Co and Cu modified Ni/Al<sub>2</sub>O<sub>3</sub> steam reforming catalysts for hydrogen production from model bio-oil

XIE Deng-yin; ZHANG Su-ping; CHEN Zhi-yuan; CHEN Zhen-qi; XU Qing-li

Volume 43 Issue 03

Mar. 2015

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Article Navigation > Journal of Fuel Chemistry and Technology > 2015 > 43(03): 302-308

XIE Deng-yin, ZHANG Su-ping, CHEN Zhi-yuan, CHEN Zhen-qi, XU Qing-li. Co and Cu modified Ni/Al2O3 steam reforming catalysts for hydrogen production from model bio-oil[J]. Journal of Fuel Chemistry and Technology, 2015, 43(03): 302-308.

Citation:

XIE Deng-yin, ZHANG Su-ping, CHEN Zhi-yuan, CHEN Zhen-qi, XU Qing-li. Co and Cu modified Ni/Al₂O₃ steam reforming catalysts for hydrogen production from model bio-oil[J]. Journal of Fuel Chemistry and Technology, 2015, 43(03): 302-308.

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Co and Cu modified Ni/Al₂O₃ steam reforming catalysts for hydrogen production from model bio-oil

Key Laboratory of Coal Gasification and Engineering of Ministry of Education, Shanghai 200237, China

Received Date: 2014-09-24
Publish Date: 2015-03-30

Abstract

Abstract

Ni/Al₂O₃ catalyst was selected as the reference catalyst for steam reforming of model bio-oil to produce hydrogen. Ni-Cu/Al₂O₃, Ni-Co/Al₂O₃ and Ni-Co-Cu/Al₂O₃ were prepared to investigate the influence of Co and Ni on steam reforming of bio-oil. The results show that Co can enhance the water gas shift (WGS) reaction rate, and Cu can prevent the formation of coke. The reaction conditions for the steam reforming of bio-oil with the Ni-Co-Cu/Al₂O₃ catalyst were optimized as the follows: temperature of 900 ℃, water-oil ratio (the mass ratio of steam to oil) of 6 g/g and weight hourly space velocity (WHSV) of 1 h^-1. The carbon selectivity of 87.5%, hydrogen yield of 84.2% and potential hydrogen yield of 92.4% can be obtained at the optimum conditions.
- bio-oil,
- catalytic reforming,
- hydrogen

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References(28)

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