G. Sintering characteristics of sewage sludge ashes at elevated temperatures[J]. Fuel Process Technol, 2012, 96: 88-97.
    LI W D, LI. M, LI W F, LIU H F. Study on the ash fusion temperatures of coal and sewage sludge mixtures[J]. Fuel, 2010, 89(7): 1566-1572.
    VAN DYK J C. Understanding the influence of acidic components (Si, Al, and Ti) on ash flow temperature of South African coal sources[J]. Miner Engineer, 2006, 19(3): 280-286.
    孟莹. 煤灰成分对煤灰熔融行为影响的研究[D]. 安徽理工大学, 2011. (MENG Ying. Study on effect of coal ash chemical composition on ash fusion behaviors[D]. Anhui, China: AnHui University of Seience and Technology 2011.)
    李文, 白进. 煤的灰化学[M]. 中国, 北京: 科学出版社, 2013: 84. (LI Wen, BAI Jin. Chemistry of ash from coal[M]. Beijing, China: Science Press, 2013: 84.)
    姚星一. 煤灰熔点与化学成分的关系[J]. 燃料化学学报, 1965, 6(2): 151-161. (YAO Xing-yi. Relation of coal ash fusion temperature and chemistry composition[J]. Journal of Fuel Chemistry and Technology, 1965, 6(2): 151-161.)
    ZHAO B T, ZHANG Z X, WU X J. Prediction of coal ash fusion temperature by least-squares support vector machine model[J]. Energy Fuels, 2010, 24(5): 3066-3071.
    VASSILEV S V, KITANO K, VASSILEVA C G. Relations between ash yield and chemical and mineral composition of coals[J]. Fuel, 1997, 76(1): 3-8.
    张强. 生物质与煤共气化过程中磷元素的迁移与影响.[D] 上海: 华东理工大学, 2012. (ZHANG Qiang. Transfer behavior and influence of phosphorus in biomass and coal co-gasification[D]. Shanghai: East China University of Science and Technology, 2012.)
    王雪花. 污泥与煤混烧成灰及结渣特性研究[D]. 沈阳: 沈阳航空航天大学, 2011. (WANG Xue-hua. Research on the characteristics of ash and slagging from Co-combustion of sewage sludge and coal[D]. Shenyang: Shenyang Aerospace University, 2011.)
    马志斌, 白宗庆, 白进, 李文, 郭振兴. 高温弱还原气氛下高硅铝比煤灰变化行为的研究[J]. 燃料化学学报, 2012, 40(3): 279-285. (MA Zhi-bin, BAI Zong-qin, BAI Jin, LI Wen, GUO Zhen-xing. Evolution of coal ash with high Si/Al ratio under reducing atmosphere at high temperature[J]. Journal of Fuel Chemistry and Technology, 2012, 40(3): 279-285.)
    PARK S W, JANGC H. Characteristics of carbonized sludge for co-combustion in pulverized coal power plants[J]. Waste Management, 2011, 31(3): 523-529.
    胡云鹏, 程世庆, 孙鹏, 谢敬思, 张浩. 生物质及其与煤掺烧的灰熔融特性研究[J]. 热力发电, 2011, 40(10): 8-12, 16. (HU Yun-peng, CHENG Shi-qin, SUN Peng, XIE Jin-si, ZHANG Hao. Study on fusion benavior of ash from mixedly burning biomass with coal. Thermal Power generation, 2011, 40(10): 8-12, 16.)
    张成, 王丹, 夏季, 陈刚. 煤粉掺烧干化污泥的燃烧特性及能效分析[J]. 热能动力工程, 2012, 27(3): 383-387, 398. (ZHANG Cheng, WANG Dan, XIA Ji, CHEN Gang. Study on the co-combustion characteristics and energy efficiency analysis of coal and sewage sludge[J]. Journal of Engineering for Thermal Energy and Power, 2012, 27(3): 383-387, 398.)
    刘涛, 陈雪莉, 李德侠, 刘霞, 梁钦锋. 生物质与煤混合灰的熔融及黏温特性[J]. 化工学报, 2012, 63(4): 1217-1225. (LIU Tao, CHEN Xue-li, LI De-xia, LIU Xia, LIANG Qin-feng. Blending ash fusion and viscosity-temperature characteristics of biomass and coal[J]. CIESC Journal, 2012, 63(4): 1217-1225.)
    毛军. 煤灰熔融特性及矿物组成研究[J]. 能源与环境, 2013, 13(1): 3-4, 6. (MAO Jun. Study on coal ash fusion characteristics and mineral composition[J]. Journal of Energy and Enviroment, 2013, 13(1): 3-4, 6.)
    李风海, 贾建波, 黄戒介, 房倚天. 含钙矿物对褐煤灰熔融特性的影响研究[J]. 煤炭转化, 2012, 35(4): 7-10, 25. (LI Feng-hai, JIA Jian-bo, HUANG Jie-jie, FANG Yi-tian. Study on the influence of Ca-bearing minerals on ash fusion characterisyics of lignite coal[J]. Coal Conversion, 2012, 35(4): 7-10, 25.)
    李平, 梁钦锋, 刘霞, 龚欣. 酸碱比值与助熔剂对煤灰熔融流动温度影响的研究[J]. 大氮肥, 2010, 33(2): 107-111. (LI Ping, LIANG Qin-feng, LIU Xia, GONG Xin. Study on the influence of base to acid ratio and fluxing agent on coal ash melting flow temperature[J]. Large Scale Nitrogenous Fertilizer Industry, 2010, 33(2): 107-111.)
    黄镇宇, 李燕, 赵京, 周志军, 周俊虎, 岑可法. 不同灰成分的低熔点煤灰熔融性调控机理研究[J].燃料化学学报, 2012, 40(9): 1038-1043. (HUANG Zhen-yu, LI Yan, ZHAO Jing, ZHOU Zhi-jun, ZHOU Jun-hu, CEN Ke-fa. Ash fusion regulation mechanismof coal with low melting point and different ash compositions[J]. Journal of Fuel Chemistry and Technology, 2012, 40(9): 1038-1043.)
    VAN DYK J C, KEYSER M L, WAANDERS F B, CONRADIE M. Manipulation of the ash flow temperature and viscosityof a carbonaceous Sasol waste stream[J]. Fuel, 2010, 89: 229-236.
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